Porous Carbon-Hosted Atomically Dispersed Iron-Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH

Fu, Shaofang; Zhu, Chengzhou; Su, Dong; Song, Junhua; Yao, Siyu; Feng, Shuo; Engelhard, Mark H.; Du, Dan; Lin, Yuehe

doi:10.1002/smll.201703118

Title: Porous Carbon-Hosted Atomically Dispersed Iron-Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH

Journal Article · Mon Feb 12 00:00:00 EST 2018 · Small

DOI:https://doi.org/10.1002/smll.201703118· OSTI ID:1439660

Fu, Shaofang ^[1]; Zhu, Chengzhou ^[2]; Su, Dong ^[3]; Song, Junhua ^[1]; Yao, Siyu ^[4]; Feng, Shuo ^[1]; Engelhard, Mark H. ^[5]; Du, Dan ^[2];

^[1]

School of Mechanical and Materials Engineering, Washington State University, WA 99164 USA
School of Mechanical and Materials Engineering, Washington State University, WA 99164 USA; Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry Central China Normal University, Wuhan 430079 P. R. China
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton NY 11973 USA
Chemistry Department, Brookhaven National Laboratory, Upton NY 11973 USA
Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA

As one of the alternatives to replace precious metal catalysts, transition-metal–nitrogen–carbon (M–N–C) electrocatalysts have attracted great research interest due to their low cost and good catalytic activities. Despite nanostructured M–N–C catalysts can achieve good electrochemical perfor-mances, they are vulnerable to aggregation and insufficient catalytic sites upon continuous catalytic reaction. In this work, metal–organic frameworks derived porous single-atom electrocatalysts (SAEs) were successfully prepared by simple pyrolysis procedure without any further posttreatment. Combining the X-ray absorption near-edge spectroscopy and electrochemical measure-ments, the SAEs have been identified with superior oxygen reduction reaction (ORR) activity and stability compared with Pt/C catalysts in alkaline condition. More impressively, the SAEs also show excellent ORR electrocatalytic perfor-mance in both acid and neutral media. This study of nonprecious catalysts provides new insights on nanoengineering catalytically active sites and porous structures for nonprecious metal ORR catalysis in a wide range of pH.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1439660

Report Number(s):: PNNL-SA-133964; 48920; KP1704020

Journal Information:: Small, Vol. 14, Issue 12; ISSN 1613-6810

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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