Small organic molecule based flow battery

Title: Small organic molecule based flow battery

Abstract

The invention provides an electrochemical cell based on a new chemistry for a flow battery for large scale, e.g., gridscale, electrical energy storage. Electrical energy is stored chemically at an electrochemical electrode by the protonation of small organic molecules called quinones to hydroquinones. The proton is provided by a complementary electrochemical reaction at the other electrode. These reactions are reversed to deliver electrical energy. A flow battery based on this concept can operate as a closed system. The flow battery architecture has scaling advantages over solid electrode batteries for large scale energy storage.

Inventors:: Huskinson, Brian; Marshak, Michael; Aziz, Michael J.; Gordon, Roy G.; Betley, Theodore A.; Aspuru-Guzik, Alan; Er, Suleyman; Suh, Changwon

Publication Date:: 2018-05-08

Research Org.:: Harvard Univ., Cambridge, MA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1440013

Patent Number(s):: 9,966,622

Application Number:: 14/823,546

Assignee:: President and Fellows of Harvard College (Cambridge, MA)

DOE Contract Number:: AR0000348

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Aug 11

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Huskinson, Brian, Marshak, Michael, Aziz, Michael J., Gordon, Roy G., Betley, Theodore A., Aspuru-Guzik, Alan, Er, Suleyman, and Suh, Changwon. Small organic molecule based flow battery.  United States: N. p., 2018. 
        Web.

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                    Huskinson, Brian, Marshak, Michael, Aziz, Michael J., Gordon, Roy G., Betley, Theodore A., Aspuru-Guzik, Alan, Er, Suleyman, & Suh, Changwon. Small organic molecule based flow battery.  United States.

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                    Huskinson, Brian, Marshak, Michael, Aziz, Michael J., Gordon, Roy G., Betley, Theodore A., Aspuru-Guzik, Alan, Er, Suleyman, and Suh, Changwon. Tue .  
        "Small organic molecule based flow battery".  United States.  https://www.osti.gov/servlets/purl/1440013.

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@article{osti_1440013,

  title        = {Small organic molecule based flow battery},

  author       = {Huskinson, Brian and Marshak, Michael and Aziz, Michael J. and Gordon, Roy G. and Betley, Theodore A. and Aspuru-Guzik, Alan and Er, Suleyman and Suh, Changwon},

  abstractNote = {The invention provides an electrochemical cell based on a new chemistry for a flow battery for large scale, e.g., gridscale, electrical energy storage. Electrical energy is stored chemically at an electrochemical electrode by the protonation of small organic molecules called quinones to hydroquinones. The proton is provided by a complementary electrochemical reaction at the other electrode. These reactions are reversed to deliver electrical energy. A flow battery based on this concept can operate as a closed system. The flow battery architecture has scaling advantages over solid electrode batteries for large scale energy storage.},

  doi          = {},

  url          = {https://www.osti.gov/biblio/1440013},
  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {5}

}

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Similar Records

Title: Small organic molecule based flow battery

Abstract

Citation Formats

Fuel cell using quinones to oxidize hydroxylic compounds patent, March 1986

Carbon monoxide-oxygen fuel cell patent, December 1987

Method of photochemical immobilization of ligands using quinones patent, March 2000

Cooking method for pulp patent-application, July 2002

Methods for use of a photobiofuel cell in production of hydrogen and other materials patent-application, August 2007

Secondary Battery, Power Supply System Using Same and Usage of Power Supply System patent-application, January 2009

Method for Manufacturing Secondary Battery and Method for Preparing Positive Electrode Active Material for Secondary Battery patent-application, April 2009

Fluid-surfaced electrode patent-application, February 2011

Cascade Redox Flow Battery Systems patent-application, September 2011

Fuel Cell Device with Electrolytes Flowing by Means of Percolation Through Electrodes Having A Porous, Three-Dimensional Structure patent-application, March 2015

Quinone and Hydroquinone Based Flow Battery patent-application, August 2016

Redox flow batteries a review journal, September 2011

A study of tiron in aqueous solutions for redox flow battery application journal, January 2010

Evaluation of organic battery electrodes: Voltammetric study of the redox behaviour of solid quinones journal, August 1972

Simple preparative synthesis of spinochrome e, a pigment from sea urchins of the genus Echinothrix journal, May 2012

A Quinone-Bromide Flow Battery with 1 W/cm2 Power Density journal, July 2015

Free And Total Energy Changes In The Reduction Of Quinones journal, November 1922

Reduction Potentials Of Quinones. I. The Effect Of The Solvent On The Potentials Of Certain Benzoquinones journal, September 1923

Reduction Potentials Of Quinones. II. The Potentials Of Certain Derivatives Of Benzoquinone, Naphthoquinone And Anthraquinone journal, August 1924

Analytical applications of 1,10-anthraquinones: A review journal, June 1991

Computational design of molecules for an all-quinone redox flow battery journal, January 2015

Electrochemical CO2 Reduction on Metal Electrodes book, January 2008

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures journal, March 2012

A metal-free organic–inorganic aqueous flow battery journal, January 2014

Cycling of a Quinone-Bromide Flow Battery for Large-Scale Electrochemical Energy Storage journal, September 2014

Novel Quinone-Based Couples for Flow Batteries journal, May 2013

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films journal, April 2012

Alkaline quinone flow battery journal, September 2015

Benzoquinone-Hydroquinone Couple for Flow Battery journal, January 2013

Anthraquinone with tailored structure for a nonaqueous metal–organic redox flow battery journal, January 2012

Novel organic redox flow batteries using soluble quinonoid compounds as positive materials conference, September 2009

High-capacity organic positive-electrode material based on a benzoquinone derivative for use in rechargeable lithium batteries journal, December 2010

Fuel cell using quinones to oxidize hydroxylic compounds
patent, March 1986

Carbon monoxide-oxygen fuel cell
patent, December 1987

Method of photochemical immobilization of ligands using quinones
patent, March 2000

Cooking method for pulp
patent-application, July 2002

Methods for use of a photobiofuel cell in production of hydrogen and other materials
patent-application, August 2007

Secondary Battery, Power Supply System Using Same and Usage of Power Supply System
patent-application, January 2009

Method for Manufacturing Secondary Battery and Method for Preparing Positive Electrode Active Material for Secondary Battery
patent-application, April 2009

Fluid-surfaced electrode
patent-application, February 2011

Cascade Redox Flow Battery Systems
patent-application, September 2011

Fuel Cell Device with Electrolytes Flowing by Means of Percolation Through Electrodes Having A Porous, Three-Dimensional Structure
patent-application, March 2015

Quinone and Hydroquinone Based Flow Battery
patent-application, August 2016

Redox flow batteries a review
journal, September 2011

A study of tiron in aqueous solutions for redox flow battery application
journal, January 2010

Evaluation of organic battery electrodes: Voltammetric study of the redox behaviour of solid quinones
journal, August 1972

Simple preparative synthesis of spinochrome e, a pigment from sea urchins of the genus Echinothrix
journal, May 2012

A Quinone-Bromide Flow Battery with 1 W/cm² Power Density
journal, July 2015

Free And Total Energy Changes In The Reduction Of Quinones
journal, November 1922

Reduction Potentials Of Quinones. I. The Effect Of The Solvent On The Potentials Of Certain Benzoquinones
journal, September 1923

Reduction Potentials Of Quinones. II. The Potentials Of Certain Derivatives Of Benzoquinone, Naphthoquinone And Anthraquinone
journal, August 1924

Analytical applications of 1,10-anthraquinones: A review
journal, June 1991

Computational design of molecules for an all-quinone redox flow battery
journal, January 2015

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Reversible hydrogen storage using CO₂ and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures
journal, March 2012

A metal-free organic–inorganic aqueous flow battery
journal, January 2014

Cycling of a Quinone-Bromide Flow Battery for Large-Scale Electrochemical Energy Storage
journal, September 2014

Novel Quinone-Based Couples for Flow Batteries
journal, May 2013

CO₂ Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu₂O Films
journal, April 2012

Alkaline quinone flow battery
journal, September 2015

Benzoquinone-Hydroquinone Couple for Flow Battery
journal, January 2013

Anthraquinone with tailored structure for a nonaqueous metal–organic redox flow battery
journal, January 2012

Novel organic redox flow batteries using soluble quinonoid compounds as positive materials
conference, September 2009

High-capacity organic positive-electrode material based on a benzoquinone derivative for use in rechargeable lithium batteries
journal, December 2010