Fe Stabilization by Intermetallic L1 0 -FePt and Pt Catalysis Enhancement in L1 0 -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells

Li, Junrui; Xi, Zheng; Pan, Yung-Tin; Spendelow, Jacob S.; Duchesne, Paul N.; Su, Dong; Li, Qing; Yu, Chao; Yin, Zhouyang; Shen, Bo; Kim, Yu Seung; Zhang, Peng; Sun, Shouheng

doi:10.1021/jacs.7b12829

Fe Stabilization by Intermetallic L1 ₀ -FePt and Pt Catalysis Enhancement in L1 ₀ -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells

Journal Article · 07 February 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b12829· OSTI ID:1438844

^[1]; ^[1]; Pan, Yung-Tin ^[2]; Spendelow, Jacob S. ^[2]; Duchesne, Paul N. ^[3]; ^[4]; ^[5]; ^[1]; Yin, Zhouyang ^[1]; ^[1]; ^[2]; ^[3]; ^[1]

Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States
Materials Physics and Application Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4R2, Canada
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States
School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, P. R. China

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) Scientific User Facilities Division; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; Canadian Light Sources, Inc., Saskatoon, SK (Canada); National Natural Science Foundation of China (NSFC); Materials Genome Initiative

DOE Contract Number:: SC0012704; AC52-06NA25396; AC02-06CH11357; 21603078; 2016YFB0700600

OSTI ID:: 1438844

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 8; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

References (25)

Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation Borup, Rod; Meyers, Jeremy; Pivovar, Bryan Chemical Reviews, Vol. 107, Issue 10 https://doi.org/10.1021/cr050182l	journal	October 2007
Toward sustainable fuel cells Stephens, Ifan Erfyl Lester; Rossmeisl, Jan; Chorkendorff, Ib Science, Vol. 354, Issue 6318 https://doi.org/10.1126/science.aal3303	journal	December 2016
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias Nature Materials, Vol. 6, Issue 3, p. 241-247 https://doi.org/10.1038/nmat1840	journal	February 2007
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces Chen, C.; Kang, Y.; Huo, Z. Science, Vol. 343, Issue 6177 https://doi.org/10.1126/science.1249061	journal	February 2014
High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction Huang, X.; Zhao, Z.; Cao, L. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa8765	journal	June 2015
Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction Li, Mufan; Zhao, Zipeng; Cheng, Tao Science, Vol. 354, Issue 6318 https://doi.org/10.1126/science.aaf9050	journal	November 2016
Core/Shell Face-Centered Tetragonal FePd/Pd Nanoparticles as an Efficient Non-Pt Catalyst for the Oxygen Reduction Reaction Jiang, Guangming; Zhu, Huiyuan; Zhang, Xu ACS Nano, Vol. 9, Issue 11 https://doi.org/10.1021/acsnano.5b04361	journal	October 2015
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts Wang, Deli; Xin, Huolin L.; Hovden, Robert Nature Materials, Vol. 12, Issue 1, p. 81-87 https://doi.org/10.1038/nmat3458	journal	October 2012
Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles Zhang, Sen; Guo, Shaojun; Zhu, Huiyuan Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja300708j	journal	March 2012
New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid Li, Qing; Wu, Liheng; Wu, Gang Nano Letters, Vol. 15, Issue 4 https://doi.org/10.1021/acs.nanolett.5b00320	journal	March 2015
WinXAS a Program for X-ray Absorption Spectroscopy Data Analysis under MS-Windows Ressler, T. Journal of Synchrotron Radiation, Vol. 5, Issue 2, p. 118-122 https://doi.org/10.1107/S0909049597019298	journal	March 1998
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure Ankudinov, A. L.; Ravel, B.; Rehr, J. J. Physical Review B, Vol. 58, Issue 12 https://doi.org/10.1103/PhysRevB.58.7565	journal	September 1998
Local Structure, Electronic Behavior, and Electrocatalytic Reactivity of CO-Reduced Platinum–Iron Oxide Nanoparticles Duchesne, Paul N.; Chen, Guangxu; Zheng, Nanfeng The Journal of Physical Chemistry C, Vol. 117, Issue 49 https://doi.org/10.1021/jp4093496	journal	November 2013
Reversibility of Pt-Skin and Pt-Skeleton Nanostructures in Acidic Media Durst, Julien; Lopez-Haro, Miguel; Dubau, Laetitia The Journal of Physical Chemistry Letters, Vol. 5, Issue 3 https://doi.org/10.1021/jz4025707	journal	January 2014
Role of Crystalline Defects in Electrocatalysis: CO Adsorption and Oxidation on Stepped Platinum Electrodes As Studied by in situ Infrared Spectroscopy Lebedeva, N. P.; Rodes, A.; Feliu, J. M. The Journal of Physical Chemistry B, Vol. 106, Issue 38 https://doi.org/10.1021/jp0203806	journal	September 2002
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
Fast Prediction of Adsorption Properties for Platinum Nanocatalysts with Generalized Coordination Numbers Calle-Vallejo, Federico; Martínez, José I.; García-Lastra, Juan M. Angewandte Chemie International Edition, Vol. 53, Issue 32 https://doi.org/10.1002/anie.201402958	journal	June 2014
Atomic-Scale Modeling of Particle Size Effects for the Oxygen Reduction Reaction on Pt Tritsaris, G. A.; Greeley, J.; Rossmeisl, J. Catalysis Letters, Vol. 141, Issue 7 https://doi.org/10.1007/s10562-011-0637-8	journal	June 2011
Size-Dependent Chemical and Magnetic Ordering inL10-FePt Nanoparticles Rong, C. -b.; Li, D.; Nandwana, V. Advanced Materials, Vol. 18, Issue 22 https://doi.org/10.1002/adma.200601904	journal	November 2006
Proton exchange membrane fuel cell from low temperature to high temperature: Material challenges Shao, Yuyan; Yin, Geping; Wang, Zhenbo Journal of Power Sources, Vol. 167, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.02.065	journal	May 2007
Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells Han, Binghong; Carlton, Christopher E.; Kongkanand, Anusorn Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE02144D	journal	January 2015
Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction Chung, Dong Young; Jun, Samuel Woojoo; Yoon, Gabin Journal of the American Chemical Society, Vol. 137, Issue 49 https://doi.org/10.1021/jacs.5b09653	journal	December 2015
Fine-grained and fully ordered intermetallic PtFe catalysts with largely enhanced catalytic activity and durability Du, Xin Xin; He, Yang; Wang, Xiao Xia Energy & Environmental Science, Vol. 9, Issue 8 https://doi.org/10.1039/C6EE01204C	journal	January 2016
Highly durable fuel cell electrodes based on ionomers dispersed in glycerol Kim, Y. S.; Welch, C. F.; Mack, N. H. Phys. Chem. Chem. Phys., Vol. 16, Issue 13 https://doi.org/10.1039/C4CP00496E	journal	January 2014

Cited By (42)

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong Science, Vol. 366, Issue 6467 https://doi.org/10.1126/science.aaw7493	journal	November 2019
Pt‐Based Nanocrystal for Electrocatalytic Oxygen Reduction Zhao, Zipeng; Chen, Changli; Liu, Zeyan Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201808115	journal	December 2018
Superior Magnetic Performance in FePt L1 ₀ Nanomaterials Son, Kwanghyo; Ryu, Gihun; Jeong, Hyeon‐Ho Small, Vol. 15, Issue 34 https://doi.org/10.1002/smll.201902353	journal	July 2019
Leaching- and sintering-resistant hollow or structurally ordered intermetallic PtFe alloy catalysts for oxygen reduction reactions Zou, Xiao; Chen, Siguo; Wang, Qingmei Nanoscale, Vol. 11, Issue 42 https://doi.org/10.1039/c9nr06698e	journal	January 2019
Role of Ultrathin Carbon Shell in Enhancing the Performance of PtZn Intermetallic Nanoparticles as an Anode Electrocatalyst for Direct Formic Acid Fuel Cells Xu, Min; Zhao, Yufei; Chen, Hong ChemElectroChem, Vol. 6, Issue 8 https://doi.org/10.1002/celc.201900332	journal	April 2019
All-metallic nanorattles consisting of a Pt core and a mesoporous PtPd shell for enhanced electrocatalysis Wang, Hongjing; Yin, Shuli; Li, Chunjie Nanotechnology, Vol. 30, Issue 47 https://doi.org/10.1088/1361-6528/ab3c94	journal	September 2019
Highly stable one-dimensional Pt nanowires with modulated structural disorder towards the oxygen reduction reaction Kong, Fanpeng; Norouzi Banis, Mohammad; Du, Lei Journal of Materials Chemistry A, Vol. 7, Issue 43 https://doi.org/10.1039/c9ta08120h	journal	January 2019
High‐Performance Platinum‐Perovskite Composite Bifunctional Oxygen Electrocatalyst for Rechargeable Zn–Air Battery Wang, Xixi; Sunarso, Jaka; Lu, Qian Advanced Energy Materials, Vol. 10, Issue 5 https://doi.org/10.1002/aenm.201903271	journal	December 2019
Unusual strain effect of a Pt-based L1 ₀ face-centered tetragonal core in core/shell nanoparticles for the oxygen reduction reaction Liu, Mingjie; Xin, Huolin; Wu, Qin Physical Chemistry Chemical Physics, Vol. 21, Issue 12 https://doi.org/10.1039/c8cp06756b	journal	January 2019
Ultralong Ternary PtRuTe Mesoporous Nanotubes Fabricated by Micelle Assembly with a Self‐Sacrificial Template Yin, Shuli; Wang, Hongjing; Deng, Kai Chemistry – A European Journal, Vol. 25, Issue 20 https://doi.org/10.1002/chem.201806382	journal	March 2019
Ligand‐Sharing‐Mediated Synthesis of Intermetallic FeM Clusters Embedded in Ultrathin γ‐Fe ₂ O ₃ Nanosheets Liu, Rui; Chen, Yanan; Zhao, Huachao Advanced Functional Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adfm.201906995	journal	November 2019
High‐Performance Ordered PdCuFe/C Intermetallic Catalyst for Electrochemical Oxygen Reduction in Proton Exchange Membrane Fuel Cells Ji, Xiangdong; Gao, Peng; Zhang, Libo ChemElectroChem, Vol. 6, Issue 12 https://doi.org/10.1002/celc.201900390	journal	May 2019
Monodisperse nanoparticles for catalysis and nanomedicine Muzzio, Michelle; Li, Junrui; Yin, Zhouyang Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr06080d	journal	January 2019
Hollow PtFe Alloy Nanoparticles Derived from Pt‐Fe ₃ O ₄ Dimers through a Silica‐Protection Reduction Strategy as Efficient Oxygen Reduction Electrocatalysts Yang, Zhaojun; Shang, Lu; Xiong, Xuyang Chemistry – A European Journal https://doi.org/10.1002/chem.201904208	journal	January 2020
Porous graphene doped with Fe/N/S and incorporating Fe ₃ O ₄ nanoparticles for efficient oxygen reduction Li, Yi; Zhou, Yazhou; Zhu, Chengzhou Catalysis Science & Technology, Vol. 8, Issue 20 https://doi.org/10.1039/c8cy01328d	journal	January 2018
Optimizing PtFe intermetallics for oxygen reduction reaction: from DFT screening to in situ XAFS characterization Gong, Mingxing; Zhu, Jing; Liu, Mingjie Nanoscale, Vol. 11, Issue 42 https://doi.org/10.1039/c9nr04975d	journal	January 2019
Recent Advances and Prospects of Metal‐Based Catalysts for Oxygen Reduction Reaction Lang, Peng; Yuan, Nannan; Jiang, Qianqian Energy Technology, Vol. 8, Issue 3 https://doi.org/10.1002/ente.201900984	journal	December 2019
Structurally Ordered Low‐Pt Intermetallic Electrocatalysts toward Durably High Oxygen Reduction Reaction Activity Wang, Zhongxiang; Yao, Xiaozhang; Kang, Yongqiang Advanced Functional Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adfm.201902987	journal	July 2019
Chemical Synthesis of Magnetically Hard and Strong Rare Earth Metal Based Nanomagnets Shen, Bo; Yu, Chao; Baker, Alexander A. Angewandte Chemie, Vol. 131, Issue 2 https://doi.org/10.1002/ange.201812007	journal	December 2018
PDA-assisted formation of ordered intermetallic CoPt ₃ catalysts with enhanced oxygen reduction activity and stability Zhao, Yige; Wang, Chen; Liu, Jingjun Nanoscale, Vol. 10, Issue 19 https://doi.org/10.1039/c8nr02207k	journal	January 2018
Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro-oxidation of Liquid Fuels Li, Junrui; Jilani, Safia Z.; Lin, Honghong Angewandte Chemie International Edition, Vol. 58, Issue 33 https://doi.org/10.1002/anie.201906137	journal	July 2019
Structurally Ordered Fe ₃ Pt Nanoparticles on Robust Nitride Support as a High Performance Catalyst for the Oxygen Reduction Reaction Liu, Quanbing; Du, Li; Fu, Gengtao Advanced Energy Materials, Vol. 9, Issue 3 https://doi.org/10.1002/aenm.201803040	journal	December 2018
Tungsten‐Doped L1 ₀ ‐PtCo Ultrasmall Nanoparticles as a High‐Performance Fuel Cell Cathode Liang, Jiashun; Li, Na; Zhao, Zhonglong Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201908824	journal	September 2019
Facile synthesis of PdFe alloy tetrahedrons for boosting electrocatalytic properties towards formic acid oxidation Cai, Bingfeng; Ma, Yanrong; Wang, Shangzhi Nanoscale, Vol. 11, Issue 39 https://doi.org/10.1039/c9nr06344g	journal	January 2019
Spherical α-MnO2 Supported on N-KB as Efficient Electrocatalyst for Oxygen Reduction in Al–Air Battery Chen, Kui; Wang, Mei; Li, Guangli Materials, Vol. 11, Issue 4 https://doi.org/10.3390/ma11040601	journal	April 2018
Invigorating the catalytic performance of CoP through interfacial engineering by Ni ₂ P precipitation Zhang, Junyu; Wei, Sufeng; Liu, Yan Journal of Materials Chemistry A, Vol. 7, Issue 45 https://doi.org/10.1039/c9ta10498d	journal	January 2019
Chemical Synthesis of Magnetic Nanoparticles for Permanent Magnet Applications Shen, Bo; Sun, Shouheng Chemistry – A European Journal, Vol. 26, Issue 30 https://doi.org/10.1002/chem.201902916	journal	October 2019
Fabrication of Superior Single‐Atom Catalysts toward Diverse Electrochemical Reactions Zhang, Bin‐Wei; Wang, Yun‐Xiao; Chou, Shu‐Lei Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201800497	journal	February 2019
Sub‐6 nm Fully Ordered L 1 ₀ ‐Pt–Ni–Co Nanoparticles Enhance Oxygen Reduction via Co Doping Induced Ferromagnetism Enhancement and Optimized Surface Strain Wang, Tanyuan; Liang, Jiashun; Zhao, Zhonglong Advanced Energy Materials, Vol. 9, Issue 17 https://doi.org/10.1002/aenm.201803771	journal	March 2019
Highly active zigzag-like Pt-Zn alloy nanowires with high-index facets for alcohol electrooxidation Xu, Yanchao; Cui, Xiaoqiang; Wei, Shuting Nano Research, Vol. 12, Issue 5 https://doi.org/10.1007/s12274-019-2374-z	journal	April 2019
Regulating locations of active sites: a novel strategy to greatly improve the stability of PtAu electrocatalysts Xu, Suying; Hou, Wenjie; Jiang, Rui Chemical Communications, Vol. 55, Issue 90 https://doi.org/10.1039/c9cc07275f	journal	January 2019
Tunable synthesis of multiply twinned intermetallic Pd ₃ Pb nanowire networks toward efficient N ₂ to NH ₃ conversion Guo, Jingchun; Wang, Hui; Xue, Fei Journal of Materials Chemistry A, Vol. 7, Issue 35 https://doi.org/10.1039/c9ta07519d	journal	January 2019
Atomically ordered non-precious Co3Ta intermetallic nanoparticles as high-performance catalysts for hydrazine electrooxidation Feng, Guang; An, Li; Li, Biao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12509-7	journal	October 2019
Pt-rare earth metal alloy/metal oxide catalysts for oxygen reduction and alcohol oxidation reactions: an overview Peera, Shaik Gouse; Lee, Tae Gwan; Sahu, Akhila Kumar Sustainable Energy & Fuels, Vol. 3, Issue 8 https://doi.org/10.1039/c9se00082h	journal	January 2019
Sub‐3 nm Intermetallic Ordered Pt ₃ In Clusters for Oxygen Reduction Reaction Wang, Qi; Zhao, Zhi Liang; Zhang, Zhe Advanced Science, Vol. 7, Issue 2 https://doi.org/10.1002/advs.201901279	journal	November 2019
High temperature self-assembly one-step synthesis of a structurally ordered PtFe catalyst for the oxygen reduction reaction Gao, Xiaoyan; Chen, Siguo; Deng, Jianghai Chemical Communications, Vol. 55, Issue 80 https://doi.org/10.1039/c9cc05714e	journal	January 2019
The application of CeO 2 -based materials in electrocatalysis Wang, Jianda; Xiao, Xiao; Liu, Yong Journal of Materials Chemistry A, Vol. 7, Issue 30 https://doi.org/10.1039/c9ta04804a	journal	January 2019
Chemical Synthesis of Magnetically Hard and Strong Rare Earth Metal Based Nanomagnets Shen, Bo; Yu, Chao; Baker, Alexander A. Angewandte Chemie International Edition, Vol. 58, Issue 2 https://doi.org/10.1002/anie.201812007	journal	December 2018
Core-Shell Polydopamine@Zr-Hemin MOFs Derived Fe-N-Doped Porous Carbon Nanospheres Electrocatalysts for the Oxygen Reduction Wang, Yinling; Wang, Juan; Zhang, Youliang Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1101810jes	journal	January 2018
Tungsten‐Doped L1 ₀ ‐PtCo Ultrasmall Nanoparticles as a High‐Performance Fuel Cell Cathode Liang, Jiashun; Li, Na; Zhao, Zhonglong Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201908824	journal	October 2019
Direct fabrication of bimetallic AuPt nanobrick spherical nanoarchitectonics for the oxygen reduction reaction Narendra Kumar, Alam Venugopal; Yin, Shuli; Wang, Ziqiang New Journal of Chemistry, Vol. 43, Issue 24 https://doi.org/10.1039/c9nj01983a	journal	January 2019
Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels Li, Junrui; Jilani, Safia Z.; Lin, Honghong Angewandte Chemie, Vol. 131, Issue 33 https://doi.org/10.1002/ange.201906137	journal	July 2019

Similar Records

Fe Stabilization by Intermetallic L1₀-FePt and Pt Catalysis Enhancement in L1₀-FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells

Journal Article · 2018 · Journal of the American Chemical Society · OSTI ID:1438309

Li, Junrui; Xi, Zheng; Pan, Yung -Tin; +10 more

Hard-Magnet L1₀-CoPt Nanoparticles Advance Fuel Cell Catalysis

Journal Article · 2018 · Joule · OSTI ID:1591934

Li, Junrui; Sharma, Shubham; Liu, Xiaoming; +17 more

Fe Stabilization by Intermetallic L1 0 -FePt and Pt Catalysis Enhancement in L1 0 -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells

Citation Formats

References (25)

Cited By (42)

Similar Records

Related Subjects

Fe Stabilization by Intermetallic L1 ₀ -FePt and Pt Catalysis Enhancement in L1 ₀ -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells