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Title: A novel coronene//Na2Ti3O7 dual-ion battery

Journal Article · · Nano Energy
 [1];  [2];  [2];  [2];  [3];  [4];  [2]
  1. Nanjing Univ. of Aeronautics and Astronautics, Nanjing (People's Republic of China); Oregon State Univ., Corvallis, OR (United States)
  2. Oregon State Univ., Corvallis, OR (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Nanjing Univ. of Aeronautics and Astronautics, Nanjing (People's Republic of China)
+ Show Author Affiliations

Here we construct a novel sodium dual-ion battery (Na-DIB) with a conventional alkyl/alkylene carbonate electrolyte by using reduced-graphene-oxide-coated Na2Ti3O7 (NTO@G) as the anode and coronene, a polycyclic aromatic hydrocarbon (PAH), as the cathode. The coronene//NTO@G configuration delivers a specific energy of 77 W h kg-1, based on the total active mass in both electrodes, and excellent cycling stability with 80% capacity retention after 5000 cycles. In addition, this device can work well in a wide range of temperatures from -20 to 40 °C. Furthermore, the results demonstrate a proof-of-concept Na-DIB that avoids the challenges of conventional dual-graphite DIBs by utilizing non-graphite intercalation anode and cathode, and a carbonate-based electrolyte without any additives.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1438485
Alternate ID(s):
OSTI ID: 1496451
Journal Information:
Nano Energy, Vol. 40, Issue C; ISSN 2211-2855
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 79 works
Citation information provided by
Web of Science

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Cited By (14)

Germanium-based high-performance dual-ion batteries journal January 2020
Ti‐Based Oxide Anode Materials for Advanced Electrochemical Energy Storage: Lithium/Sodium Ion Batteries and Hybrid Pseudocapacitors journal December 2019
Strategies towards Low‐Cost Dual‐Ion Batteries with High Performance journal November 2019
In situ growth of MnO@Na 2 Ti 6 O 13 heterojunction nanowires for high performance supercapacitors journal May 2019
A Novel Graphite-Graphite Dual Ion Battery Using an AlCl 3 -[EMIm]Cl Liquid Electrolyte journal June 2018
A novel aqueous ammonium dual-ion battery based on organic polymers journal January 2019
Designing Graphite‐Based Positive Electrodes and Their Properties in Dual‐Ion Batteries Using Particle Size‐Adjusted Active Materials journal July 2019
A Review on the Features and Progress of Dual-Ion Batteries journal March 2018
Strategien für kostengünstige und leistungsstarke Dual‐Ionen‐Batterien journal November 2019
A Dual‐Ion Battery with a Ferric Ferricyanide Anode Enabling Reversible Na + Intercalation journal March 2019
Cell Configurations and Electrode Materials for Nonaqueous Sodium-Ion Capacitors: The Current State of the Field journal May 2018
Hybridizing anions towards fast diffusion kinetics for tri-ion batteries with significantly improved rate capability and cycling life journal January 2019
Reversible Anion Storage in a Metal-Organic Framework for Dual-Ion Battery Systems journal January 2019
Red blood cell-like hollow carbon sphere anchored ultrathin Na 2 Ti 3 O 7 nanosheets as long cycling and high rate-performance anodes for sodium-ion batteries journal January 2018

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Related Subjects

25 ENERGY STORAGE
Anion intercalation
Coronene
Cycling life
Graphene-coated Na2Ti3O7
Sodium dual-ion battery