skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Large resistance change on magnetic tunnel junction based molecular spintronics devices

Journal Article · · Journal of Magnetism and Magnetic Materials
ORCiD logo [1];  [2]
  1. Univ. of the District of Columbia, Washington, D.C. (United States); Univ. of Kentucky, Lexington, KY (United States)
  2. Univ. of the District of Columbia, Washington, D.C. (United States)

Here, molecular bridges covalently bonded to two ferromagnetic electrodes can transform ferromagnetic materials and produce intriguing spin transport characteristics. This paper discusses the impact of molecule induced strong coupling on the spin transport. To study molecular coupling effect the octametallic molecular cluster (OMC) was bridged between two ferromagnetic electrodes of a magnetic tunnel junction (Ta/Co/NiFe/AlOx/NiFe/Ta) along the exposed side edges. OMCs induced strong inter-ferromagnetic electrode coupling to yield drastic changes in transport properties of the magnetic tunnel junction testbed at the room temperature. These OMCs also transformed the magnetic properties of magnetic tunnel junctions. SQUID and ferromagnetic resonance studies provided insightful data to explain transport studies on the magnetic tunnel junction based molecular spintronics devices.

Research Organization:
Univ. of the District of Columbia, Washington, D.C. (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation
Grant/Contract Number:
NA0002687
OSTI ID:
1439170
Journal Information:
Journal of Magnetism and Magnetic Materials, Vol. 453, Issue C; ISSN 0304-8853
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 22 works
Citation information provided by
Web of Science

References (35)

Molecular spintronics using single-molecule magnets journal March 2008
The Kondo Effect in the Presence of Ferromagnetism journal October 2004
Spin-Dependent Transport in Molecular Tunnel Junctions journal September 2004
Vibration-Assisted Electron Tunneling in C 140 Transistors journal February 2005
Multilayer edge molecular electronics devices: a review journal January 2011
Electron Transport through Single Mn 12 Molecular Magnets journal May 2006
Paramagnetic molecule induced strong antiferromagnetic exchange coupling on a magnetic tunnel junction based molecular spintronics device journal July 2015
Thioester-functionalised and oxime-based hexametallic manganese( iii ) single-molecule magnets journal January 2017
Porphyrins as molecular electronic components of functional devices journal October 2010
DNA spintronics journal July 2002
An S = 6 Cyanide-Bridged Octanuclear Fe III 4 Ni II 4 Complex that Exhibits Slow Relaxation of the Magnetization journal April 2006
Molecular Electrodes at the Exposed Edge of Metal/Insulator/Metal Trilayer Structures journal April 2007
Fabrication of tunnel junction-based molecular electronics and spintronics devices journal September 2012
Addressing the challenges of using ferromagnetic electrodes in the magnetic tunnel junction-based molecular spintronics devices journal November 2015
C60/NiFe combination as a promising platform for molecular spintronics journal March 2012
Permanent Magnetism, Magnetic Anisotropy, and Hysteresis of Thiol-Capped Gold Nanoparticles journal August 2004
1-Dodecanethiol Self-Assembled Monolayers on Cobalt journal December 2011
Activating the molecular spinterface journal April 2017
Tunneling path toward spintronics journal February 2011
Ferromagnetic resonance in coupled ultrathin films journal February 2003
Ferromagnetic resonance in a coupled two-layer system journal November 1990
Tunneling Conductance of Asymmetrical Barriers journal April 1970
Making electrical contacts to molecular monolayers journal October 2001
Interlayer exchange coupling and magnetic anisotropy in prototype trilayers: Ab initio theory versus experiment journal September 2003
Why are spin wave excitations all important in nanoscale magnetism? journal January 2008
Giant tunnel magnetoresistance in magnetic tunnel junctions with a crystalline MgO(0 0 1) barrier journal October 2007
Spin-Polarized Current in Spin Valves and Magnetic Tunnel Junctions journal May 2006
FeCoCp 3 Molecular Magnets as Spin Filters journal May 2015
Ancillary Ligand Functionalization of Cyanide-Bridged S = 6 Fe III 4 Ni II 4 Complexes for Molecule-Based Electronics journal September 2006
Change of cobalt magnetic anisotropy and spin polarization with alkanethiolates self-assembled monolayers journal June 2015
The Rise of Single-Ion Magnets as Spin Qubits journal November 2016
Quantum computing in molecular magnets journal April 2001
Molecular spintronics and quantum computing journal January 2009
Single molecule magnets for quantum computation journal May 2007
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆ journal May 2017

Cited By (1)

Molecular spintronics devices exhibiting properties of a solar cell journal September 2019

Figures / Tables (5)