skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand

Abstract

Coumarin appended DO3A complexes of Cm( iii ), Eu( iii ), and Tb( iii ) show that more than ionic radius determines the coordination chemistry of the f-elements.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]
  1. Nano-Science Center & Department of Chemistry, University of Copenhagen, 2100 København Ø, Denmark
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Nuclear Engineering
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1437673
Grant/Contract Number:
AC02-05CH11231
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 21; Related Information: CHORUS Timestamp: 2018-05-29 07:17:09; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Junker, Anne Kathrine R., Deblonde, Gauthier J. -P., Abergel, Rebecca J., and Sørensen, Thomas Just. Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT01547C.
Junker, Anne Kathrine R., Deblonde, Gauthier J. -P., Abergel, Rebecca J., & Sørensen, Thomas Just. Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand. United Kingdom. doi:10.1039/C8DT01547C.
Junker, Anne Kathrine R., Deblonde, Gauthier J. -P., Abergel, Rebecca J., and Sørensen, Thomas Just. Mon . "Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand". United Kingdom. doi:10.1039/C8DT01547C.
@article{osti_1437673,
title = {Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu( iii ), Tb( iii ), and Cm( iii ) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand},
author = {Junker, Anne Kathrine R. and Deblonde, Gauthier J. -P. and Abergel, Rebecca J. and Sørensen, Thomas Just},
abstractNote = {Coumarin appended DO3A complexes of Cm( iii ), Eu( iii ), and Tb( iii ) show that more than ionic radius determines the coordination chemistry of the f-elements.},
doi = {10.1039/C8DT01547C},
journal = {Dalton Transactions},
number = 21,
volume = 47,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on May 9, 2019
Publisher's Accepted Manuscript

Save / Share: