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Title: In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation

Journal Article · · Advanced Energy Materials
 [1];  [2];  [3];  [4];  [5];  [3];  [6];  [6];  [5];  [4];  [5];  [3];  [3];  [2]
  1. Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Photon Sciences Directorate
  5. Argonne National Lab. (ANL), Argonne, IL (United States). Electron Microscopy Center-Center for Nanoscale Materials
  6. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
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In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC)
Grant/Contract Number:
SC0012704; AC02-06CH11357
OSTI ID:
1436248
Report Number(s):
BNL-203469-2018-JAAM
Journal Information:
Advanced Energy Materials, Vol. 6, Issue 24; ISSN 1614-6832
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 98 works
Citation information provided by
Web of Science

References (26)

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Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography journal June 2015
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Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries journal August 2011
Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode journal October 2015
Electrochemical properties of P2-Na2/3[Ni1/3Mn2/3]O2 cathode material for sodium ion batteries when cycled in different voltage ranges journal December 2013
The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery journal January 2011
Electrochemical intercalation of sodium in NaxCoO2 bronzes journal August 1981
Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life journal June 2011
Prussian blue without coordinated water as a superior cathode for sodium-ion batteries journal January 2015
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes journal June 2014
Large-Scale Synthesis of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 as High Performance Cathode Materials for Sodium Ion Batteries journal January 2016
O3–Na x Mn 1/3 Fe 2/3 O 2 as a positive electrode material for Na-ion batteries: structural evolutions and redox mechanisms upon Na + (de)intercalation journal January 2015
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal January 2013
Prussian blue: a new framework of electrode materials for sodium batteries journal January 2012
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Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2 journal April 2012
A thermodynamic study of sodium-intercalated TaS2 and TiS2 journal September 1979
O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries journal December 2014
First-principles investigation on crystal, electronic structures and Diffusion barriers of NaNi1/3Co1/3Mn1/3O2 for advanced rechargeable Na-ion batteries journal February 2015
New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe 3+ /Fe 4+ Redox in α-NaFeO 2 journal September 2015
Advanced Na[Ni 0.25 Fe 0.5 Mn 0.25 ]O 2 /C–Fe 3 O 4 Sodium-Ion Batteries Using EMS Electrolyte for Energy Storage journal February 2014
Study of Thermal Decomposition of Li 1-x (Ni 1/3 Mn 1/3 Co 1/3 ) 0.9 O 2 Using In-Situ High-Energy X-Ray Diffraction journal March 2013
In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy journal August 2014

Cited By (15)

Ti-Substituted NaNi 0.5 Mn 0.5- x Ti x O 2 Cathodes with Reversible O3−P3 Phase Transition for High-Performance Sodium-Ion Batteries journal March 2017
Exposing {010} Active Facets by Multiple-Layer Oriented Stacking Nanosheets for High-Performance Capacitive Sodium-Ion Oxide Cathode journal August 2018
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance journal November 2017
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries journal February 2018
Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals) journal June 2018
Deciphering the Cathode-Electrolyte Interfacial Chemistry in Sodium Layered Cathode Materials journal October 2018
High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies journal February 2019
A Stable Layered Oxide Cathode Material for High‐Performance Sodium‐Ion Battery journal March 2019
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode journal December 2019
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy journal July 2019
The effect of Na content on the electrochemical performance of the O3-type NaxFe0.5Mn0.5O2 for sodium-ion batteries journal January 2019
Ni-based cathode materials for Na-ion batteries journal June 2019
Synthesis, structure, and electrochemical properties of O′3-type monoclinic NaNi 0.8 Co 0.15 Al 0.05 O 2 cathode materials for sodium-ion batteries journal January 2019
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures journal January 2019
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode journal January 2020

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36 MATERIALS SCIENCE