Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Systems and methods for preparation and separation of products

Patent ·
OSTI ID:1439331
There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.
Research Organization:
Calera Corporation, Moss Landing, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0002472
Assignee:
Calera Corporation (Moss Landing, CA)
Patent Number(s):
9,957,623
OSTI ID:
1439331
Country of Publication:
United States
Language:
English

References (22)

Olefin Chlorination in Homogeneous Aqueous Copper Chloride Solutions
  • Spector, M. L.; Heinemann, Heinz; Miller, K. D.
  • Industrial & Engineering Chemistry Process Design and Development, Vol. 6, Issue 3, p. 327-331 https://doi.org/10.1021/i260023a012
journal July 1967
Redox potential characteristics of cupric chloride solutions journal February 2009
Modelling of copper etching in aerated chloride solutions journal January 1997
A spectrophotometric study of aqueous copper(I)–chloride complexes in LiCl solutions between 100 °C and 250 °C journal October 2002
Complexation of metal ions in brines: application of electronic spectroscopy in the study of the Cu(II)-LiCl-H2O system between 25 and 90°C journal August 2001
Selective additions of polyhalogenated compounds to chloro substituted ethenes catalyzed by a copper complex journal August 1991
Copper(II) PMDTA and copper(II) TMEDA complexes: precursors for the synthesis of dinuclear dicationic copper(II) complexes journal March 2005
Effective adsorption of cationic dye from aqueous solution using low-cost corncob in batch and column studies journal June 2016
Chemical speciation of environmentally significant metals with inorganic ligands Part 2: The Cu2+-OH-, Cl-, CO32-, SO42-, and PO43- systems (IUPAC Technical Report) journal January 2009
Mechanism of oxidation of cuprous ion in hydrochloric acid solution by oxygen journal May 1970
Oxidation of ferrous ions by ozone in acidic solutions journal August 1992
Liquid-Phase Oxychlorination of Ethylene To Produce Vinyl Chloride book June 1974
Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine journal November 2005
Kinetics of absorption of oxygen in aqueous solutions of cuprous chloride journal January 1967
Electron Transfer by Copper Centers journal February 2004
Electrogenerative and Voltameiotic Processes
  • Langer, Stanley H.; Sakellaropoulos, George P.
  • Industrial & Engineering Chemistry Process Design and Development, Vol. 18, Issue 4, p. 567-579 https://doi.org/10.1021/i260072a001
journal October 1979
Electrogenerative Chlorination journal January 1970
The electrochemistry of nickel complexes with triphenylphosphine and ethylene in methylpyrrolidinone journal February 1985
A study of oxygen absorption kinetics in ionic Cu(I) aqueous solutions journal February 1996
The electrochlorination of aliphatic hydrocarbons journal November 1972
Mass transport in an electrochemical laboratory filterpress reactor and its enhancement by turbulence promoters journal March 1996
Mass-Transfer Study of Carbon Felt, Flow-Through Electrode journal January 1982

Related Subjects