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Title: Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes

Abstract

Unprecedented sequential substitution/reduction synthetic strategy on the Pd radical carbenes afforded heterobimetallic Pd–K carbene complexes, which features novel Pd–C carbene–K structural moieties.

Authors:
 [1];  [1];  [2];  [1]
  1. Univ. of Notre Dame, IN (United States)
  2. Univ. of Notre Dame, IN (United States). Notre Dame Radiation Lab. (NDRL)
Publication Date:
Research Org.:
Univ. of Notre Dame, IN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1438193
Grant/Contract Number:  
FC02-04ER15533
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 7; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Cui, Peng, Hoffbauer, Melissa R., Vyushkova, Mariya, and Iluc, Vlad M.. Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes. United States: N. p., 2016. Web. doi:10.1039/c6sc00948d.
Cui, Peng, Hoffbauer, Melissa R., Vyushkova, Mariya, & Iluc, Vlad M.. Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes. United States. doi:10.1039/c6sc00948d.
Cui, Peng, Hoffbauer, Melissa R., Vyushkova, Mariya, and Iluc, Vlad M.. Thu . "Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes". United States. doi:10.1039/c6sc00948d. https://www.osti.gov/servlets/purl/1438193.
@article{osti_1438193,
title = {Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes},
author = {Cui, Peng and Hoffbauer, Melissa R. and Vyushkova, Mariya and Iluc, Vlad M.},
abstractNote = {Unprecedented sequential substitution/reduction synthetic strategy on the Pd radical carbenes afforded heterobimetallic Pd–K carbene complexes, which features novel Pd–Ccarbene–K structural moieties.},
doi = {10.1039/c6sc00948d},
journal = {Chemical Science},
number = 7,
volume = 7,
place = {United States},
year = {Thu Mar 24 00:00:00 EDT 2016},
month = {Thu Mar 24 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 7 works
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Works referenced in this record:

Olefin-Metathesis Catalysts for the Preparation of Molecules and Materials (Nobel Lecture)
journal, June 2006

  • Grubbs, Robert H.
  • Angewandte Chemie International Edition, Vol. 45, Issue 23, p. 3760-3765
  • DOI: 10.1002/anie.200600680

Multiple Metal–Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture)
journal, June 2006

  • Schrock, Richard R.
  • Angewandte Chemie International Edition, Vol. 45, Issue 23, p. 3748-3759
  • DOI: 10.1002/anie.200600085