Prediction of trivalent actinide amino(poly)carboxylate complex stability constants using linear free energy relationships with the lanthanide series

Uhnak, Nic E.

doi:10.1080/01496395.2017.1397026

Title: Prediction of trivalent actinide amino(poly)carboxylate complex stability constants using linear free energy relationships with the lanthanide series

Journal Article · Mon Nov 27 00:00:00 EST 2017 · Separation Science and Technology

DOI:https://doi.org/10.1080/01496395.2017.1397026· OSTI ID:1439689

Uhnak, Nic E. ^[1]

Chemistry of Nuclear Materials Group, Radiochemistry Separations Division, Pacific Northwest National Laboratory, Washington, United States

Prediction of Trivalent Actinide Amino(poly)carboxylate Complex Stability Constants Using Linear Free Energy Relationships with the Lanthanide Series Alternative title: LFER Based Prediction of An(III) APC Stability Constants There is a gap in the literature regarding the complexation of amino(poly)carboxylate (APC) ligands with trivalent actinides (An(III))). The chemistry of the An(III) is nearly identical to that of the trivalent lanthanides Lns, but the An(III) express a slight enhancement when binding APC ligands. Presented in this report is a simple method of predicting the stability constants of the An(III), Pu, Am, Cm, Bk and Cf by using linear free energy relationships (LFER) of the An and the lanthanide (Ln) series for 91 APCs. This method produced An stability constants within uncertainty to available literature values for most ligands.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1439689

Report Number(s):: PNNL-SA-129004; 45304036L

Journal Information:: Separation Science and Technology, Vol. 53, Issue 5; ISSN 0149-6395

Publisher:: Taylor & Francis

Country of Publication:: United States

Language:: English

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