Covalent Organic Frameworks as a Decorating Platform for Utilization and Affinity Enhancement of Chelating Sites for Radionuclide Sequestration

Sun, Qi; Aguila, Briana; Earl, Lyndsey D.; Abney, Carter W.; Wojtas, Lukasz; Thallapally, Praveen K.; Ma, Shengqian

doi:10.1002/adma.201705479

Title: Covalent Organic Frameworks as a Decorating Platform for Utilization and Affinity Enhancement of Chelating Sites for Radionuclide Sequestration

Journal Article · Tue Mar 27 00:00:00 EDT 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201705479· OSTI ID:1435179

Sun, Qi ^[1]; Aguila, Briana ^[1];

^[2];

^[2]; Wojtas, Lukasz ^[1]; Thallapally, Praveen K. ^[3];

^[1]

Univ. of South Florida, Tampa, FL (United States). Department of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Science Directorate

Abstract The potential consequences of nuclear events and the complexity of nuclear waste management motivate the development of selective solid‐phase sorbents to provide enhanced protection. Herein, it is shown that 2D covalent organic frameworks (COFs) with unique structures possess all the traits to be well suited as a platform for the deployment of highly efficient sorbents such that they exhibit remarkable performance, as demonstrated by uranium capture. The chelating groups laced on the open 1D channels exhibit exceptional accessibility, allowing significantly higher utilization efficiency. In addition, the 2D extended polygons packed closely in an eclipsed fashion bring chelating groups in adjacent layers parallel to each other, which may facilitate their cooperation, thereby leading to high affinity toward specific ions. As a result, the amidoxime‐functionalized COFs far outperform their corresponding amorphous analogs in terms of adsorption capacities, kinetics, and affinities. Specifically, COF‐TpAb‐AO is able to reduce various uranium contaminated water samples from 1 ppm to less than 0.1 ppb within several minutes, well below the drinking water limit (30 ppb), as well as mine uranium from spiked seawater with an exceptionally high uptake capacity of 127 mg g ⁻¹ . These results delineate important synthetic advances toward the implementation of COFs in environmental remediation.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; NE0008281; AC02‐76SF00515; DE‐NE0008281; DE‐AC02‐76SF00515

OSTI ID:: 1435179

Alternate ID(s):: OSTI ID: 1430134

Journal Information:: Advanced Materials, Journal Name: Advanced Materials; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 350 works

Citation information provided by
Web of Science

References (83)

NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO ₄ ⁻ from Solution Wang, Shuao; Alekseev, Evgeny V.; Diwu, Juan Angewandte Chemie International Edition, Vol. 49, Issue 6 https://doi.org/10.1002/anie.200906397	journal	February 2010
Nano-Composites for Water Remediation: A Review Tesh, Sarah J.; Scott, Thomas B. Advanced Materials, Vol. 26, Issue 35 https://doi.org/10.1002/adma.201401376	journal	July 2014
A half-wave rectified alternating current electrochemical method for uranium extraction from seawater Liu, Chong; Hsu, Po-Chun; Xie, Jin Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.7	journal	February 2017
Functionalized Porous Aromatic Framework for Efficient Uranium Adsorption from Aqueous Solutions Li, Baiyan; Sun, Qi; Zhang, Yiming ACS Applied Materials & Interfaces, Vol. 9, Issue 14 https://doi.org/10.1021/acsami.7b01711	journal	March 2017
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
Wavelet data analysis of EXAFS spectra Timoshenko, J.; Kuzmin, A. Computer Physics Communications, Vol. 180, Issue 6 https://doi.org/10.1016/j.cpc.2008.12.020	journal	June 2009
Glutarimidedioxime: A Complexing and Reducing Reagent for Plutonium Recovery from Spent Nuclear Fuel Reprocessing Xian, Liang; Tian, Guoxin; Beavers, Christine M. Angewandte Chemie International Edition, Vol. 55, Issue 15 https://doi.org/10.1002/anie.201510712	journal	March 2016
Structural clues to UO ₂ ²⁺ /VO ₂ ⁺ competition in seawater extraction using amidoxime-based extractants Kelley, Steven P.; Barber, Patrick S.; Mullins, Peter H. K. Chem. Commun., Vol. 50, Issue 83 https://doi.org/10.1039/C4CC06370H	journal	January 2014
The removal of uranium(VI) from aqueous solutions onto activated carbon: Kinetic and thermodynamic investigations Mellah, A.; Chegrouche, S.; Barkat, M. Journal of Colloid and Interface Science, Vol. 296, Issue 2 https://doi.org/10.1016/j.jcis.2005.09.045	journal	April 2006
Extraction of Photogenerated Electrons and Holes from a Covalent Organic Framework Integrated Heterojunction Calik, Mona; Auras, Florian; Salonen, Laura M. Journal of the American Chemical Society, Vol. 136, Issue 51 https://doi.org/10.1021/ja509551m	journal	December 2014
Hydrophilic Clicked 2,6-Bis-triazolyl-pyridines Endowed with High Actinide Selectivity and Radiochemical Stability: Toward a Closed Nuclear Fuel Cycle Macerata, Elena; Mossini, Eros; Scaravaggi, Stefano Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b03106	journal	May 2016
Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework Baldwin, Luke A.; Crowe, Jonathan W.; Pyles, David A. Journal of the American Chemical Society, Vol. 138, Issue 46 https://doi.org/10.1021/jacs.6b10316	journal	November 2016
Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework Xie, Jian; Wang, Yaxing; Liu, Wei Angewandte Chemie International Edition, Vol. 56, Issue 26 https://doi.org/10.1002/anie.201700919	journal	May 2017
Materials for the Recovery of Uranium from Seawater Abney, Carter W.; Mayes, Richard T.; Saito, Tomonori Chemical Reviews, Vol. 117, Issue 23 https://doi.org/10.1021/acs.chemrev.7b00355	journal	June 2017
Introduction of amino groups into acid-resistant MOFs for enhanced U( vi ) sorption Bai, Zhi-Qiang; Yuan, Li-Yong; Zhu, Lin Journal of Materials Chemistry A, Vol. 3, Issue 2 https://doi.org/10.1039/C4TA04878D	journal	January 2015
Stable Covalent Organic Frameworks for Exceptional Mercury Removal from Aqueous Solutions Huang, Ning; Zhai, Lipeng; Xu, Hong Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b12328	journal	February 2017
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao Science, Vol. 349, Issue 6253 https://doi.org/10.1126/science.aac8343	journal	August 2015
Efficient Uranium Capture by Polysulfide/Layered Double Hydroxide Composites Ma, Shulan; Huang, Lu; Ma, Lijiao Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/jacs.5b00762	journal	March 2015
Function-led design of new porous materials Slater, A. G.; Cooper, A. I. Science, Vol. 348, Issue 6238 https://doi.org/10.1126/science.aaa8075	journal	May 2015
Protein Hydrogel Microbeads for Selective Uranium Mining from Seawater Kou, Songzi; Yang, Zhongguang; Sun, Fei ACS Applied Materials & Interfaces, Vol. 9, Issue 3 https://doi.org/10.1021/acsami.6b15968	journal	January 2017
Actinide Sequestration Using Self-Assembled Monolayers on Mesoporous Supports Fryxell, Glen E.; Lin, Yuehe; Fiskum, Sandy Environmental Science & Technology, Vol. 39, Issue 5 https://doi.org/10.1021/es049201j	journal	March 2005
An Elastic Hydrogen-Bonded Cross-Linked Organic Framework for Effective Iodine Capture in Water Lin, Yunxiao; Jiang, Xuanfeng; Kim, Samuel T. Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b03204	journal	May 2017
Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki–Miyaura Coupling Reaction Ding, San-Yuan; Gao, Jia; Wang, Qiong Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja206846p	journal	December 2011
Ultrathin Two-Dimensional Covalent Organic Framework Nanosheets: Preparation and Application in Highly Sensitive and Selective DNA Detection Peng, Yongwu; Huang, Ying; Zhu, Yihan Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b04096	journal	June 2017
Layered Metal Sulfides Capture Uranium from Seawater Manos, Manolis. J.; Kanatzidis, Mercouri G. Journal of the American Chemical Society, Vol. 134, Issue 39 https://doi.org/10.1021/ja308028n	journal	September 2012
Acetylcysteine-functionalized microporous conjugated polymers for potential separation of uranium from radioactive effluents Han, Xiaoli; Xu, Meiyun; Yang, Sen Journal of Materials Chemistry A, Vol. 5, Issue 10 https://doi.org/10.1039/C6TA10824E	journal	January 2017
UO ₂ ²⁺ Uptake by Proteins: Understanding the Binding Features of the Super Uranyl Binding Protein and Design of a Protein with Higher Affinity Odoh, Samuel O.; Bondarevsky, Gary D.; Karpus, Jason Journal of the American Chemical Society, Vol. 136, Issue 50 https://doi.org/10.1021/ja5087563	journal	December 2014
A protein engineered to bind uranyl selectively and with femtomolar affinity Zhou, Lu; Bosscher, Mike; Zhang, Changsheng Nature Chemistry, Vol. 6, Issue 3 https://doi.org/10.1038/nchem.1856	journal	January 2014
Seawater Uranium Sorbents: Preparation from a Mesoporous Copolymer Initiator by Atom-Transfer Radical Polymerization Yue, Yanfeng; Mayes, Richard T.; Kim, Jungseung Angewandte Chemie International Edition, Vol. 52, Issue 50 https://doi.org/10.1002/anie.201307825	journal	October 2013
Efficient Removal and Recovery of Uranium by a Layered Organic–Inorganic Hybrid Thiostannate Feng, Mei-Ling; Sarma, Debajit; Qi, Xing-Hui Journal of the American Chemical Society, Vol. 138, Issue 38 https://doi.org/10.1021/jacs.6b07351	journal	September 2016
Pore-Free Matrix with Cooperative Chelating of Hyperbranched Ligands for High-Performance Separation of Uranium Li, Yang; Wang, Lei; Li, Bo ACS Applied Materials & Interfaces, Vol. 8, Issue 42 https://doi.org/10.1021/acsami.6b09681	journal	October 2016
MOF-76: from a luminescent probe to highly efficient UVI sorption material Yang, Weiting; Bai, Zhi-Qiang; Shi, Wei-Qun Chemical Communications, Vol. 49, Issue 88 https://doi.org/10.1039/c3cc44983a	journal	January 2013
Thiophene-based covalent organic frameworks Bertrand, G. H. V.; Michaelis, V. K.; Ong, T. -C. Proceedings of the National Academy of Sciences, Vol. 110, Issue 13 https://doi.org/10.1073/pnas.1221824110	journal	March 2013
Covalent Organic Frameworks for CO ₂ Capture Zeng, Yongfei; Zou, Ruqiang; Zhao, Yanli Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201505004	journal	February 2016
Titanate Nanofibers as Intelligent Absorbents for the Removal of Radioactive Ions from Water Yang, Dong Jiang; Zheng, Zhan Feng; Zhu, Huai Yong Advanced Materials, Vol. 20, Issue 14 https://doi.org/10.1002/adma.200702055	journal	July 2008
Removal of TcO ₄ ⁻ ions from solution: materials and future outlook Banerjee, Debasis; Kim, Dongsang; Schweiger, Michael J. Chemical Society Reviews, Vol. 45, Issue 10 https://doi.org/10.1039/C5CS00330J	journal	January 2016
Superselective clay for radium uptake Komarneni, Sridhar; Kozai, Naofumi; Paulus, William J. Nature, Vol. 410, Issue 6830 https://doi.org/10.1038/35071173	journal	April 2001
3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery Fang, Qianrong; Wang, Junhua; Gu, Shuang Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b04147	journal	June 2015
Exploiting Noncovalent Interactions in an Imine-Based Covalent Organic Framework for Quercetin Delivery Vyas, Vijay S.; Vishwakarma, Medhavi; Moudrakovski, Igor Advanced Materials, Vol. 28, Issue 39 https://doi.org/10.1002/adma.201603006	journal	August 2016
Tuning Amidoximate to Enhance Uranyl Binding: A Density Functional Theory Study Abney, Carter W.; Liu, Shubin; Lin, Wenbin The Journal of Physical Chemistry A, Vol. 117, Issue 45 https://doi.org/10.1021/jp408460x	journal	October 2013
Tessellated multiporous two-dimensional covalent organic frameworks Jin, Yinghua; Hu, Yiming; Zhang, Wei Nature Reviews Chemistry, Vol. 1, Issue 7 https://doi.org/10.1038/s41570-017-0056	journal	July 2017
Covalent organic frameworks (COFs): from design to applications Ding, San-Yuan; Wang, Wei Chem. Soc. Rev., Vol. 42, Issue 2 https://doi.org/10.1039/C2CS35072F	journal	January 2013
Highly Selective and Rapid Uptake of Radionuclide Cesium Based on Robust Zeolitic Chalcogenide via Stepwise Ion-Exchange Strategy Yang, Huajun; Luo, Min; Luo, Li Chemistry of Materials, Vol. 28, Issue 23 https://doi.org/10.1021/acs.chemmater.6b04273	journal	November 2016
Ionic Covalent Organic Frameworks with Spiroborate Linkage Du, Ya; Yang, Haishen; Whiteley, Justin Michael Angewandte Chemie International Edition, Vol. 55, Issue 5 https://doi.org/10.1002/anie.201509014	journal	December 2015
Construction of Covalent Organic Frameworks Bearing Three Different Kinds of Pores through the Heterostructural Mixed Linker Strategy Pang, Zhong-Fu; Xu, Shun-Qi; Zhou, Tian-You Journal of the American Chemical Society, Vol. 138, Issue 14 https://doi.org/10.1021/jacs.6b01244	journal	March 2016
Highly porous and stable metal–organic frameworks for uranium extraction Carboni, Michaël; Abney, Carter W.; Liu, Shubin Chemical Science, Vol. 4, Issue 6, p. 2396-2402 https://doi.org/10.1039/c3sc50230a	journal	January 2013
Exfoliation of Covalent Organic Frameworks into Few-Layer Redox-Active Nanosheets as Cathode Materials for Lithium-Ion Batteries Wang, Shan; Wang, Qianyou; Shao, Pengpeng Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b02648	journal	March 2017
Surface functionalized nanostructured ceramic sorbents for the effective collection and recovery of uranium from seawater Chouyyok, Wilaiwan; Pittman, Jonathan W.; Warner, Marvin G. Dalton Transactions, Vol. 45, Issue 28 https://doi.org/10.1039/C6DT01318J	journal	January 2016
Porous, Crystalline, Covalent Organic Frameworks Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W. Science, Vol. 310, Issue 5751, p. 1166-1170 https://doi.org/10.1126/science.1120411	journal	November 2005
Conjugated Covalent Organic Frameworks via Michael Addition–Elimination Rao, M. Rajeswara; Fang, Yuan; De Feyter, Steven Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b12005	journal	January 2017
Postsynthetically Modified Covalent Organic Frameworks for Efficient and Effective Mercury Removal Sun, Qi; Aguila, Briana; Perman, Jason Journal of the American Chemical Society, Vol. 139, Issue 7 https://doi.org/10.1021/jacs.6b12885	journal	February 2017
Coordination chemistry in the ocean Lu, Yi Nature Chemistry, Vol. 6, Issue 3 https://doi.org/10.1038/nchem.1880	journal	February 2014
How Amidoximate Binds the Uranyl Cation Vukovic, Sinisa; Watson, Lori A.; Kang, Sung Ok Inorganic Chemistry, Vol. 51, Issue 6 https://doi.org/10.1021/ic300062s	journal	February 2012
Impacts of the Fukushima Nuclear Power Plants on Marine Radioactivity Buesseler, Ken; Aoyama, Michio; Fukasawa, Masao Environmental Science & Technology, Vol. 45, Issue 23 https://doi.org/10.1021/es202816c	journal	December 2011
Flexibility Matters: Cooperative Active Sites in Covalent Organic Framework and Threaded Ionic Polymer Sun, Qi; Aguila, Briana; Perman, Jason Journal of the American Chemical Society, Vol. 138, Issue 48 https://doi.org/10.1021/jacs.6b10629	journal	November 2016
Design Principles for High H ₂ Storage Using Chelation of Abundant Transition Metals in Covalent Organic Frameworks for 0–700 bar at 298 K Pramudya, Yohanes; Mendoza-Cortes, Jose L. Journal of the American Chemical Society, Vol. 138, Issue 46 https://doi.org/10.1021/jacs.6b08803	journal	November 2016
Novel poly(imide dioxime) sorbents: Development and testing for enhanced extraction of uranium from natural seawater Das, S.; Brown, S.; Mayes, R. T. Chemical Engineering Journal, Vol. 298 https://doi.org/10.1016/j.cej.2016.04.013	journal	August 2016
Enrichment and Encapsulation of Uranium with Iron Nanoparticle Ling, Lan; Zhang, Wei-xian Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja510488r	journal	February 2015
Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis Wang, Xiuren; Han, Xing; Zhang, Jie Journal of the American Chemical Society, Vol. 138, Issue 38 https://doi.org/10.1021/jacs.6b07714	journal	September 2016
Topotactic Transformations of Metal–Organic Frameworks to Highly Porous and Stable Inorganic Sorbents for Efficient Radionuclide Sequestration Abney, Carter W.; Taylor-Pashow, Kathryn M. L.; Russell, Shane R. Chemistry of Materials, Vol. 26, Issue 18 https://doi.org/10.1021/cm501894h	journal	September 2014
Construction of Crystalline 2D Covalent Organic Frameworks with Remarkable Chemical (Acid/Base) Stability via a Combined Reversible and Irreversible Route Kandambeth, Sharath; Mallick, Arijit; Lukose, Binit Journal of the American Chemical Society, Vol. 134, Issue 48 https://doi.org/10.1021/ja308278w	journal	November 2012
Wavelet analysis of extended x-ray absorption fine structure data Funke, H.; Scheinost, A. C.; Chukalina, M. Physical Review B, Vol. 71, Issue 9 https://doi.org/10.1103/PhysRevB.71.094110	journal	March 2005
A bifunctional covalent organic framework as an efficient platform for cascade catalysis Sun, Qi; Aguila, Briana; Ma, Shengqian Materials Chemistry Frontiers, Vol. 1, Issue 7 https://doi.org/10.1039/C6QM00363J	journal	January 2017
Determination of bimetallic architectures in nanometer-scale catalysts by combining molecular dynamics simulations with x-ray absorption spectroscopy Timoshenko, Janis; Keller, Kayla R.; Frenkel, Anatoly I. The Journal of Chemical Physics, Vol. 146, Issue 11 https://doi.org/10.1063/1.4978500	journal	March 2017
Covalent Organic Frameworks as a Platform for Multidimensional Polymerization Bisbey, Ryan P.; Dichtel, William R. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00127	journal	May 2017
Highly Porous Acrylonitrile-Based Submicron Particles for UO ₂ ²⁺ Absorption in an Immunosensor Assay Sahiner, Nurettin; Yu, Haini; Tan, Grace ACS Applied Materials & Interfaces, Vol. 4, Issue 1 https://doi.org/10.1021/am201204r	journal	December 2011
Porous Organic Materials: Strategic Design and Structure–Function Correlation Das, Saikat; Heasman, Patrick; Ben, Teng Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00439	journal	December 2016
Rational Design of Sequestering Agents for Plutonium and Other Actinides Gorden, Anne E. V.; Xu, Jide; Raymond, Kenneth N. Chemical Reviews, Vol. 103, Issue 11 https://doi.org/10.1021/cr990114x	journal	November 2003
Covalent organic frameworks Feng, Xiao; Ding, Xuesong; Jiang, Donglin Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35157a	journal	January 2012
Reverse Monte Carlo modeling of thermal disorder in crystalline materials from EXAFS spectra Timoshenko, Janis; Kuzmin, Alexei; Purans, Juris Computer Physics Communications, Vol. 183, Issue 6 https://doi.org/10.1016/j.cpc.2012.02.002	journal	June 2012
A Combined Experimental and Theoretical Study on the Extraction of Uranium by Amino-Derived Metal–Organic Frameworks through Post-Synthetic Strategy Li, Linnan; Ma, Wen; Shen, Sensen ACS Applied Materials & Interfaces, Vol. 8, Issue 45 https://doi.org/10.1021/acsami.6b11332	journal	November 2016
A Pyrene-Based, Fluorescent Three-Dimensional Covalent Organic Framework Lin, Guiqing; Ding, Huimin; Yuan, Daqiang Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.6b00652	journal	March 2016
Targeted Drug Delivery in Covalent Organic Nanosheets (CONs) via Sequential Postsynthetic Modification Mitra, Shouvik; Sasmal, Himadri Sekhar; Kundu, Tanay Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b00925	journal	March 2017
XAFS investigation of polyamidoxime-bound uranyl contests the paradigm from small molecule studies Abney, C. W.; Mayes, R. T.; Piechowicz, M. Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE02913A	journal	January 2016
Rapid extraction of uranium ions from seawater using novel porous polymeric adsorbents Sihn, Y. H.; Byun, J.; Patel, H. A. RSC Advances, Vol. 6, Issue 51 https://doi.org/10.1039/C6RA06807C	journal	January 2016
Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts Xu, Hong; Gao, Jia; Jiang, Donglin Nature Chemistry, Vol. 7, Issue 11 https://doi.org/10.1038/nchem.2352	journal	September 2015
EXAFS study of hydrogen intercalation into ReO ₃ using the evolutionary algorithm Timoshenko, J.; Kuzmin, A.; Purans, J. Journal of Physics: Condensed Matter, Vol. 26, Issue 5 https://doi.org/10.1088/0953-8984/26/5/055401	journal	January 2014
Seawater Uranium Sorbents: Preparation from a Mesoporous Copolymer Initiator by Atom-Transfer Radical Polymerization Yue, Yanfeng; Mayes, Richard T.; Kim, Jungseung Angewandte Chemie, Vol. 125, Issue 50 https://doi.org/10.1002/ange.201307825	journal	October 2013
Ionic Covalent Organic Frameworks with Spiroborate Linkage Du, Ya; Yang, Haishen; Whiteley, Justin Michael Angewandte Chemie, Vol. 128, Issue 5 https://doi.org/10.1002/ange.201509014	journal	December 2015
Zurückgezogen: Glutarimidedioxime: A Complexing and Reducing Reagent for Plutonium Recovery from Spent Nuclear Fuel Reprocessing Xian, Liang; Tian, Guoxin; Beavers, Christine M. Angewandte Chemie, Vol. 128, Issue 15 https://doi.org/10.1002/ange.201510712	journal	March 2016
Rational Design of Sequestering Agents for Plutonium and Other Actinides Gorden, Anne E. V.; Xu, Jide; Raymond, Kenneth N. ChemInform, Vol. 35, Issue 5 https://doi.org/10.1002/chin.200405275	journal	February 2004
NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution Wang, Shuao; Alekseev, Evgeny V.; Diwu, Juan Angewandte Chemie, Vol. 122, Issue 6 https://doi.org/10.1002/ange.200906397	journal	December 2009
Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework Xie, Jian; Wang, Yaxing; Liu, Wei Angewandte Chemie, Vol. 129, Issue 26 https://doi.org/10.1002/ange.201700919	journal	May 2017

Cited By (54)

Squaramide-decorated covalent organic framework as a new platform for biomimetic hydrogen-bonding organocatalysis Li, Xia; Wang, Zhifang; Sun, Jiaxing Chemical Communications, Vol. 55, Issue 38 https://doi.org/10.1039/c9cc01317b	journal	January 2019
Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption Sun, Qi; Zhu, Lin; Aguila, Briana Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09630-y	journal	April 2019
Covalent Organic Frameworks with Chirality Enriched by Biomolecules for Efficient Chiral Separation Zhang, Sainan; Zheng, Yunlong; An, Hongde Angewandte Chemie, Vol. 130, Issue 51 https://doi.org/10.1002/ange.201810571	journal	December 2018
Enhancing C ₂ H ₂ /C ₂ H ₄ separation by incorporating low-content sodium in covalent organic frameworks Tao, Yuan; Krishna, Rajamani; Yang, Li Xiao Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00922a	journal	January 2019
Regenerable and stable sp2 carbon-conjugated covalent organic frameworks for selective detection and extraction of uranium Cui, Wei-Rong; Zhang, Cheng-Rong; Jiang, Wei Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14289-x	journal	January 2020
Ultrafast and Highly Selective Uranium Extraction from Seawater by Hydrogel‐like Spidroin‐based Protein Fiber Yuan, Yihui; Yu, Qiuhan; Wen, Jun Angewandte Chemie, Vol. 131, Issue 34 https://doi.org/10.1002/ange.201906191	journal	July 2019
In situ Preparation of Chitosan/ZIF-8 Composite Beads for Highly Efficient Removal of U(VI) Liu, Lijuan; Yang, Weiting; Gu, Dongxu Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00607	journal	September 2019
Kovalente organische Gerüstverbindungen: chemische Ansätze für Designerstrukturen und integrierte Funktionen Chen, Xinyi; Geng, Keyu; Liu, Ruoyang Angewandte Chemie, Vol. 132, Issue 13 https://doi.org/10.1002/ange.201904291	journal	December 2019
Designed Synthesis of a 2D Porphyrin‐Based sp ² Carbon‐Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis Chen, Rufan; Shi, Ji‐Long; Ma, Yuan Angewandte Chemie International Edition, Vol. 58, Issue 19 https://doi.org/10.1002/anie.201902543	journal	May 2019
Mechanochromic luminescent covalent organic frameworks for highly selective hydroxyl radical detection Liu, Wei; Cao, Yuping; Wang, Wenzhuang Chemical Communications, Vol. 55, Issue 2 https://doi.org/10.1039/c8cc07783e	journal	January 2019
Dual luminescent covalent organic frameworks for nitro-explosive detection Faheem, Muhammad; Aziz, Saba; Jing, Xiaofei Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta09497k	journal	January 2019
Polypropylene nonwoven fabric modified with oxime and guanidine for antibiofouling and highly selective uranium recovery from seawater Yang, Sen; Ji, Guoxun; Cai, Suya Journal of Radioanalytical and Nuclear Chemistry, Vol. 321, Issue 1 https://doi.org/10.1007/s10967-019-06578-7	journal	May 2019
Covalent Organic Frameworks: Chemical Approaches to Designer Structures and Built‐In Functions Chen, Xinyi; Geng, Keyu; Liu, Ruoyang Angewandte Chemie International Edition, Vol. 59, Issue 13 https://doi.org/10.1002/anie.201904291	journal	March 2020
Synthesis of novel nanomaterials and their application in efficient removal of radionuclides Wang, Xiangxue; Chen, Long; Wang, Lin Science China Chemistry, Vol. 62, Issue 8 https://doi.org/10.1007/s11426-019-9492-4	journal	June 2019
Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage Zheng, Bingna; Lin, Xidong; Zhang, Xingcai Advanced Functional Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adfm.201907006	journal	November 2019
N, P, and S Codoped Graphene-Like Carbon Nanosheets for Ultrafast Uranium (VI) Capture with High Capacity Chen, Zhe; Chen, Wanying; Jia, Dashuang Advanced Science, Vol. 5, Issue 10 https://doi.org/10.1002/advs.201800235	journal	August 2018
All-in-One Porous Polymer Adsorbents with Excellent Environmental Chemosensory Responsivity, Visual Detectivity, Superfast Adsorption, and Easy Regeneration Xie, Yiming; Huang, Wen; Zheng, Bingna Advanced Materials, Vol. 31, Issue 16 https://doi.org/10.1002/adma.201900104	journal	March 2019
Ag Nanoparticles Supported on a Resorcinol‐Phenylenediamine‐Based Covalent Organic Framework for Chemical Fixation of CO ₂ Chakraborty, Debanjan; Shekhar, Pragalbh; Singh, Himan Dev Chemistry – An Asian Journal, Vol. 14, Issue 24 https://doi.org/10.1002/asia.201901157	journal	October 2019
Bio-inspired nano-traps for uranium extraction from seawater and recovery from nuclear waste Sun, Qi; Aguila, Briana; Perman, Jason Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04032-y	journal	April 2018
An Ion‐Crosslinked Supramolecular Hydrogel for Ultrahigh and Fast Uranium Recovery from Seawater Yan, Bingjie; Ma, Chunxin; Gao, Jinxiang Advanced Materials, Vol. 32, Issue 10 https://doi.org/10.1002/adma.201906615	journal	January 2020
Isostructural Three‐Dimensional Covalent Organic Frameworks Gao, Chao; Li, Jian; Yin, Sheng Angewandte Chemie, Vol. 131, Issue 29 https://doi.org/10.1002/ange.201905591	journal	June 2019
Tailored covalent organic frameworks by post-synthetic modification Ding, Huimin; Mal, Arindam; Wang, Cheng Materials Chemistry Frontiers, Vol. 4, Issue 1 https://doi.org/10.1039/c9qm00555b	journal	January 2020
Redox‐Active Two‐Dimensional Covalent Organic Frameworks (COFs) for Selective Reductive Separation of Valence‐Variable, Redox‐Sensitive and Long‐Lived Radionuclides Li, Yang; Guo, Xinghua; Li, Xiaofeng Angewandte Chemie, Vol. 132, Issue 10 https://doi.org/10.1002/ange.201916360	journal	January 2020
Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets Yuan, Yihui; Niu, Biye; Yu, Qiuhan Angewandte Chemie, Vol. 132, Issue 3 https://doi.org/10.1002/ange.201913644	journal	November 2019
Selective adsorption of uranium from salt lake-simulated solution by phenolic-functionalized hollow sponge-like adsorbent: Selective adsorption of uranium from salt lake-simulated solution He, Yu; Lin, Xiaoyan; Yan, Tingsong Journal of Chemical Technology & Biotechnology, Vol. 94, Issue 2 https://doi.org/10.1002/jctb.5790	journal	September 2018
Ammoniating Covalent Organic Framework (COF) for High‐Performance and Selective Extraction of Toxic and Radioactive Uranium Ions Xiong, Xiao Hong; Yu, Zhi Wu; Gong, Le Le Advanced Science, Vol. 6, Issue 16 https://doi.org/10.1002/advs.201900547	journal	June 2019
Extraction and adsorption of U(VI) from aqueous solution using affinity ligand-based technologies: an overview Wang, Jianlong; Zhuang, Shuting Reviews in Environmental Science and Bio/Technology, Vol. 18, Issue 3 https://doi.org/10.1007/s11157-019-09507-y	journal	July 2019
Opportunities of Covalent Organic Frameworks for Advanced Applications Song, Yanpei; Sun, Qi; Aguila, Briana Advanced Science, Vol. 6, Issue 2 https://doi.org/10.1002/advs.201801410	journal	November 2018
Postsynthetic functionalization of covalent organic frameworks Yusran, Yusran; Guan, Xinyu; Li, Hui National Science Review, Vol. 7, Issue 1 https://doi.org/10.1093/nsr/nwz122	journal	August 2019
A Dual‐Surface Amidoximated Halloysite Nanotube for High‐Efficiency Economical Uranium Extraction from Seawater Zhao, Shilei; Yuan, Yihui; Yu, Qiuhan Angewandte Chemie, Vol. 131, Issue 42 https://doi.org/10.1002/ange.201908762	journal	September 2019
Iridium complex immobilization on covalent organic framework for effective C—H borylation Vardhan, Harsh; Pan, Yanxiong; Yang, Zhongyu APL Materials, Vol. 7, Issue 10 https://doi.org/10.1063/1.5122674	journal	October 2019
Postsynthetic Covalent Modification in Covalent Organic Frameworks Yusran, Yusran; Fang, Qianrong; Qiu, Shilun Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800066	journal	July 2018
Adsorption behaviours of Th(IV) and U(VI) using nitric acid (HNO ₃ ) modified activated carbon: equilibrium, thermodynamic and kinetic studies Öter, Çiğdem; Selçuk Zorer, Özlem International Journal of Environmental Analytical Chemistry https://doi.org/10.1080/03067319.2019.1691184	journal	November 2019
Isostructural Three-Dimensional Covalent Organic Frameworks Gao, Chao; Li, Jian; Yin, Sheng Angewandte Chemie International Edition, Vol. 58, Issue 29 https://doi.org/10.1002/anie.201905591	journal	June 2019
A Universally Applicable Strategy for Construction of Anti‐Biofouling Adsorbents for Enhanced Uranium Recovery from Seawater Yu, Qiuhan; Yuan, Yihui; Wen, Jun Advanced Science, Vol. 6, Issue 13 https://doi.org/10.1002/advs.201900002	journal	March 2019
A Marine‐Inspired Hybrid Sponge for Highly Efficient Uranium Extraction from Seawater Wang, Dong; Song, Jianan; Lin, Sen Advanced Functional Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adfm.201901009	journal	May 2019
Sunlight Polymerization of Poly(amidoxime) Hydrogel Membrane for Enhanced Uranium Extraction from Seawater Ma, Chunxin; Gao, Jinxiang; Wang, Dong Advanced Science https://doi.org/10.1002/advs.201900085	journal	April 2019
Designed Synthesis of a 2D Porphyrin‐Based sp ² Carbon‐Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis Chen, Rufan; Shi, Ji‐Long; Ma, Yuan Angewandte Chemie, Vol. 131, Issue 19 https://doi.org/10.1002/ange.201902543	journal	February 2019
2D and 3D Porphyrinic Covalent Organic Frameworks: The Influence of Dimensionality on Functionality Meng, Yi; Luo, Yi; Shi, Ji‐Long Angewandte Chemie, Vol. 132, Issue 9 https://doi.org/10.1002/ange.201913091	journal	January 2020
A Dual‐Surface Amidoximated Halloysite Nanotube for High‐Efficiency Economical Uranium Extraction from Seawater Zhao, Shilei; Yuan, Yihui; Yu, Qiuhan Angewandte Chemie International Edition, Vol. 58, Issue 42 https://doi.org/10.1002/anie.201908762	journal	September 2019
Redox‐Active Two‐Dimensional Covalent Organic Frameworks (COFs) for Selective Reductive Separation of Valence‐Variable, Redox‐Sensitive and Long‐Lived Radionuclides Li, Yang; Guo, Xinghua; Li, Xiaofeng Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201916360	journal	January 2020
Tailoring Covalent Organic Frameworks To Capture Water Contaminants Fernandes, Soraia P. S.; Romero, Vanesa; Espiña, Begoña Chemistry – A European Journal, Vol. 25, Issue 26 https://doi.org/10.1002/chem.201806025	journal	February 2019
Designed synthesis of stable light-emitting two-dimensional sp2 carbon-conjugated covalent organic frameworks Jin, Enquan; Li, Juan; Geng, Keyu Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06719-8	journal	October 2018
Symbiotic Aerogel Fibers Made via In-Situ Gelation of Aramid Nanofibers with Polyamidoxime for Uranium Extraction Li, Juan; Wang, Jin; Wang, Wei Molecules, Vol. 24, Issue 9 https://doi.org/10.3390/molecules24091821	journal	May 2019
Three Mechanisms in One Material: Uranium Capture by a Polyoxometalate–Organic Framework through Combined Complexation, Chemical Reduction, and Photocatalytic Reduction Zhang, Hailong; Liu, Wei; Li, Ao Angewandte Chemie, Vol. 131, Issue 45 https://doi.org/10.1002/ange.201909718	journal	September 2019
Amidation, Esterification, and Thioesterification of a Carboxyl‐Functionalized Covalent Organic Framework Guo, Lei; Jia, Shang; Diercks, Christian S. Angewandte Chemie, Vol. 132, Issue 5 https://doi.org/10.1002/ange.201912579	journal	December 2019
Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets Yuan, Yihui; Niu, Biye; Yu, Qiuhan Angewandte Chemie International Edition, Vol. 59, Issue 3 https://doi.org/10.1002/anie.201913644	journal	December 2019
Ultrafast and Highly Selective Uranium Extraction from Seawater by Hydrogel-like Spidroin-based Protein Fiber Yuan, Yihui; Yu, Qiuhan; Wen, Jun Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201906191	journal	July 2019
Three Mechanisms in One Material: Uranium Capture by a Polyoxometalate-Organic Framework through Combined Complexation, Chemical Reduction, and Photocatalytic Reduction Zhang, Hailong; Liu, Wei; Li, Ao Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201909718	journal	September 2019
Amidation, Esterification, and Thioesterification of a Carboxyl‐Functionalized Covalent Organic Framework Guo, Lei; Jia, Shang; Diercks, Christian S. Angewandte Chemie International Edition, Vol. 59, Issue 5 https://doi.org/10.1002/anie.201912579	journal	January 2020
2D and 3D Porphyrinic Covalent Organic Frameworks: The Influence of Dimensionality on Functionality Meng, Yi; Luo, Yi; Shi, Ji‐Long Angewandte Chemie International Edition, Vol. 59, Issue 9 https://doi.org/10.1002/anie.201913091	journal	January 2020
Covalent Organic Frameworks with Chirality Enriched by Biomolecules for Efficient Chiral Separation Zhang, Sainan; Zheng, Yunlong; An, Hongde Angewandte Chemie International Edition, Vol. 57, Issue 51 https://doi.org/10.1002/anie.201810571	journal	November 2018
A Molecular Coordination Template Strategy for Designing Selective Porous Aromatic Framework Materials for Uranyl Capture Yuan, Ye; Meng, Qinghao; Faheem, Muhammad ACS Central Science, Vol. 5, Issue 8 https://doi.org/10.1021/acscentsci.9b00494	journal	July 2019
Sustained Solar H ₂ Evolution from a Thiazolo[5,4- d ]thiazole-Bridged Covalent Organic Framework and Nickel-Thiolate Cluster in Water Biswal, Bishnu P.; Vignolo-González, Hugo A.; Banerjee, Tanmay Journal of the American Chemical Society, Vol. 141, Issue 28 https://doi.org/10.1021/jacs.9b03243	journal	June 2019

Figures / Tables (7)

Similar Records

Covalent Organic Frameworks as a Decorating Platform for Utilization and Affinity Enhancement of Chelating Sites for Radionuclide Sequestration

Journal Article · Thu May 17 00:00:00 EDT 2018 · Advanced Materials · OSTI ID:1435179

Sun, Qi; Aguila, Briana A.; Earl, Lyndsey D.; +4 more

Functionalized Porous Aromatic Framework for Efficient Uranium Adsorption from Aqueous Solutions

Journal Article · Tue Mar 28 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces · OSTI ID:1435179

Li, Baiyan; Sun, Qi; Zhang, Yiming; +4 more

Spatial Engineering Direct Cooperativity between Binding Sites for Uranium Sequestration

Journal Article · Fri Dec 04 00:00:00 EST 2020 · Advanced Science · OSTI ID:1435179

Sun, Qi; Song, Yanpei; Aguila, Briana; +3 more

Related Subjects

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
amidoxime chelating groups
covalent organic frameworks
environmental remediation
radionuclide sequestration
uranium capture