Freestanding NiFe Oxyfluoride Holey Film with Ultrahigh Volumetric Capacitance for Flexible Asymmetric Supercapacitors

Liang, Kun; Marcus, Kyle; Yang, Zhenzhong; Zhou, Le; Pan, Hao; Bai, Yuanli; Du, Yingge; Engelhard, Mark H.; Yang, Yang

doi:10.1002/smll.201702295

Title: Freestanding NiFe Oxyfluoride Holey Film with Ultrahigh Volumetric Capacitance for Flexible Asymmetric Supercapacitors

Journal Article · Tue Nov 14 00:00:00 EST 2017 · Small

DOI:https://doi.org/10.1002/smll.201702295· OSTI ID:1439669

Liang, Kun ^[1]; Marcus, Kyle ^[1]; Yang, Zhenzhong ^[2]; Zhou, Le ^[3]; Pan, Hao ^[4]; Bai, Yuanli ^[4]; Du, Yingge ^[2]; Engelhard, Mark H. ^[5];

^[6]

NanoScience Technology Center, University of Central Florida, Orlando FL 32826 USA
Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA
Department of Materials Science and Engineering, University of Central Florida, Orlando FL 32826 USA
Department of Mechanical and Aerospace Engineering, University of Central Florida, Orlando FL 32816 USA
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99352 USA
NanoScience Technology Center, University of Central Florida, Orlando FL 32826 USA; Department of Materials Science and Engineering, University of Central Florida, Orlando FL 32826 USA

In this work, a freestanding NiFe oxyfluoride (NiFeOF) holey film was prepared by electrochemical deposition and anodic treatments. With the combination of good electrical conductivity and holey structure, the NiFeOF holey film offers superior electrochemical performance, due to the following reasons: (i) The residual metal alloy framework can be used as the current collector to improve electrode conductivity. Moreover, the as-prepared freestanding NiFeOF holey film can be used as a supercapacitor electrode without reliance on binders and other additives. The residual metal alloy framework and binder-free electrode effectively reduces electrode resistance, thus improving electron transport. (ii) The highly interconnected holey structure and hierarchical pore distribution provides a high specific surface area to improve electron transport, enhancing rapid ion transport and mitigating diffusion limitations throughout the holey film. (iii) The excellent mechanical characteristics facilitate flexibility and cyclability related performance. Additionally, the NiFeOF holey film presents exceptional electrochemical performance, showing that it is a promising alternative for small/micro-size electronic devices.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1439669

Report Number(s):: PNNL-SA-130019; KC0203020

Journal Information:: Small, Vol. 14, Issue 3; ISSN 1613-6810

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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