skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High Energy-Density and Reversibility of Iron Fluoride Cathode Enabled Via an Intercalation-Extrusion Reaction

Abstract

Iron fluoride, an intercalation-conversion cathode for lithium ion batteries, promises a high theoretical energy density of 1922 Wh Kg –1. However, poor electrochemical reversibility due to repeated breaking/reformation of metal-fluoride bonds poses a grand challenge for its practical application. Here we report that both a high reversibility over 1000 cycles and a high capacity of 420 mAh g –1 can be realized by concerted doping of cobalt and oxygen into iron fluoride. In the doped nanorods, an energy density of ~1000 Wh Kg –1 with a decay rate of 0.03% per cycle is achieved. The anion and cation’s co-substitutions thermodynamically reduce conversion-reaction potential and shift the reaction from less reversible intercalation-conversion reaction in iron fluoride to a highly reversible intercalation-extrusion reaction in doped material. Furthermore, the co-substitution strategy to tune the thermodynamic features of the reactions could be extended to other high energy conversion materials for improved performance.

Authors:
 [1]; ORCiD logo [2];  [1];  [1];  [1];  [2];  [3];  [2];  [1];  [1];  [1];  [2];  [2];  [1];  [4];  [2];  [1]
  1. Univ. of Maryland, College Park, MD (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. U.S. Army Research Lab., Adelphi, MD (United States)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1436283
Report Number(s):
BNL-203611-2018-JAAM
Journal ID: ISSN 2041--1723
Grant/Contract Number:
SC0012704
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041--1723
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Fan, Xiulin, Hu, Enyuan, Ji, Xiao, Zhu, Yizhou, Han, Fudong, Hwang, Sooyeon, Liu, Jue, Bak, Seongmin, Ma, Zhaohui, Gao, Tao, Liou, Sz -Chian, Bai, Jianming, Yang, Xiao -Qing, Mo, Yifei, Xu, Kang, Su, Dong, and Wang, Chunsheng. High Energy-Density and Reversibility of Iron Fluoride Cathode Enabled Via an Intercalation-Extrusion Reaction. United States: N. p., 2018. Web. doi:10.1038/s41467-018-04476-2.
Fan, Xiulin, Hu, Enyuan, Ji, Xiao, Zhu, Yizhou, Han, Fudong, Hwang, Sooyeon, Liu, Jue, Bak, Seongmin, Ma, Zhaohui, Gao, Tao, Liou, Sz -Chian, Bai, Jianming, Yang, Xiao -Qing, Mo, Yifei, Xu, Kang, Su, Dong, & Wang, Chunsheng. High Energy-Density and Reversibility of Iron Fluoride Cathode Enabled Via an Intercalation-Extrusion Reaction. United States. doi:10.1038/s41467-018-04476-2.
Fan, Xiulin, Hu, Enyuan, Ji, Xiao, Zhu, Yizhou, Han, Fudong, Hwang, Sooyeon, Liu, Jue, Bak, Seongmin, Ma, Zhaohui, Gao, Tao, Liou, Sz -Chian, Bai, Jianming, Yang, Xiao -Qing, Mo, Yifei, Xu, Kang, Su, Dong, and Wang, Chunsheng. Wed . "High Energy-Density and Reversibility of Iron Fluoride Cathode Enabled Via an Intercalation-Extrusion Reaction". United States. doi:10.1038/s41467-018-04476-2.
@article{osti_1436283,
title = {High Energy-Density and Reversibility of Iron Fluoride Cathode Enabled Via an Intercalation-Extrusion Reaction},
author = {Fan, Xiulin and Hu, Enyuan and Ji, Xiao and Zhu, Yizhou and Han, Fudong and Hwang, Sooyeon and Liu, Jue and Bak, Seongmin and Ma, Zhaohui and Gao, Tao and Liou, Sz -Chian and Bai, Jianming and Yang, Xiao -Qing and Mo, Yifei and Xu, Kang and Su, Dong and Wang, Chunsheng},
abstractNote = {Iron fluoride, an intercalation-conversion cathode for lithium ion batteries, promises a high theoretical energy density of 1922 Wh Kg–1. However, poor electrochemical reversibility due to repeated breaking/reformation of metal-fluoride bonds poses a grand challenge for its practical application. Here we report that both a high reversibility over 1000 cycles and a high capacity of 420 mAh g–1 can be realized by concerted doping of cobalt and oxygen into iron fluoride. In the doped nanorods, an energy density of ~1000 Wh Kg–1 with a decay rate of 0.03% per cycle is achieved. The anion and cation’s co-substitutions thermodynamically reduce conversion-reaction potential and shift the reaction from less reversible intercalation-conversion reaction in iron fluoride to a highly reversible intercalation-extrusion reaction in doped material. Furthermore, the co-substitution strategy to tune the thermodynamic features of the reactions could be extended to other high energy conversion materials for improved performance.},
doi = {10.1038/s41467-018-04476-2},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {Wed May 30 00:00:00 EDT 2018},
month = {Wed May 30 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on May 30, 2019
Publisher's Version of Record

Save / Share: