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Title: Systems and methods for preparation and separation of products

Patent ·
OSTI ID:1439331

There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.

Research Organization:
Calera Corporation, Moss Landing, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0002472
Assignee:
Calera Corporation (Moss Landing, CA)
Patent Number(s):
9,957,623
OSTI ID:
1439331
Resource Relation:
Patent File Date: 2015 Oct 21
Country of Publication:
United States
Language:
English

References (213)

Oxygen gas diffusion cathode for sodium chloride electrolysis patent March 2011
CO2 Utilization In Electrochemical Systems patent-application September 2010
Manufacture of Dichloropropanol patent-application July 2010
Processes For The Production Of Chlorine From Hydrogen Chloride And Oxygen patent-application February 2008
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application December 2015
Treatment Of Solutions Or Wastewater patent-application December 2011
Halogenation process patent March 1983
CO2 Commodity Trading System And Method patent-application March 2010
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application April 2016
Electron Transfer by Copper Centers journal February 2004
Electrowinning of Copper patent May 1957
Compositions And Methods Using Substances Containing Carbon patent-application April 2010
Systems And Methods For Processing CO2 patent-application November 2011
Indirect cerium medicated electrosynthesis patent March 1994
Electrically controlled ion transport device patent-application January 2008
Electrolytic process for production of gaseous hydrogen chloride and aqueous alkali metal hydroxide patent June 1986
Systems and Methods for Processing CO2 patent-application September 2010
Nickel-Chromium Nanolaminate Coating Having High Hardness patent-application January 2016
Gas Stream Multi-Pollutants Control Systems And Methods patent-application September 2010
Neutralization Of Acid And Production Of Carbonate-Containing Compositions patent-application April 2011
Methods Of Sequestering CO2 patent-application March 2011
CO2-sequestering formed building materials patent August 2011
Process And Apparatus For Vapor Phase Purification During Hydrochlorination Of Multi-Hydroxylated Aliphatic Hydrocarbon Compounds patent-application June 2011
Gas Stream Multi-Pollutants Control Systems And Methods patent-application September 2011
Fuel Cell System patent-application December 2009
Detecting the stoichiometric end point of phosgenation reactions patent March 1989
Electrochemical Systems And Methods Using Metal Halide To Form Products patent-application March 2016
Production Of Carbonate-Containing Compositions From Material Comprising Metal Silicates patent-application December 2009
Electrochemical Production of An Alkaline Solution Using CO2 patent-application April 2010
Desalination Methods And Systems That Include Carbonate Compound Precipitation patent-application June 2010
Utilizing Salts For Carbon Capture And Storage patent-application February 2011
Low-Energy Electrochemical Hydroxide System And Method patent-application September 2010
Preparation Of Olefin Oxide From An Olefin patent January 1972
Halogenation of Ethylene by Contact with Aqueous Cupric-Cuprous Chloride Solution patent August 1969
Methods And Compositions Using Calcium Carbonate patent-application August 2011
Carbon Dioxide Capture and Related Processes patent-application March 2010
Structured Gas Diffusion Electrode For Electrolysis Cells patent-application January 2012
Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine journal November 2005
Selective additions of polyhalogenated compounds to chloro substituted ethenes catalyzed by a copper complex journal August 1991
Methods and compositions using calcium carbonate patent-application March 2011
Cathode for the electrolytic production of hydrogen and its use patent November 1985
Waste water treating method and waste water treating apparatus patent-application August 2003
Oxidation of ferrous ions by ozone in acidic solutions journal August 1992
Method for paired electrochemical synthesis with simultaneous production of ethylene glycol patent August 1990
Hydraulic cements comprising carbonate compound compositions patent-application January 2009
Carbon Capture And Storage patent-application February 2011
Process For Electrolysis Of Alkali Metal Chlorides With Oxygen-Consuming Electrodes Having Orifices patent-application September 2013
Carbonate Products For Carbon Capture And Storage patent-application February 2011
Gas diffusion electrode patent May 2010
Carbon dioxide capture from a cement manufacturing process patent-application December 2010
Methods And Apparatuses For Decreasing The CO2 Concentration Of A Fluid patent-application October 2010
Systems and Methods for Processing CO2 patent-application September 2010
The electrochlorination of aliphatic hydrocarbons journal November 1972
CO2-sequestering formed building materials patent August 2010
Systems and methods for preparation and separation of products patent December 2015
Method of electrolysis employing two-chamber ion exchange membrane electrolytic cell having gas diffusion electrode patent November 2015
Methods And Systems For Treating Industrial Waste Gases patent-application April 2011
Methods of Sequestering CO2 patent-application July 2009
Mechanism of oxidation of cuprous ion in hydrochloric acid solution by oxygen journal May 1970
Electrochemical hydroxide systems and methods using metal oxidation patent November 2015
Non-Cementitious Compositions Comprising CO2 Sequestering Additives patent-application October 2011
Methods and compositions using calcium carbonate patent February 2012
Electrochemical systems and methods using metal and ligand patent November 2015
Systems and Methods for Processing CO2 patent-application October 2011
Method for the electrolysis of an aqueous solution of hydrogen chloride or alkali metal chloride patent February 2010
Ion exchange membrane electrolytic cell patent June 2012
Hydrogen generator and method for the production of hydrogen patent November 2010
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application November 2015
Gas Diffusion Anode and CO2 Cathode Electrolyte System patent-application June 2010
Desalination Methods And Systems That Include Carbonate Compound Precipitation patent-application January 2009
Apparatus and process for electrochemically decomposing salt solutions to form the relevant base and acid patent January 1997
Highly Electrically Conductive Surfaces For Electrochemical Applications And Methods To Produce Same patent-application March 2011
Desalination methods and systems that include carbonate compound precipitation patent June 2010
Laser driver and control circuit patent August 1990
Oxygen gas diffusion cathode, electrolytic cell employing same, method of producing chlorine gas and method of producing sodium hydroxide patent November 2015
Electrogenerative and Voltameiotic Processes
  • Langer, Stanley H.; Sakellaropoulos, George P.
  • Industrial & Engineering Chemistry Process Design and Development, Vol. 18, Issue 4, p. 567-579 https://doi.org/10.1021/i260072a001
journal October 1979
Reduced-Carbon Footprint Concrete Compositions patent-application December 2010
Olefin Chlorination in Homogeneous Aqueous Copper Chloride Solutions
  • Spector, M. L.; Heinemann, Heinz; Miller, K. D.
  • Industrial & Engineering Chemistry Process Design and Development, Vol. 6, Issue 3, p. 327-331 https://doi.org/10.1021/i260023a012
journal July 1967
Soda electrolytic cell provided with gas diffusion electrode patent April 2002
Non-Cementitious Compositions Comprising CO2 Sequestering Additives patent-application May 2010
Methods and compositions using calcium carbonate patent April 2011
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application February 2015
Electrochemical cell for the electrolysis of an alkali metal halide and the production of a halogenated hydrocarbon patent May 1989
Bipolar system electrolytic cell patent September 1978
Process for Separating Olefins from Admixtures with High Porosity Cuprous Halide Salts patent April 1969
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application December 2014
Low energy electrochemical hydroxide system and method patent September 2010
Reduced-Carbon Footprint Concrete Compositions patent-application April 2010
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application February 2016
Methods of Sequestering CO2 patent-application June 2010
Monopolar and bipolar electrolyzer and electrodic structures thereof patent August 1988
Compositions and methods using substances containing carbon patent May 2011
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application August 2013
Process For Converting Hydrocarbon Feedstocks With Electrolytic And Photoelectrocatalytic Recovery Of Halogens patent-application October 2010
Low-Voltage Alkaline Production Using Hydrogen And Electrocatalytic Electrodes patent-application April 2011
Electrolytic cell employing gas diffusion electrode patent September 2000
Electrogenerative Chlorination journal January 1970
Rocks And Aggregate, And Methods Of Making And Using The Same patent-application February 2010
Production of Carbonate-Containing Compositions from Material Comprising Metal Silicates patent-application December 2010
Process And Apparatus For Efficient Recovery Of Dichlorohydrins patent-application February 2011
Process for the combined manufacture of chlorinated hydrocarbons and sodium bicarbonate patent March 1981
Redox potential characteristics of cupric chloride solutions journal February 2009
Copper(II) PMDTA and copper(II) TMEDA complexes: precursors for the synthesis of dinuclear dicationic copper(II) complexes journal March 2005
Process for removing chalcophile elements from aqueous solutions by electrolysis patent February 1980
Systems and methods for separation and purification of products patent November 2017
Electrochemical production of an alkaline solution using CO2 patent August 2011
Utilizing Salts For Carbon Capture And Storage patent-application February 2011
CO2 commodity trading system and method patent June 2011
Process for producing sodium bicarbonate for flue gas desulphurization patent-application November 2010
Low Energy 4-Cell Electrochemical System with Carbon Dioxide Gas patent-application May 2010
Process for the Halogenation of Hydrocarbons patent October 1965
Industrial wastewater treatment and metals recovery apparatus patent-application December 2004
Process for the Halogenation of Hydrocarbons patent October 1965
Low-Voltage Alkaline Production From Brines patent-application August 2010
Electrolysis Cell For Hydrogen Chloride Electrolysis patent-application January 2011
Electrolysis Cell for the Conversion of Cuprous Chloride in Hydrochloric Acid to Cupric Chloride and Hydrogen Gas patent-application March 2010
Gas diffusion anode and CO2 cathode electrolyte system patent August 2011
Electrical heating reactor for gas phase reforming patent-application June 2006
Rocks and aggregate, and methods of making and using the same patent July 2010
Mass transport in an electrochemical laboratory filterpress reactor and its enhancement by turbulence promoters journal March 1996
Rocks and Aggregate, And Methods Of Making And Using The Same patent-application September 2010
Desalination Methods And Systems That Include Carbonate Compound Precipitation patent-application June 2010
Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons patent August 1999
Gas diffusion composite electrode having novel hydrophilic layer patent April 1986
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application November 2012
Capture and Sequestration of Carbon Dioxide in Flue Gases patent-application August 2009
Multi-cell electrolyzer patent February 1987
Electrolytic cell and processes for producing alkali hydroxide and hydrogen peroxide patent August 1995
Electrochemical Hydroxide Systems and Methods Using Metal Oxidation patent-application November 2012
The electrochemistry of nickel complexes with triphenylphosphine and ethylene in methylpyrrolidinone journal February 1985
Alkaline electrochemical cell patent-application December 2007
Non-Cementitious Compositions Comprising CO2 Sequestering Additives patent-application September 2010
Low Energy Electrochemical Hydroxide System and Method patent-application June 2010
Methods and compositions using calcium carbonate patent-application March 2011
Method for reducing charge in gas diffusing electrode and its charge reducing structure patent April 2002
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application March 2016
Low-Energy Electrochemical Bicarbonate Ion Solution patent-application February 2011
Gas diffusion electrode assembly, bonding method for gas diffusion electrodes, and electrolyzer comprising gas diffusion electrodes patent August 2009
Mobile vapor recovery and vapor scavenging unit patent September 1991
Hydraulic Cements Comprising Carbonate Compound Compositions patent-application June 2011
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application August 2016
Methods of sequestering CO2 patent February 2011
Reduced-carbon footprint concrete compositions patent October 2010
Process for the production of vinyl acetate from ethylene patent October 1976
Desalination methods and systems that include carbonate compound precipitation patent April 2011
Diaphragm cell patent May 2002
Process And Apparatus For Production Of Vinyl Chloride Monomer patent-application February 2010
Methods and systems for utilizing waste sources of metal oxides patent July 2010
Two-layer corrugated electrode patent March 1982
Production of ethylene dichloride by direct chlorination and production of vinyl chloride monomer using chlorine recycle and apparatus patent April 1999
CO2-Sequestering Formed Building Materials patent-application April 2010
High Pressure Electrolysis Cell For Hydrogen Production From Water patent-application November 2010
Hydraulic cements comprising carbonate compound compositions patent June 2010
Continuous Co-Current Electrochemical Reduction of Carbon Dioxide patent-application September 2008
Complexation of metal ions in brines: application of electronic spectroscopy in the study of the Cu(II)-LiCl-H2O system between 25 and 90°C journal August 2001
Method for producing hydrogen chloride or an aqueous solution thereof using untreated salt water, thus produced product, use of the product and electrodialysis system patent August 2015
Process for preparing olefin oxides in an electrochemical cell patent February 1988
Methods of Sequestering CO2 patent-application June 2010
Systems and Methods for Processing CO2 patent-application September 2010
Method of Preparing Halogen-Substituted Aliphatic Hydrocarbons patent February 1963
Electrolytic cell using gas diffusion electrode and power distribution method for the electrolytic cell patent May 2002
Methods and Systems for Utilization of HCI patent-application March 2011
Method for the production of 1,2-dichloroethane patent-application December 2004
Halogenation of an Acyclic Olefin patent May 1970
Low energy 4-cell electrochemical system with carbon dioxide gas patent January 2011
Alkaline Production Using A Gas Diffusion Anode With A Hydrostatic Pressure patent-application April 2011
Electrochemical Hydroxide Systems And Methods Using Metal Oxidation patent-application March 2017
Process for electrolysis of alkali metal chlorides with oxygen-consuming electrodes patent March 2016
Gas-Phase Hydrotreating Of Middle-Distillates Hydrocarbon Feedstocks patent-application February 2010
Compositions And Methods Using Substances Containing Carbon patent-application October 2010
Acid Separation By Acid Retardation On An Ion Exchange Resin In An Electrochemical System patent-application June 2011
Hydraulic Cements Comprising Carbonate Compound Compositions patent-application June 2010
A study of oxygen absorption kinetics in ionic Cu(I) aqueous solutions journal February 1996
Effective adsorption of cationic dye from aqueous solution using low-cost corncob in batch and column studies journal June 2016
Methods And Systems For Utilizing Waste Sources Of Metal Oxides patent-application January 2010
Hydraulic cements comprising carbonate compound compositions patent-application March 2011
Rocks and aggregate, and methods of making and using the same patent March 2011
Methods And Systems Using Natural Gas Power Plant patent-application November 2011
Oxidative Halogenation of C1 Hydrocarbons to Halogenated C1 Hydrocarbons patent-application November 2008
Electrochemical Methods of Sequestering CO2 patent-application June 2010
Process for preparing alkanediols by electrochemical coupling of halohydrins patent April 1982
Solid polymer battery electrolyte and reactive metal-water battery patent November 2000
Methods and compositions using calcium carbonate patent November 2011
Hydraulic cements comprising carbonate compound compositions patent March 2011
Methods and compositions using calcium carbonate patent March 2012
Cathode Arrangements for Fuel Cells and Other Applications patent-application January 2009
Process for making 1,2-dichloroethane patent June 1987
Gas diffusion electrode assembly, bonding method for gas diffusion electrodes, and electrolyzer comprising gas diffusion electrodes patent July 2008
Hydrochloric acid electrolytic cell for the preparation of chlorine and hydrogen patent September 1983
Gas diffusion electrode equipped ion exchange membrane electrolyzer patent January 2015
Membrane Electrode Assembly With Hydrogenatable Material For A Fuel Cell patent-application April 2009
CO2 Sequestering Soil Stabilization Composition patent-application August 2010
Mass-Transfer Study of Carbon Felt, Flow-Through Electrode journal January 1982
Kinetics of absorption of oxygen in aqueous solutions of cuprous chloride journal January 1967
Electrochemical process for the preparation of benzanthrones and planar, polycyclic aromatic oxygen-containing compounds patent July 1983
Chemical speciation of environmentally significant metals with inorganic ligands Part 2: The Cu2+-OH-, Cl-, CO32-, SO42-, and PO43- systems (IUPAC Technical Report) journal January 2009
Modelling of copper etching in aerated chloride solutions journal January 1997
Process For Purification Of Ethylene Dichloride patent September 1972
Production of carbonate-containing compositions from material comprising metal silicates patent July 2010
Non-cementitious compositions comprising CO2 sequestering additives patent November 2010
CO2-Sequestering Formed Building Materials patent-application December 2010
Low-Energy Electrochemical Proton Transfer System And Method patent-application February 2011
Method For Electrochemical Modification Of Liquid Streams patent-application May 2011
Processing CO2 Utilizing A Recirculating Solution patent-application June 2010
Electrolytic cell bank having spring loaded intercell connectors patent August 1978
A spectrophotometric study of aqueous copper(I)–chloride complexes in LiCl solutions between 100 °C and 250 °C journal October 2002
Lens barrel and image pickup apparatus patent April 2011
Methods And Systems For Utilizing Waste Sources Of Metal Oxides patent-application September 2010
Integrated Desulfurization And Denitrification Process Including Mild Hydrotreating Of Aromatic-Lean Fraction And Oxidation Of Aromatic-Rich Fraction patent-application June 2012
Liquid-Phase Oxychlorination of Ethylene To Produce Vinyl Chloride book June 1974
Rocks and Aggregate, and Methods of Making and Using the Same patent-application June 2010
Methods and compositions using calcium carbonate patent-application March 2011
Elastic Current Collector For Electrochemical Cells patent-application May 2010