Benchmarking nanoparticulate metal oxide electrocatalysts for the alkaline water oxidation reaction

Jung, Suho; McCrory, Charles C.  L.; Ferrer, Ivonne M.; Peters, Jonas C.; Jaramillo, Thomas F.

doi:10.1039/c5ta07586f

Title: Benchmarking nanoparticulate metal oxide electrocatalysts for the alkaline water oxidation reaction

Journal Article · Sun Nov 27 00:00:00 EST 2016 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c5ta07586f· OSTI ID:1436119

Jung, Suho ^[1]; McCrory, Charles C. L. ^[1]; Ferrer, Ivonne M. ^[2]; Peters, Jonas C. ^[2]; Jaramillo, Thomas F. ^[3]

California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP); California Inst. of Technology (CalTech), Pasadena, CA (United States). Division of Chemistry and Chemical Engineering
California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP); Stanford Univ., CA (United States). Dept. of Chemical Engineering

Nanoparticulate metal-oxide catalysts are among the most prevalent systems for alkaline water oxidation. However, comparisons of the electrochemical performance of these materials have been challenging due to the different methods of attachment, catalyst loadings, and electrochemical test conditions reported in the literature. Here in this paper, we have leveraged a conventional drop-casting method that allows for the successful adhesion of a wide range of nanoparticulate catalysts to glassy-carbon electrode surfaces. We have applied this adhesion method to prepare catalyst films from 16 crystalline metal-oxide nanoparticles with a constant loading of 0.8 mg cm^-2, and evaluated the resulting nanoparticulate films for the oxygen evolution reaction under conditions relevant to an integrated solar fuels device. In general, the activities of the adhered nanoparticulate films are similar to those of thin-film catalysts prepared by electrodeposition or sputtering, achieving 10 mA cm^-2 current densities per geometric area at overpotentials of ~0.35–0.5 V.

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Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0004993

OSTI ID:: 1436119

Journal Information:: Journal of Materials Chemistry. A, Vol. 4, Issue 8; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 390 works

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References (52)

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Electrochemical study of La0.6Sr0.4Co0.8Fe0.2O3 during oxygen evolution reaction Garcia, Eric M.; Tarôco, Hosane A.; Matencio, Tulio International Journal of Hydrogen Energy, Vol. 37, Issue 8 https://doi.org/10.1016/j.ijhydene.2012.01.058	journal	April 2012
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Meeting the Clean Energy Demand: Nanostructure Architectures for Solar Energy Conversion Kamat, Prashant V. The Journal of Physical Chemistry C, Vol. 111, Issue 7 https://doi.org/10.1021/jp066952u	journal	January 2007
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting Osterloh, Frank E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35266D	journal	January 2013
Characterization of High-Surface-Area Electrocatalysts Using a Rotating Disk Electrode Configuration Schmidt, T. J.; Gasteiger, H. A.; Stäb, G. D. Journal of The Electrochemical Society, Vol. 145, Issue 7, p. 2354-2358 https://doi.org/10.1149/1.1838642	journal	January 1998
Optimizing Perovskites for the Water-Splitting Reaction Vojvodic, A.; Norskov, J. K. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1215081	journal	December 2011
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Molecular Mixed-Metal Manganese Oxido Cubanes as Precursors to Heterogeneous Oxygen Evolution Catalysts Suseno, Sandy; McCrory, Charles C. L.; Tran, Rosalie Chemistry - A European Journal, Vol. 21, Issue 38 https://doi.org/10.1002/chem.201501104	journal	August 2015
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
Mechanism of oxygen evolution on perovskites Bockris, John O'M.; Otagawa, Takaaki The Journal of Physical Chemistry, Vol. 87, Issue 15 https://doi.org/10.1021/j100238a048	journal	July 1983
The Electrocatalysis of Oxygen Evolution on Perovskites Bockris, John O'M. Journal of The Electrochemical Society, Vol. 131, Issue 2 https://doi.org/10.1149/1.2115565	journal	January 1984
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution Grimaud, Alexis; May, Kevin J.; Carlton, Christopher E. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3439	journal	September 2013
Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen Bard, Allen J.; Fox, Marye Anne Accounts of Chemical Research, Vol. 28, Issue 3 https://doi.org/10.1021/ar00051a007	journal	March 1995
The Nature of Lithium Battery Materials under Oxygen Evolution Reaction Conditions Lee, Seung Woo; Carlton, Christopher; Risch, Marcel Journal of the American Chemical Society, Vol. 134, Issue 41 https://doi.org/10.1021/ja307814j	journal	October 2012
Identifying active surface phases for metal oxide electrocatalysts: a study of manganese oxide bi-functional catalysts for oxygen reduction and water oxidation catalysis Su, Hai-Yan; Gorlin, Yelena; Man, Isabela C. Physical Chemistry Chemical Physics, Vol. 14, Issue 40 https://doi.org/10.1039/c2cp40841d	journal	January 2012
Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic Electrolyte Benck, Jesse D.; Pinaud, Blaise A.; Gorlin, Yelena PLoS ONE, Vol. 9, Issue 10 https://doi.org/10.1371/journal.pone.0107942	journal	October 2014
Oxygen evolution on well-characterized mass-selected Ru and RuO ₂ nanoparticles Paoli, Elisa A.; Masini, Federico; Frydendal, Rasmus Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02685C	journal	January 2015
Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis Koper, Marc T. M. Journal of Electroanalytical Chemistry, Vol. 660, Issue 2 https://doi.org/10.1016/j.jelechem.2010.10.004	journal	September 2011
Kinetic study of electrochemical reactions at catalyst-recast ionomer interfaces from thin active layer modelling Gloaguen, F.; Andolfatto, F.; Durand, R. Journal of Applied Electrochemistry, Vol. 24, Issue 9 https://doi.org/10.1007/BF00348773	journal	September 1994
Electrochemical study of sulphonated ferrocenes as redox mediators in enzyme electrodes Liaudet, E.; Battaglini, F.; Calvo, E. J. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 293, Issue 1-2 https://doi.org/10.1016/0022-0728(90)80052-8	journal	October 1990
Size-Dependent Activity of Co ₃ O ₄ Nanoparticle Anodes for Alkaline Water Electrolysis Esswein, Arthur J.; McMurdo, Meredith J.; Ross, Phillip N. The Journal of Physical Chemistry C, Vol. 113, Issue 33 https://doi.org/10.1021/jp904022e	journal	July 2009
Artificial photosynthesis for solar water-splitting Tachibana, Yasuhiro; Vayssieres, Lionel; Durrant, James R. Nature Photonics, Vol. 6, Issue 8 https://doi.org/10.1038/nphoton.2012.175	journal	July 2012
Improving O2 production of WO3 photoanodes with IrO2 in acidic aqueous electrolyte Spurgeon, Joshua M.; Velazquez, Jesus M.; McDowell, Matthew T. Physical Chemistry Chemical Physics, Vol. 16, Issue 8 https://doi.org/10.1039/c3cp55527e	journal	January 2014
Modified LaCoO3 nano-perovskite catalysts for the environmental application of automotive CO oxidation Seyfi, Bahman; Baghalha, Morteza; Kazemian, Hossein Chemical Engineering Journal, Vol. 148, Issue 2-3 https://doi.org/10.1016/j.cej.2008.08.041	journal	May 2009
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
High surface area lanthanum cobaltate and its A and B sites substituted derivatives for electrocatalysis of O2 evolution in alkaline solution Singh, R. International Journal of Hydrogen Energy, Vol. 27, Issue 1 https://doi.org/10.1016/S0360-3199(01)00078-7	journal	January 2002
Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y. Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr100246c	journal	November 2010
Structural Requirements in Lithium Cobalt Oxides for the Catalytic Oxidation of Water Gardner, Graeme P.; Go, Yong Bok; Robinson, David M. Angewandte Chemie International Edition, Vol. 51, Issue 7 https://doi.org/10.1002/anie.201107625	journal	January 2012
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
Artificial photosynthesis: water cleavage into hydrogen and oxygen by visible light Graetzel, Michael Accounts of Chemical Research, Vol. 14, Issue 12 https://doi.org/10.1021/ar00072a003	journal	December 1981
Powering the planet with solar fuel Gray, Harry B. Nature Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/nchem.141	journal	April 2009
Electrocatalytic Measurement Methodology of Oxide Catalysts Using a Thin-Film Rotating Disk Electrode Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki Journal of The Electrochemical Society, Vol. 157, Issue 8 https://doi.org/10.1149/1.3456630	journal	January 2010
Highly efficient and robust oxygen evolution catalysts achieved by anchoring nanocrystalline cobalt oxides onto mildly oxidized multiwalled carbon nanotubes Lu, Xunyu; Zhao, Chuan Journal of Materials Chemistry A, Vol. 1, Issue 39 https://doi.org/10.1039/c3ta12912h	journal	January 2013
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico ChemCatChem, Vol. 3, Issue 7 https://doi.org/10.1002/cctc.201000397	journal	March 2011
Structure–Property Relationship of Bifunctional MnO ₂ Nanostructures: Highly Efficient, Ultra-Stable Electrochemical Water Oxidation and Oxygen Reduction Reaction Catalysts Identified in Alkaline Media Meng, Yongtao; Song, Wenqiao; Huang, Hui Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja505186m	journal	August 2014
LaNi1 − x Cu x O3 (x = 0.05, 0.10, 0.30) coated electrodes for oxygen evolution in alkaline medium Costa, A.; Jorge, M. E. Melo; Carvalho, M. D. Journal of Solid State Electrochemistry, Vol. 17, Issue 8 https://doi.org/10.1007/s10008-013-2106-3	journal	May 2013
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs3003098	journal	July 2012
Electrocatalytic activities of LiCo1−yMyO2 (M=Ni or Fe) synthesized at low temperature and acid-delithiated products for oxygen evolution/reduction in alkaline solution Li, N.; Li, J.; Yang, L. Electrochimica Acta, Vol. 46, Issue 5 https://doi.org/10.1016/S0013-4686(00)00649-6	journal	January 2001
Photoelectrochemical cells for solar hydrogen production: current state of promising photoelectrodes, methods to improve their properties, and outlook Li, Zhaosheng; Luo, Wenjun; Zhang, Minglong Energy Environ. Sci., Vol. 6, Issue 2 https://doi.org/10.1039/C2EE22618A	journal	January 2013
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Kinetics of Activation Controlled Consecutive Electrochemical Reactions: Anodic Evolution of Oxygen Bockris, J. O'M. The Journal of Chemical Physics, Vol. 24, Issue 4 https://doi.org/10.1063/1.1742616	journal	April 1956
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting Khaselev, O. Science, Vol. 280, Issue 5362 https://doi.org/10.1126/science.280.5362.425	journal	April 1998
The Hydrogen Fuel Alternative Crabtree, G. W.; Dresselhaus, M. S. MRS Bulletin, Vol. 33, Issue 4 https://doi.org/10.1557/mrs2008.84	journal	April 2008
Role of the Morphology and Surface Planes on the Catalytic Activity of Spinel LiMn _1.5 Ni _0.5 O ₄ for Oxygen Evolution Reaction Maiyalagan, Thandavarayan; Chemelewski, Katharine R.; Manthiram, Arumugam ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs400981d	journal	December 2013
Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst: a thin-film rotating ring-disk electrode study Paulus, U. A.; Schmidt, T. J.; Gasteiger, H. A. Journal of Electroanalytical Chemistry, Vol. 495, Issue 2 https://doi.org/10.1016/S0022-0728(00)00407-1	journal	January 2001
Efficiency of Splitting Water with Semiconducting Photoelectrodes Weber, Michael F. Journal of The Electrochemical Society, Vol. 131, Issue 6 https://doi.org/10.1149/1.2115797	journal	January 1984
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki Nature Chemistry, Vol. 3, Issue 7, p. 546-550 https://doi.org/10.1038/nchem.1069	journal	June 2011
Electrocatalytic properties of transition metal oxides for oxygen evolution reaction Matsumoto, Y.; Sato, E. Materials Chemistry and Physics, Vol. 14, Issue 5, p. 397-426 https://doi.org/10.1016/0254-0584(86)90045-3	journal	May 1986
Electrocatalysis in the anodic evolution of oxygen and chlorine Trasatti, S. Electrochimica Acta, Vol. 29, Issue 11, p. 1503-1512 https://doi.org/10.1016/0013-4686(84)85004-5	journal	November 1984
Solar hydrogen production with nanostructured metal oxides van de Krol, Roel; Liang, Yongqi; Schoonman, Joop Journal of Materials Chemistry, Vol. 18, Issue 20 https://doi.org/10.1039/b718969a	journal	January 2008
Structural Requirements in Lithium Cobalt Oxides for the Catalytic Oxidation of Water Gardner, Graeme P.; Go, Yong Bok; Robinson, David M. Angewandte Chemie, Vol. 124, Issue 7 https://doi.org/10.1002/ange.201107625	journal	January 2012

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B-site doping effects of NdBa _0.75 Ca _0.25 Co ₂ O _5+δ double perovskite catalysts for oxygen evolution and reduction reactions Kim, Nam-In; Cho, Sung-Hwa; Park, Se Hwan Journal of Materials Chemistry A, Vol. 6, Issue 36 https://doi.org/10.1039/c8ta06236f	journal	January 2018
Tunable nano-interfaces between MnO _x and layered double hydroxides boost oxygen evolving electrocatalysis Xue, Yudong; Fishman, Zachary S.; Röhr, Jason A. Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta07508e	journal	January 2018
A highly efficient electrocatalyst based on double perovskite cobaltites with immense intrinsic catalytic activity for water oxidation Andersen, Håkon; Xu, Kaiqi; Malyshkin, Dmitry Chemical Communications, Vol. 56, Issue 7 https://doi.org/10.1039/c9cc08765f	journal	January 2020
Ir nanoparticles with ultrahigh dispersion as oxygen evolution reaction (OER) catalysts: synthesis and activity benchmarking Bizzotto, Francesco; Quinson, Jonathan; Zana, Alessandro Catalysis Science & Technology, Vol. 9, Issue 22 https://doi.org/10.1039/c9cy01728c	journal	January 2019
MOF-templated cobalt nanoparticles embedded in nitrogen-doped porous carbon: a bifunctional electrocatalyst for overall water splitting Nath, Karabi; Bhunia, Kousik; Pradhan, Debabrata Nanoscale Advances, Vol. 1, Issue 6 https://doi.org/10.1039/c9na00169g	journal	January 2019
Insight into the role of Ni–Fe dual sites in the oxygen evolution reaction based on atomically metal-doped polymeric carbon nitride Wu, Chuchu; Zhang, Xiaoming; Xia, Zhangxun Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta03163d	journal	January 2019
Tailoring the facets of Ni ₃ S ₂ as a bifunctional electrocatalyst for high-performance overall water-splitting Li, Lingjie; Sun, Caiyun; Shang, Bo Journal of Materials Chemistry A, Vol. 7, Issue 30 https://doi.org/10.1039/c9ta05578a	journal	January 2019
Stability profiles of transition metal oxides in the oxygen evolution reaction in alkaline medium Moysiadou, Aliki; Hu, Xile Journal of Materials Chemistry A, Vol. 7, Issue 45 https://doi.org/10.1039/c9ta10308b	journal	January 2019
Iron and Nickel Mixed Oxides Derived From NiIIFeII-PBA for Oxygen Evolution Electrocatalysis Xie, Zhuohong; Zhang, Chi; He, Xin Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00539	journal	July 2019
Metal-Ion (Fe, V, Co, and Ni)-Doped MnO ₂ Ultrathin Nanosheets Supported on Carbon Fiber Paper for the Oxygen Evolution Reaction Ye, Zhiguo; Li, Tao; Ma, Guang Advanced Functional Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adfm.201704083	journal	October 2017
⁵⁷ Fe Mössbauer Spectroscopy Characterization of Electrocatalysts Kramm, Ulrike I.; Ni, Lingmei; Wagner, Stephan Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201805623	journal	December 2018
Remarkable Oxygen-Evolution Activity of a Perovskite Oxide from the Ca _{2− x} Sr _x Fe ₂ O _{6− δ} Series Hona, Ram Krishna; Ramezanipour, Farshid Angewandte Chemie International Edition, Vol. 58, Issue 7 https://doi.org/10.1002/anie.201813000	journal	January 2019
Electrospinning Hetero-Nanofibers of Fe ₃ C-Mo ₂ C/Nitrogen-Doped-Carbon as Efficient Electrocatalysts for Hydrogen Evolution Lin, Huanlei; Zhang, Wenbiao; Shi, Zhangping ChemSusChem, Vol. 10, Issue 12 https://doi.org/10.1002/cssc.201700833	journal	June 2017
Molybdenum Carbide-Decorated Metallic Cobalt@Nitrogen-Doped Carbon Polyhedrons for Enhanced Electrocatalytic Hydrogen Evolution Wu, Can; Liu, Dan; Li, Hui Small, Vol. 14, Issue 16 https://doi.org/10.1002/smll.201704227	journal	March 2018
Graphene–carbon nanotube hybrid catalyst layer architecture for reversible oxygen electrodes in rechargeable metal–air batteries Garcia-Contreras, Miguel A.; Hosseini-Benhangi, Pooya; Gyenge, Előd L. Journal of Applied Electrochemistry, Vol. 49, Issue 3 https://doi.org/10.1007/s10800-018-01280-0	journal	January 2019
Improving the performance of porous nickel foam for water oxidation using hydrothermally prepared Ni and Fe metal oxides Browne, Michelle P.; Vasconcelos, Joana M.; Coelho, João Sustainable Energy & Fuels, Vol. 1, Issue 1 https://doi.org/10.1039/c6se00032k	journal	January 2017
Nickel oxide–polypyrrole nanocomposite electrode materials for electrocatalytic water oxidation Morales, Daniela V.; Astudillo, Catalina N.; Lattach, Youssef Catalysis Science & Technology, Vol. 8, Issue 16 https://doi.org/10.1039/c7cy01949a	journal	January 2018
Spin state engineered Zn _x Co _3−x O ₄ as an efficient oxygen evolution electrocatalyst Ramsundar, Rani Mohan; Pillai, Vijayamohanan Kunjukrishna; Joy, Pattayil Alias Physical Chemistry Chemical Physics, Vol. 20, Issue 46 https://doi.org/10.1039/c8cp06641h	journal	January 2018
Approaches for measuring the surface areas of metal oxide electrocatalysts for determining their intrinsic electrocatalytic activity Wei, Chao; Sun, Shengnan; Mandler, Daniel Chemical Society Reviews, Vol. 48, Issue 9 https://doi.org/10.1039/c8cs00848e	journal	January 2019
Ultrahigh-performance tungsten-doped perovskites for the oxygen evolution reaction Chen, Gao; Hu, Zhiwei; Zhu, Yanping Journal of Materials Chemistry A, Vol. 6, Issue 21 https://doi.org/10.1039/c8ta02864h	journal	January 2018
Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction Ramos-Garcés, Mario V.; Sanchez, Joel; La Luz-Rivera, Kálery Dalton Transactions, Vol. 49, Issue 12 https://doi.org/10.1039/c9dt04135d	journal	January 2020
Homogeneously dispersed multimetal oxygen-evolving catalysts Zhang, B.; Zheng, X.; Voznyy, O. Science, Vol. 352, Issue 6283 https://doi.org/10.1126/science.aaf1525	journal	March 2016
Oxygen Reduction Reaction Electrocatalysis in Alkaline Electrolyte on Glassy-Carbon-Supported Nanostructured Pr6O11 Thin-Films Sharma, Rakesh; Müller, Verónica; Chatenet, Marian Catalysts, Vol. 8, Issue 10 https://doi.org/10.3390/catal8100461	journal	October 2018
Solar‐Driven Production of Hydrogen Peroxide from Water and Dioxygen Fukuzumi, Shunichi; Lee, Yong‐Min; Nam, Wonwoo Chemistry – A European Journal, Vol. 24, Issue 20 https://doi.org/10.1002/chem.201704512	journal	February 2018
Cobalt Oxide Materials for Oxygen Evolution Catalysis via Single-Source Precursor Chemistry Kuznetsov, Denis A.; Konev, Dmitry V.; Sokolov, Sergey A. Chemistry - A European Journal, Vol. 24, Issue 52 https://doi.org/10.1002/chem.201802632	journal	August 2018
One-step solid phase synthesis of a highly efficient and robust cobalt pentlandite electrocatalyst for the oxygen evolution reaction Al-Mamun, Mohammad; Wang, Yun; Liu, Porun Journal of Materials Chemistry A, Vol. 4, Issue 47 https://doi.org/10.1039/c6ta07962h	journal	January 2016
Cobalt-Doped Goethite-Type Iron Oxyhydroxide (α-FeOOH) for Highly Efficient Oxygen Evolution Catalysis Inohara, Daijiro; Maruyama, Heishi; Kakihara, Yasuo ACS Omega, Vol. 3, Issue 7 https://doi.org/10.1021/acsomega.8b01206	journal	July 2018
Recent Advances of First d-Block Metal-Based Perovskite Oxide Electrocatalysts for Alkaline Water Splitting Wang, Jian; Choi, Subin; Kim, Juwon Catalysts, Vol. 10, Issue 7 https://doi.org/10.3390/catal10070770	journal	July 2020

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