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Title: Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock

Abstract

A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100.degree. C. and up to 550.degree. C., wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.

Inventors:
;
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1435782
Patent Number(s):
9,944,861
Application Number:
14/878,663
Assignee:
UT-BATTELLE, LLC (Oak Ridge, TN)
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Oct 08
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Narula, Chaitanya K., and Davison, Brian H. Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock. United States: N. p., 2018. Web.
Narula, Chaitanya K., & Davison, Brian H. Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock. United States.
Narula, Chaitanya K., and Davison, Brian H. 2018. "Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock". United States. https://www.osti.gov/servlets/purl/1435782.
@article{osti_1435782,
title = {Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock},
author = {Narula, Chaitanya K. and Davison, Brian H.},
abstractNote = {A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100.degree. C. and up to 550.degree. C., wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.},
doi = {},
url = {https://www.osti.gov/biblio/1435782}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 17 00:00:00 EDT 2018},
month = {Tue Apr 17 00:00:00 EDT 2018}
}

Works referenced in this record:

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journal, September 1989


Conversion of ethanol over metal-exchanged zeolites
journal, October 1993


Ethylene from ethanol over zeolite catalysts
journal, January 1987


Works referencing / citing this record:

Process to Make Olefins from Methanol and Isobutanol
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Porous composite materials having micro and meso/macroporosity
patent-application, April 2007


Alkylaromatics Production
patent-application, November 2008


Process for producing olefins and aromatics from non-aromatics
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Method for producing gasoline from methanol
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Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst
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Aviation-Grade Kerosene from Independently Produced Blendstocks
patent-application, March 2011


Conversion Of Carbohydrates To Hydrocarbons
patent-application, June 2011


Conversion of methanol to gasoline
patent, September 1983


Process to Make Olefins from Isobutanol
patent-application, May 2014


Hydrocarbon manufacture from alcohols
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Catalyst composition for treating heavy feedstocks
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High porosity honeycomb and method
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Reactive Distillation Process for the Alkylation of Aromatic Hydrocarbons
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Activation of zeolites
patent, June 1986


Hydrocarbon manufacture from alcohols
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Conversion of methanol to gasoline product
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Method for converting alcohols to hydrocarbons
patent, December 1983


Process for obtaining ethylene from ethanol
patent, February 1988


Production of gasoline hydrocarbons
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Synthesis of Drop-In Liquid Fuels and Chemicals from Methanol, Ethanol or Syngas Using Mixed Catalysts
patent-application, June 2014


Compositions and Methods for Fermentation of Biomass
patent-application, October 2010


Process for Converting Aliphatic Oxygenates to Aromatics
patent-application, July 2010


Benzene reduction in gasoline by alkylation with higher olefins
patent, February 1996


Process for preparing a pentasil zeolite
patent, January 1988


Method and Systems for Making Distillate Fuels from Biomass
patent-application, August 2012


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patent, January 1984


System for conversion of methanol to gasoline
patent, November 1988


Conversion of alcohols, mercaptans, sulfides, halides and/or amines
patent, July 1975


Conversion of methanol to gasoline
patent, November 1988