Overcoming the Photovoltage Plateau in Large Bandgap Perovskite Photovoltaics

Rajagopal, Adharsh; Stoddard, Ryan J.; Jo, Sae Byeok; Hillhouse, Hugh W.; Jen, Alex K. -Y.

doi:10.1021/acs.nanolett.8b01480

Title: Overcoming the Photovoltage Plateau in Large Bandgap Perovskite Photovoltaics

Journal Article · Mon May 07 00:00:00 EDT 2018 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.8b01480· OSTI ID:1436489

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^[1]; Jo, Sae Byeok ^[1];

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Univ. of Washington, Seattle, WA (United States)
Univ. of Washington, Seattle, WA (United States); City Univ. of Hong Kong (China)

Development of large bandgap (1.80-1.85 eV Eg) perovskite is crucial for perovskite-perovskite tandem solar cells. However, the performance of 1.80-1.85 eV Eg perovskite solar cells (PVKSCs) are significantly lagging their counterparts in the 1.60-1.75 eV Eg range. This is because the photovoltage (Voc) does not proportionally increase with Eg due to lower optoelectronic quality of conventional (MA,FA,Cs)Pb(I,Br)3 and results in a photovoltage plateau (Voc limited to 80% of the theoretical limit for ~1.8 eV Eg). Here, we incorporate phenyl- ethylammonium (PEA) in a mixed-halide perovskite composition to solve the inherent material-level challenges in 1.80-1.85 eV Eg perovskites. The amount of PEA incorporation governs the topography and optoelectronic properties of resultant films. Detailed structural and spectroscopic characterization reveal the characteristic trends in crystalline size, orientation, and charge carrier recombination dynamics and rationalize the origin of improved material quality with higher luminescence. With careful interface optimization, the improved material characteristics were translated to devices and Voc values of 1.30-1.35 V were achieved, which correspond to 85-87% of the theoretical limit. Using an optimal amount of PEA incorporation to balance the increase in Voc and the decrease in charge collection, a highest power conversion efficiency of 12.2% was realized. Our results clearly overcome the photovoltage plateau in the 1.80-1.85 eV Eg range and represent the highest Voc achieved for mixed-halide PVKSCs. This study provides widely translatable insights, an important breakthrough, and a promising platform for next- generation perovskite tandems.

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Research Organization:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: EE0006710

OSTI ID:: 1436489

Journal Information:: Nano Letters, Vol. 18, Issue 6; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 77 works

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References (55)

Understanding the physical properties of hybrid perovskites for photovoltaic applications Huang, Jinsong; Yuan, Yongbo; Shao, Yuchuan Nature Reviews Materials, Vol. 2, Issue 7 https://doi.org/10.1038/natrevmats.2017.42	journal	July 2017
Intriguing Optoelectronic Properties of Metal Halide Perovskites Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V. Chemical Reviews, Vol. 116, Issue 21 https://doi.org/10.1021/acs.chemrev.6b00136	journal	June 2016
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design Saparov, Bayrammurad; Mitzi, David B. Chemical Reviews, Vol. 116, Issue 7 https://doi.org/10.1021/acs.chemrev.5b00715	journal	March 2016
Photovoltaic materials: Present efficiencies and future challenges Polman, A.; Knight, M.; Garnett, E. C. Science, Vol. 352, Issue 6283 https://doi.org/10.1126/science.aad4424	journal	April 2016
Solar cell efficiency tables (version 51) Green, Martin A.; Hishikawa, Yoshihiro; Dunlop, Ewan D. Progress in Photovoltaics: Research and Applications, Vol. 26, Issue 1 https://doi.org/10.1002/pip.2978	journal	December 2017
Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering Rajagopal, Adharsh; Yao, Kai; Jen, Alex K. -Y. Advanced Materials, Vol. 30, Issue 32 https://doi.org/10.1002/adma.201800455	journal	June 2018
Promises and challenges of perovskite solar cells Correa-Baena, Juan-Pablo; Saliba, Michael; Buonassisi, Tonio Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam6323	journal	November 2017
Capturing the Sun: A Review of the Challenges and Perspectives of Perovskite Solar Cells Petrus, Michiel L.; Schlipf, Johannes; Li, Cheng Advanced Energy Materials, Vol. 7, Issue 16 https://doi.org/10.1002/aenm.201700264	journal	June 2017
ABX3 Perovskites for Tandem Solar Cells Anaya, Miguel; Lozano, Gabriel; Calvo, Mauricio E. Joule, Vol. 1, Issue 4 https://doi.org/10.1016/j.joule.2017.09.017	journal	December 2017
Metal halide perovskite tandem and multiple-junction photovoltaics Eperon, Giles E.; Hörantner, Maximilian T.; Snaith, Henry J. Nature Reviews Chemistry, Vol. 1, Issue 12 https://doi.org/10.1038/s41570-017-0095	journal	November 2017
Environmental analysis of perovskites and other relevant solar cell technologies in a tandem configuration Celik, Ilke; Phillips, Adam B.; Song, Zhaoning Energy & Environmental Science, Vol. 10, Issue 9 https://doi.org/10.1039/C7EE01650F	journal	January 2017
Perovskite-perovskite tandem photovoltaics with optimized band gaps Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A. Science, Vol. 354, Issue 6314 https://doi.org/10.1126/science.aaf9717	journal	October 2016
Highly Efficient Perovskite-Perovskite Tandem Solar Cells Reaching 80% of the Theoretical Limit in Photovoltage Rajagopal, Adharsh; Yang, Zhibin; Jo, Sae Byeok Advanced Materials, Vol. 29, Issue 34 https://doi.org/10.1002/adma.201702140	journal	July 2017
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability Bush, Kevin A.; Palmstrom, Axel F.; Yu, Zhengshan J. Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.9	journal	February 2017
Roadmap and roadblocks for the band gap tunability of metal halide perovskites Unger, E. L.; Kegelmann, L.; Suchan, K. Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00404D	journal	January 2017
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aan2301	journal	June 2017
Maximizing and stabilizing luminescence from halide perovskites with potassium passivation Abdi-Jalebi, Mojtaba; Andaji-Garmaroudi, Zahra; Cacovich, Stefania Nature, Vol. 555, Issue 7697 https://doi.org/10.1038/nature25989	journal	March 2018
Light-Induced Anion Phase Segregation in Mixed Halide Perovskites Brennan, Michael C.; Draguta, Sergiu; Kamat, Prashant V. ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b01151	journal	November 2017
Current-Induced Phase Segregation in Mixed Halide Hybrid Perovskites and its Impact on Two-Terminal Tandem Solar Cell Design Braly, Ian L.; Stoddard, Ryan J.; Rajagopal, Adharsh ACS Energy Letters, Vol. 2, Issue 8 https://doi.org/10.1021/acsenergylett.7b00525	journal	July 2017
Optoelectronic Quality and Stability of Hybrid Perovskites from MAPbI ₃ to MAPbI ₂ Br Using Composition Spread Libraries Braly, Ian L.; Hillhouse, Hugh W. The Journal of Physical Chemistry C, Vol. 120, Issue 2 https://doi.org/10.1021/acs.jpcc.5b10728	journal	January 2016
Correlation between Photoluminescence and Carrier Transport and a Simple In Situ Passivation Method for High-Bandgap Hybrid Perovskites Stoddard, Ryan J.; Eickemeyer, Felix T.; Katahara, John K. The Journal of Physical Chemistry Letters, Vol. 8, Issue 14 https://doi.org/10.1021/acs.jpclett.7b01185	journal	July 2017
Rationalizing the light-induced phase separation of mixed halide organic–inorganic perovskites Draguta, Sergiu; Sharia, Onise; Yoon, Seog Joon Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00284-2	journal	August 2017
Band Tailing and Deep Defect States in CH ₃ NH ₃ Pb(I _{1– x} Br _x ) ₃ Perovskites As Revealed by Sub-Bandgap Photocurrent Sutter-Fella, Carolin M.; Miller, D. Westley; Ngo, Quynh P. ACS Energy Letters, Vol. 2, Issue 3 https://doi.org/10.1021/acsenergylett.6b00727	journal	February 2017
Stabilized Wide Bandgap Perovskite Solar Cells by Tin Substitution Yang, Zhibin; Rajagopal, Adharsh; Jo, Sae Byeok Nano Letters, Vol. 16, Issue 12 https://doi.org/10.1021/acs.nanolett.6b03857	journal	November 2016
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells McMeekin, D. P.; Sadoughi, G.; Rehman, W. Science, Vol. 351, Issue 6269 https://doi.org/10.1126/science.aad5845	journal	January 2016
Matching Charge Extraction Contact for Wide-Bandgap Perovskite Solar Cells Lin, Yuze; Chen, Bo; Zhao, Fuwen Advanced Materials, Vol. 29, Issue 26 https://doi.org/10.1002/adma.201700607	journal	May 2017
Rubidium Multication Perovskite with Optimized Bandgap for Perovskite-Silicon Tandem with over 26% Efficiency Duong, The; Wu, YiLiang; Shen, Heping Advanced Energy Materials, Vol. 7, Issue 14 https://doi.org/10.1002/aenm.201700228	journal	April 2017
Synergistic Effects of Lead Thiocyanate Additive and Solvent Annealing on the Performance of Wide-Bandgap Perovskite Solar Cells Yu, Yue; Wang, Changlei; Grice, Corey R. ACS Energy Letters, Vol. 2, Issue 5 https://doi.org/10.1021/acsenergylett.7b00278	journal	April 2017
Amide‐Catalyzed Phase‐Selective Crystallization Reduces Defect Density in Wide‐Bandgap Perovskites Kim, Junghwan; Saidaminov, Makhsud I.; Tan, Hairen Advanced Materials, Vol. 30, Issue 13 https://doi.org/10.1002/adma.201706275	journal	February 2018
Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations Zheng, Xiaopeng; Chen, Bo; Dai, Jun Nature Energy, Vol. 2, Issue 7 https://doi.org/10.1038/nenergy.2017.102	journal	June 2017
Benzylamine-Treated Wide-Bandgap Perovskite with High Thermal-Photostability and Photovoltaic Performance Zhou, Yang; Wang, Feng; Cao, Yu Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701048	journal	September 2017
Efficient ambient-air-stable solar cells with 2D–3D heterostructured butylammonium-caesium-formamidinium lead halide perovskites Wang, Zhiping; Lin, Qianqian; Chmiel, Francis P. Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.135	journal	August 2017
Mixed-Halide Perovskites with Stabilized Bandgaps Xiao, Zhengguo; Zhao, Lianfeng; Tran, Nhu L. Nano Letters, Vol. 17, Issue 11 https://doi.org/10.1021/acs.nanolett.7b03179	journal	October 2017
Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance Saliba, M.; Matsui, T.; Domanski, K. Science, Vol. 354, Issue 6309 https://doi.org/10.1126/science.aah5557	journal	September 2016
Defect Passivation via a Graded Fullerene Heterojunction in Low-Bandgap Pb–Sn Binary Perovskite Photovoltaics Rajagopal, Adharsh; Liang, Po-Wei; Chueh, Chu-Chen ACS Energy Letters, Vol. 2, Issue 11 https://doi.org/10.1021/acsenergylett.7b00847	journal	October 2017
Ligand-Stabilized Reduced-Dimensionality Perovskites Quan, Li Na; Yuan, Mingjian; Comin, Riccardo Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b11740	journal	February 2016
Ultralow Self-Doping in Two-dimensional Hybrid Perovskite Single Crystals Peng, Wei; Yin, Jun; Ho, Kang-Ting Nano Letters, Vol. 17, Issue 8 https://doi.org/10.1021/acs.nanolett.7b01475	journal	June 2017
Passivation of Grain Boundaries by Phenethylammonium in Formamidinium-Methylammonium Lead Halide Perovskite Solar Cells Lee, Da Seul; Yun, Jae Sung; Kim, Jincheol ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00121	journal	February 2018
Dimensional Engineering of a Graded 3D-2D Halide Perovskite Interface Enables Ultrahigh V _oc Enhanced Stability in the p-i-n Photovoltaics Bai, Yang; Xiao, Shuang; Hu, Chen Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701038	journal	July 2017
Stabilization of the Metastable Lead Iodide Perovskite Phase via Surface Functionalization Fu, Yongping; Wu, Tao; Wang, Jue Nano Letters, Vol. 17, Issue 7 https://doi.org/10.1021/acs.nanolett.7b01500	journal	June 2017
Mixed Cation FA _x PEA _1- _x PbI ₃ with Enhanced Phase and Ambient Stability toward High-Performance Perovskite Solar Cells Li, Nan; Zhu, Zonglong; Chueh, Chu-Chen Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601307	journal	September 2016
Perovskite energy funnels for efficient light-emitting diodes Yuan, Mingjian; Quan, Li Na; Comin, Riccardo Nature Nanotechnology, Vol. 11, Issue 10 https://doi.org/10.1038/nnano.2016.110	journal	June 2016
Charge-Carrier Dynamics in 2D Hybrid Metal–Halide Perovskites Milot, Rebecca L.; Sutton, Rebecca J.; Eperon, Giles E. Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03114	journal	October 2016
Optical Properties and Modeling of 2D Perovskite Solar Cells Liu, Bin; Soe, Chan Myae Myae; Stoumpos, Constantinos C. Solar RRL, Vol. 1, Issue 8 https://doi.org/10.1002/solr.201700062	journal	July 2017
Composite Nature of Layered Hybrid Perovskites: Assessment on Quantum and Dielectric Confinements and Band Alignment Traore, Boubacar; Pedesseau, Laurent; Assam, Linda ACS Nano, Vol. 12, Issue 4 https://doi.org/10.1021/acsnano.7b08202	journal	February 2018
Hybrid perovskite films approaching the radiative limit with over 90% photoluminescence quantum efficiency Braly, Ian L.; deQuilettes, Dane W.; Pazos-Outón, Luis M. Nature Photonics, Vol. 12, Issue 6 https://doi.org/10.1038/s41566-018-0154-z	journal	April 2018
Local Observation of Phase Segregation in Mixed-Halide Perovskite Tang, Xiaofeng; van den Berg, Marius; Gu, Ening Nano Letters, Vol. 18, Issue 3 https://doi.org/10.1021/acs.nanolett.8b00505	journal	February 2018
Carrier Diffusion Lengths of over 500 nm in Lead-Free Perovskite CH ₃ NH ₃ SnI ₃ Films Ma, Lin; Hao, Feng; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 138, Issue 44 https://doi.org/10.1021/jacs.6b09257	journal	October 2016
Spatially segregated free-carrier and exciton populations in individual lead halide perovskite grains Nah, S.; Spokoyny, B.; Stoumpos, C. Nature Photonics, Vol. 11, Issue 5 https://doi.org/10.1038/nphoton.2017.36	journal	March 2017
Band filling with free charge carriers in organometal halide perovskites Manser, Joseph S.; Kamat, Prashant V. Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.171	journal	August 2014
Hybrid Perovskites for Photovoltaics: Charge-Carrier Recombination, Diffusion, and Radiative Efficiencies Johnston, Michael B.; Herz, Laura M. Accounts of Chemical Research, Vol. 49, Issue 1 https://doi.org/10.1021/acs.accounts.5b00411	journal	December 2015
Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films Reid, Obadiah G.; Yang, Mengjin; Kopidakis, Nikos ACS Energy Letters, Vol. 1, Issue 3 https://doi.org/10.1021/acsenergylett.6b00288	journal	August 2016
Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite Leblebici, Sibel Y.; Leppert, Linn; Li, Yanbo Nature Energy, Vol. 1, Issue 8 https://doi.org/10.1038/nenergy.2016.93	journal	July 2016
Ideal Bandgap Organic-Inorganic Hybrid Perovskite Solar Cells Yang, Zhibin; Rajagopal, Adharsh; Jen, Alex K. -Y. Advanced Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adma.201704418	journal	November 2017
Compositional Engineering for Efficient Wide Band Gap Perovskites with Improved Stability to Photoinduced Phase Segregation Bush, Kevin A.; Frohna, Kyle; Prasanna, Rohit ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01255	journal	January 2018

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