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Title: Chemistry through cocrystals: pressure-induced polymerization of C 2H 2·C 6H 6 to an extended crystalline hydrocarbon

Abstract

The 1:1 acetylene–benzene cocrystal, C 2H 2·C 6H 6, was synthesized under pressure in a diamond anvil cell (DAC) and its evolution under pressure was studied with single-crystal X-ray diffraction and Raman spectroscopy.

Authors:
 [1]; ORCiD logo [2];  [1];  [3];  [4];  [5]; ORCiD logo [1]
  1. Geophysical Laboratory; Carnegie Institution of Washington; Washington; USA
  2. Department of Materials Science and Engineering; Pennsylvania State University; University Park; USA
  3. Department of Chemistry; Pennsylvania State University; University Park; USA
  4. High Pressure Collaborative Access Team (HPCAT); Geophysical Laboratory; Carnegie Institution of Washington; Argonne; USA
  5. Department of Materials Science and Engineering; Pennsylvania State University; University Park; USA; Department of Chemistry
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
Defense Advanced Research Projects Agency (DARPA)
OSTI Identifier:
1435813
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 20; Journal Issue: 10
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Ward, Matthew D., Huang, Haw-Tyng, Zhu, Li, Biswas, Arani, Popov, Dmitry, Badding, John V., and Strobel, Timothy A.. Chemistry through cocrystals: pressure-induced polymerization of C2H2·C 6H6 to an extended crystalline hydrocarbon. United States: N. p., 2018. Web. doi:10.1039/C7CP07852H.
Ward, Matthew D., Huang, Haw-Tyng, Zhu, Li, Biswas, Arani, Popov, Dmitry, Badding, John V., & Strobel, Timothy A.. Chemistry through cocrystals: pressure-induced polymerization of C2H2·C 6H6 to an extended crystalline hydrocarbon. United States. doi:10.1039/C7CP07852H.
Ward, Matthew D., Huang, Haw-Tyng, Zhu, Li, Biswas, Arani, Popov, Dmitry, Badding, John V., and Strobel, Timothy A.. Mon . "Chemistry through cocrystals: pressure-induced polymerization of C2H2·C 6H6 to an extended crystalline hydrocarbon". United States. doi:10.1039/C7CP07852H.
@article{osti_1435813,
title = {Chemistry through cocrystals: pressure-induced polymerization of C2H2·C 6H6 to an extended crystalline hydrocarbon},
author = {Ward, Matthew D. and Huang, Haw-Tyng and Zhu, Li and Biswas, Arani and Popov, Dmitry and Badding, John V. and Strobel, Timothy A.},
abstractNote = {The 1:1 acetylene–benzene cocrystal, C2H2·C6H6, was synthesized under pressure in a diamond anvil cell (DAC) and its evolution under pressure was studied with single-crystal X-ray diffraction and Raman spectroscopy.},
doi = {10.1039/C7CP07852H},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 10,
volume = 20,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}