Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces

Wan, Weiming; Tackett, Brian M.; Chen, Jingguang G.

doi:10.1039/C6CS00862C

Title: Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces

Journal Article · Thu Feb 23 00:00:00 EST 2017 · Chemical Society Reviews

DOI:https://doi.org/10.1039/C6CS00862C· OSTI ID:1434771

Wan, Weiming ^[1]; Tackett, Brian M. ^[1];

^[2]

Columbia Univ., New York, NY (United States)
Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States). Biological, Environmental & Climate Sciences Dept.

The formation of carbides can significantly modify the physical and chemical properties of the parent metals. In the current review, we summarize the general trends in the reactions of water and C1 molecules over transition metal carbide (TMC) and metal-modified TMC surfaces and thin films. Although the primary focus of the current review is on the theoretical and experimental studies of reactions of C1 molecules (CO, CO₂, CH₃OH, etc.), the reactions of water will also be reviewed because water plays an important role in many of the C1 transformation reactions. This review is organized by discussing separately thermal reactions and electrochemical reactions, which provides insights into the application of TMCs in heterogeneous catalysis and electrocatalysis, respectively. In thermal reactions, we discuss the thermal decomposition of water and methanol, as well as the reactions of CO and CO₂ over TMC surfaces. In electrochemical reactions, we summarize recent studies in the hydrogen evolution reaction, electrooxidation of methanol and CO, and electroreduction of CO₂. Lastly, future research opportunities and challenges associated with using TMCs as catalysts and electrocatalysts are also discussed.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1434771

Report Number(s):: BNL-203549-2018-JAAM; CSRVBR

Journal Information:: Chemical Society Reviews, Vol. 46, Issue 7; ISSN 0306-0012

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 74 works

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References (138)

Low-temperature water–gas shift reaction over cobalt–molybdenum carbide catalyst Nagai, M.; Matsuda, K. Journal of Catalysis, Vol. 238, Issue 2 https://doi.org/10.1016/j.jcat.2006.01.003	journal	March 2006
Adsorption of Water on TiC(100): Evidence for Complex Reaction and Desorption Pathways Merrill, Philip B.; Perry, Scott S.; Frantz, Peter The Journal of Physical Chemistry B, Vol. 102, Issue 39 https://doi.org/10.1021/jp981982l	journal	September 1998
Reaction of Ethylene with Clean and Carbide-Modified Mo(110): Converting Surface Reactivities of Molybdenum to Pt-Group Metals Frühberger, B.; Chen, J. G. Journal of the American Chemical Society, Vol. 118, Issue 46 https://doi.org/10.1021/ja960656l	journal	January 1996
Chemisorption of CO on NbC(111) at 80 K: Angle‐resolved photoemission study Edamoto, Kazuyuki; Shiobara, Eishi; Anazawa, Toshihisa The Journal of Chemical Physics, Vol. 96, Issue 1 https://doi.org/10.1063/1.462470	journal	January 1992
The adsorption and decomposition of formaldehyde and formic acid on the clean and modified Fe (100) surface Hung, Wei-Hsiu; Bernasek, Steven L. Surface Science, Vol. 346, Issue 1-3 https://doi.org/10.1016/0039-6028(95)00905-1	journal	February 1996
Molecular adsorption of oxygen on transition-metal carbide Aizawa, Takashi; Hayami, Wataru; Souda, Ryutaro Surface Science, Vol. 357-358 https://doi.org/10.1016/0039-6028(96)00238-5	journal	June 1996
In situ gas-phase catalytic properties of TiC-supported size-selected gold nanoparticles synthesized by diblock copolymer encapsulation Ono, L. K.; Sudfeld, D.; Roldan Cuenya, B. Surface Science, Vol. 600, Issue 23 https://doi.org/10.1016/j.susc.2006.08.025	journal	December 2006
Transition metal carbides (WC, Mo2C, TaC, NbC) as potential electrocatalysts for the hydrogen evolution reaction (HER) at medium temperatures Meyer, Simon; Nikiforov, Aleksey V.; Petrushina, Irina M. International Journal of Hydrogen Energy, Vol. 40, Issue 7 https://doi.org/10.1016/j.ijhydene.2014.12.076	journal	February 2015
Small Cluster Models of the Surface Electronic Structure and Bonding Properties of Titanium Carbide, Vanadium Carbide, and Titanium Nitride Didziulis, Stephen V.; Butcher, Kristine D.; Perry, Scott S. Inorganic Chemistry, Vol. 42, Issue 24 https://doi.org/10.1021/ic030140k	journal	December 2003
Substrate-Dependent Reactivity of Water on Metal Carbide Surfaces Didziulis, Stephen V.; Frantz, Peter; Perry, Scott S. The Journal of Physical Chemistry B, Vol. 103, Issue 50 https://doi.org/10.1021/jp9923668	journal	December 1999
Effects of Potassium on the Chemisorption of CO on the Mo ₂ C/Mo(100) Surface Bugyi, L.; Solymosi, F. The Journal of Physical Chemistry B, Vol. 105, Issue 19 https://doi.org/10.1021/jp004350j	journal	May 2001
Effect of cobalt (nickel) content on the catalytic performance of molybdenum carbides in dry-methane reforming Cheng, Jinmin; Huang, Wei Fuel Processing Technology, Vol. 91, Issue 2, p. 185-193 https://doi.org/10.1016/j.fuproc.2009.09.011	journal	February 2010
High Activity Carbide Supported Catalysts for Water Gas Shift Schweitzer, Neil M.; Schaidle, Joshua A.; Ezekoye, Obiefune K. Journal of the American Chemical Society, Vol. 133, Issue 8 https://doi.org/10.1021/ja110705a	journal	March 2011
Theoretical study of methane reforming on molybdenum carbide Tominaga, Hiroyuki; Nagai, Masatoshi Applied Catalysis A: General, Vol. 328, Issue 1 https://doi.org/10.1016/j.apcata.2007.05.011	journal	August 2007
Identifying Different Types of Catalysts for CO ₂ Reduction by Ethane through Dry Reforming and Oxidative Dehydrogenation Porosoff, Marc D.; Myint, Myat Noe Zin; Kattel, Shyam Angewandte Chemie International Edition, Vol. 54, Issue 51 https://doi.org/10.1002/anie.201508128	journal	November 2015
Effects of sulfur on Mo2C and Pt/Mo2C catalysts: Water gas shift reaction Schaidle, Joshua A.; Lausche, Adam C.; Thompson, Levi T. Journal of Catalysis, Vol. 272, Issue 2 https://doi.org/10.1016/j.jcat.2010.04.004	journal	June 2010
Hydrogenation of CO ₂ to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO ₂ Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01755	journal	October 2015
Monolayer bimetallic surfaces: Experimental and theoretical studies of trends in electronic and chemical properties Chen, Jingguang G.; Menning, Carl A.; Zellner, Michael B. Surface Science Reports, Vol. 63, Issue 5 https://doi.org/10.1016/j.surfrep.2008.02.001	journal	May 2008
Enhancing CO Tolerance of Electrocatalysts: Electro-oxidation of CO on WC and Pt-Modified WC Mellinger, Zachary J.; Weigert, Erich C.; Stottlemyer, Alan L. Electrochemical and Solid-State Letters, Vol. 11, Issue 5 https://doi.org/10.1149/1.2844209	journal	January 2008
Comparison of bond scission sequence of methanol on tungsten monocarbide and Pt-modified tungsten monocarbide Stottlemyer, Alan Lee; Liu, Ping; Chen, Jingguang G. The Journal of Chemical Physics, Vol. 133, Issue 10 https://doi.org/10.1063/1.3488056	journal	September 2010
Preparation of a Nickel Molybdenum Carbide Catalyst and Its Activity in the Dry Reforming of Methane Hirose, Taro; Ozawa, Yasushi; Nagai, Masatoshi Chinese Journal of Catalysis, Vol. 32, Issue 5 https://doi.org/10.1016/S1872-2067(10)60185-4	journal	May 2011
Trends in the Exchange Current for Hydrogen Evolution Nørskov, J. K.; Bligaard, T.; Logadottir, A. Journal of The Electrochemical Society, Vol. 152, Issue 3 https://doi.org/10.1149/1.1856988	journal	January 2005
In-situ synthesis of nickel modified molybdenum carbide catalyst for dry reforming of methane Zhang, Anjie; Zhu, Aimin; Chen, Bingbing Catalysis Communications, Vol. 12, Issue 9 https://doi.org/10.1016/j.catcom.2011.01.019	journal	April 2011
Chemistry of SO ₂ , H ₂ S, and CH ₃ SH on Carbide-Modified Mo(110) and Mo ₂ C Powders: Photoemission and XANES Studies Rodriguez, José A.; Dvorak, Joseph; Jirsak, Tomas The Journal of Physical Chemistry B, Vol. 104, Issue 48 https://doi.org/10.1021/jp002792p	journal	December 2000
Correlating NEXAFS characterization of Co–W and Ni–W bimetallic carbide catalysts with reactivity for dry reforming of methane Shao, Huifang; Kugler, Edwin L.; Dadyburjor, Dady B. Applied Catalysis A: General, Vol. 356, Issue 1 https://doi.org/10.1016/j.apcata.2008.11.012	journal	March 2009
Adsorption of O2, Co and CH3OH on NbC (100) and (111) single crystal surfaces by ultraviolet photoelectron spectroscopy Kojima, Isao; Orita, Masahiro; Miyazaki, Eizo Surface Science, Vol. 160, Issue 1 https://doi.org/10.1016/0039-6028(85)91033-7	journal	September 1985
Hydrogen adsorption on model tungsten carbide surfaces Gaston, Nicola; Hendy, Shaun Catalysis Today, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.cattod.2008.10.050	journal	August 2009
Water-Gas-Shift Reaction on Molybdenum Carbide Surfaces: Essential Role of the Oxycarbide Liu, Ping; Rodriguez, José A. The Journal of Physical Chemistry B, Vol. 110, Issue 39 https://doi.org/10.1021/jp0621629	journal	October 2006
Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts Ren, Hui; Yu, Weiting; Salciccioli, Michael ChemSusChem, Vol. 6, Issue 5 https://doi.org/10.1002/cssc.201200991	journal	April 2013
The interaction of water with oxygen-modified ZrC(100) surfaces Kitaoka, H.; Ozawa, K.; Edamoto, K. Solid State Communications, Vol. 118, Issue 1 https://doi.org/10.1016/S0038-1098(01)00037-0	journal	March 2001
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces Sheng, Wenchao; Myint, MyatNoeZin; Chen, Jingguang G. Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee00045a	journal	January 2013
Dry reforming kinetics over a bulk molybdenum carbide catalyst LaMont, David C.; Thomson, William J. Chemical Engineering Science, Vol. 60, Issue 13 https://doi.org/10.1016/j.ces.2005.01.021	journal	July 2005
Production of CO-Free H2 by Formic Acid Decomposition over Mo2C/Carbon Catalysts Koós, Ákos; Solymosi, Frigyes Catalysis Letters, Vol. 138, Issue 1-2 https://doi.org/10.1007/s10562-010-0375-3	journal	June 2010
Interaction of water and methanol with oxygen-modified ZrC() surfaces Kitaoka, H.; Ozawa, K.; Edamoto, K. Surface Science, Vol. 518, Issue 3 https://doi.org/10.1016/S0039-6028(02)02163-5	journal	October 2002
Activity and coke formation of nickel and nickel carbide in dry reforming: A deactivation scheme from density functional theory Wang, Ziyun; Cao, X. -M.; Zhu, Jinghao Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.12.015	journal	March 2014
Hydrogen evolution reaction (HER) at thin film and bulk TiC electrodes Ferri, T.; Gozzi, D.; Latini, A. International Journal of Hydrogen Energy, Vol. 32, Issue 18 https://doi.org/10.1016/j.ijhydene.2007.08.003	journal	December 2007
Hydrogen evolution activity and electrochemical stability of selected transition metal carbides in concentrated phosphoric acid Tomás-García, Antonio Luis; Jensen, Jens Oluf; Bjerrum, Niels J. Electrochimica Acta, Vol. 137 https://doi.org/10.1016/j.electacta.2014.06.087	journal	August 2014
Theoretical prediction and experimental verification of low loading of platinum on titanium carbide as low-cost and stable electrocatalysts Kimmel, Yannick C.; Yang, Leerang; Kelly, Thomas G. Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.02.002	journal	April 2014
Trends in the chemical properties of early transition metal carbide surfaces: A density functional study Kitchin, John R.; Nørskov, Jens K.; Barteau, Mark A. Catalysis Today, Vol. 105, Issue 1 https://doi.org/10.1016/j.cattod.2005.04.008	journal	July 2005
Theoretical Study of the Interaction of CO on TiC(001) and Au Nanoparticles Supported on TiC(001): Probing the Nature of the Au/TiC Interface Asara, Gian Giacomo; Feria, Leticia; Florez, Elizabeth The Journal of Physical Chemistry C, Vol. 115, Issue 45 https://doi.org/10.1021/jp207770u	journal	October 2011
The Carburization of Transition Metal Molybdates (MxMoO4, M = Cu, Ni or Co) and the Generation of Highly Active Metal/Carbide Catalysts for CO2 Hydrogenation Xu, Wenqian; Ramírez, Pedro J.; Stacchiola, Dario Catalysis Letters, Vol. 145, Issue 7 https://doi.org/10.1007/s10562-015-1540-5	journal	May 2015
CO and O2 adsorption on α-Mo2C (0001) St. Clair, Todd P.; Oyama, S. Ted; Cox, David F. Surface Science, Vol. 468, Issue 1-3 https://doi.org/10.1016/S0039-6028(00)00763-9	journal	November 2000
Metal-modified niobium carbides as low-cost and impurity-resistant electrocatalysts for hydrogen evolution in acidic and alkaline electrolytes Tackett, Brian M.; Kimmel, Yannick C.; Chen, Jingguang G. International Journal of Hydrogen Energy, Vol. 41, Issue 14 https://doi.org/10.1016/j.ijhydene.2016.01.167	journal	April 2016
Reactions of methanol and water over carbide-modified Mo() Hwu, Henry H.; Chen, Jingguang G. Surface Science, Vol. 536, Issue 1-3 https://doi.org/10.1016/S0039-6028(03)00607-1	journal	June 2003
Carbide and Nitride Overlayers on Early Transition Metal Surfaces: Preparation, Characterization, and Reactivities Chen, Jingguang G. Chemical Reviews, Vol. 96, Issue 4 https://doi.org/10.1021/cr950232u	journal	January 1996
The chemical and electronic properties of oxygen-modified C/Mo(110): a model system for molybdenum oxycarbides Hwu, H.; Zellner, M.; Chen, J. Journal of Catalysis, Vol. 229, Issue 1 https://doi.org/10.1016/j.jcat.2004.09.014	journal	January 2005
Frictional properties of titanium carbide, titanium nitride, and vanadium carbide: Measurement of a compositional dependence with atomic force microscopy Lee, Seunghwan; El-bjeirami, Oussama; Perry, Scott S. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 18, Issue 1 https://doi.org/10.1116/1.591153	journal	January 2000
Effect of surface carbon on the hydrogen evolution reactivity of tungsten carbide (WC) and Pt-modified WC electrocatalysts Kimmel, Yannick C.; Esposito, Daniel V.; Birkmire, Robert W. International Journal of Hydrogen Energy, Vol. 37, Issue 4 https://doi.org/10.1016/j.ijhydene.2011.11.079	journal	February 2012
Glycolaldehyde as a Probe Molecule for Biomass Derivatives: Reaction of C—OH and C═O Functional Groups on Monolayer Ni Surfaces Yu, Weiting; Barteau, Mark A.; Chen, Jingguang G. Journal of the American Chemical Society, Vol. 133, Issue 50 https://doi.org/10.1021/ja208786f	journal	December 2011
The decomposition of formic acid on W(100) and W(100)?(5 $times; 1) C surfaces Benziger, J. Journal of Catalysis, Vol. 58, Issue 1 https://doi.org/10.1016/0021-9517(79)90253-7	journal	June 1979
Surface Chemistry of Transition Metal Carbides Hwu, Henry H.; Chen, Jingguang G. Chemical Reviews, Vol. 105, Issue 1 https://doi.org/10.1021/cr0204606	journal	January 2005
Engineering Transition-Metal-Coated Tungsten Carbides for Efficient and Selective Electrochemical Reduction of CO ₂ to Methane Wannakao, Sippakorn; Artrith, Nongnuch; Limtrakul, Jumras ChemSusChem, Vol. 8, Issue 16 https://doi.org/10.1002/cssc.201500245	journal	July 2015
Self-assembly of noble metal monolayers on transition metal carbide nanoparticle catalysts Hunt, S. T.; Milina, M.; Alba-Rubio, A. C. Science, Vol. 352, Issue 6288 https://doi.org/10.1126/science.aad8471	journal	May 2016
Electrochemical Stability of Tungsten and Tungsten Monocarbide (WC) Over Wide pH and Potential Ranges Weidman, Mark C.; Esposito, Daniel V.; Hsu, Irene J. Journal of The Electrochemical Society, Vol. 157, Issue 12 https://doi.org/10.1149/1.3491341	journal	January 2010
Effect of Temperature on Structure and Performance of In-House Cobalt−Tungsten Carbide Catalyst for Dry Reforming of Methane Shao, Huifang; Kugler, Edwin L.; Ma, Wenping Industrial & Engineering Chemistry Research, Vol. 44, Issue 14 https://doi.org/10.1021/ie049186r	journal	July 2005
Surface chemistry of transition metal carbides: a theoretical analysis Jansen, Susan A.; Hoffmann, Roald Surface Science, Vol. 197, Issue 3 https://doi.org/10.1016/0039-6028(88)90641-3	journal	January 1988
A Combined Surface Science and Electrochemical Study of Tungsten Carbides as Anode Electrocatalysts Weigert, Erich C.; Zellner, Michael B.; Stottlemyer, Alan L. Topics in Catalysis, Vol. 46, Issue 3-4 https://doi.org/10.1007/s11244-007-9006-7	journal	November 2007
Electrocatalytic activity of some carburised nickel, tungsten and molybdenum compounds Barnett, C. J.; Burstein, G. T.; Kucernak, A. R. J. Electrochimica Acta, Vol. 42, Issue 15 https://doi.org/10.1016/S0013-4686(96)00425-2	journal	January 1997
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Rotating disk electrode measurements of activity and stability of monolayer Pt on tungsten carbide disks for oxygen reduction reaction Hsu, Irene J.; Kimmel, Yannick C.; Dai, Yu Journal of Power Sources, Vol. 199 https://doi.org/10.1016/j.jpowsour.2011.10.024	journal	February 2012
Potential Application of Tungsten Carbides as Electrocatalysts: 4. Reactions of Methanol, Water, and Carbon Monoxide over Carbide-Modified W(110) Hwu, Henry H.; Chen, Jingguang G. The Journal of Physical Chemistry B, Vol. 107, Issue 9 https://doi.org/10.1021/jp0269118	journal	March 2003
Spectroscopic characterization of thin vanadium carbide films on a vanadium (110) surface: Formation, stability, and reactivities Chen, J. G.; DeVries, B. D.; Frühberger, B. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3 https://doi.org/10.1116/1.579735	journal	May 1995
Core-shell structured tungsten–tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation Obradović, M. D.; Babić, B. M.; Radmilović, V. R. International Journal of Hydrogen Energy, Vol. 37, Issue 14 https://doi.org/10.1016/j.ijhydene.2012.04.114	journal	July 2012
Electron spectroscopic study of the interaction of WC(0001) with different adsorbates (C6H6, CO and NO) Brillo, J.; Sur, R.; Kuhlenbeck, H. Journal of Electron Spectroscopy and Related Phenomena, Vol. 88-91 https://doi.org/10.1016/S0368-2048(97)00214-4	journal	March 1998
Effect of carbon modification on a vanadium(110) surface: observation of surface reactivities characteristics of platinum-group metals Chen, J. G.; Weisel, M. D.; Liu, Z. M. Journal of the American Chemical Society, Vol. 115, Issue 19 https://doi.org/10.1021/ja00072a065	journal	September 1993
Reactions of methanol on W(100) and W(100)-(5 $times; 1)C surfaces Ko, E. Journal of Catalysis, Vol. 62, Issue 2 https://doi.org/10.1016/0021-9517(80)90454-6	journal	April 1980
Interaction of O2 with WC(0001) Brillo, J.; Kuhlenbeck, H.; Freund, H. -J Surface Science, Vol. 409, Issue 2 https://doi.org/10.1016/S0039-6028(98)00193-9	journal	July 1998
Evidence for nitrile hydrogenation on tungsten(100)-(5 .times. 1)-carbon: spectroscopic studies of surface intermediates derived from hydrogen cyanide Serafin, J. G.; Friend, C. M. The Journal of Physical Chemistry, Vol. 92, Issue 23 https://doi.org/10.1021/j100334a041	journal	November 1988
New Catalysts for the Conversion of Methane to Synthesis Gas: Molybdenum and Tungsten Carbide Claridge, John B.; York, Andrew P. E.; Brungs, Attila J. Journal of Catalysis, Vol. 180, Issue 1 https://doi.org/10.1006/jcat.1998.2260	journal	November 1998
Trends in Hydrogen Evolution Activity of Metal-Modified Molybdenum Carbides in Alkaline and Acid Electrolytes Zhang, Qian; Tackett, Brian M.; Wu, Qiyuan ChemElectroChem, Vol. 3, Issue 10 https://doi.org/10.1002/celc.201600171	journal	May 2016
Fundamentals of Methanol Synthesis on Metal Carbide Based Catalysts: Activation of CO2 and H2 Posada-Pérez, Sergio; Viñes, Francesc; Rodriguez, José A. Topics in Catalysis, Vol. 58, Issue 2-3 https://doi.org/10.1007/s11244-014-0355-8	journal	December 2014
Identifying trends and descriptors for selective CO ₂ conversion to CO over transition metal carbides Porosoff, Marc D.; Kattel, Shyam; Li, Wenhui Chemical Communications, Vol. 51, Issue 32 https://doi.org/10.1039/C5CC01545F	journal	January 2015
Electrochemical reduction of carbon dioxides to carbon monoxide at a gold electrode in aqueous potassium hydrogen carbonate Hori, Yoshio; Murata, Akira; Kikuchi, Katsuhei Journal of the Chemical Society, Chemical Communications, Issue 10 https://doi.org/10.1039/c39870000728	journal	January 1987
Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO ₂ to CO Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal Angewandte Chemie International Edition, Vol. 53, Issue 26 https://doi.org/10.1002/anie.201404109	journal	May 2014
SECM characterization of Pt–Ru–WC and Pt–Ru–Co ternary thin film combinatorial libraries as anode electrocatalysts for PEMFC Lu, Guojin; Cooper, James S.; McGinn, Paul J. Journal of Power Sources, Vol. 161, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.04.089	journal	October 2006
Kinetic study of a ceria-promoted <mml:math altimg="si34.gif" display="inline" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd"><mml:msub><mml:mrow><mml:mi>Mo</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi>γ</mml:mi><mml:mtext>-</mml:mtext><mml:msub><mml:mrow><mml:mi>Al</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:math> catalyst in dry-methane reforming Darujati, Anna R. S.; Thomson, William J. Chemical Engineering Science, Vol. 61, Issue 13 https://doi.org/10.1016/j.ces.2006.02.007	journal	July 2006
Surface science and electrochemical studies of WC and W2C PVD films as potential electrocatalysts Zellner, Michael B.; Chen, Jingguang G. Catalysis Today, Vol. 99, Issue 3-4 https://doi.org/10.1016/j.cattod.2004.10.004	journal	January 2005
Mechanistic study on the methane activation over various supported molybdenum carbide catalysts with isotopic tracer methods Naito, Shuichi; Takada, Akiko; Tokizawa, Satoshi Applied Catalysis A: General, Vol. 289, Issue 1 https://doi.org/10.1016/j.apcata.2005.04.011	journal	August 2005
Selective decomposition of formic acid on molybdenum carbide: A new reaction pathway Flaherty, David W.; Berglund, Sean P.; Mullins, C. Buddie Journal of Catalysis, Vol. 269, Issue 1 https://doi.org/10.1016/j.jcat.2009.10.012	journal	January 2010
Exploring the activity of a novel Au/TiC(001) model catalyst towards CO and CO2 hydrogenation Asara, Gian Giacomo; Ricart, Josep M.; Rodriguez, Jose A. Surface Science, Vol. 640 https://doi.org/10.1016/j.susc.2015.01.018	journal	October 2015
Low-Cost Hydrogen-Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates Esposito, Daniel V.; Hunt, Sean T.; Stottlemyer, Alan L. Angewandte Chemie International Edition, Vol. 49, Issue 51 https://doi.org/10.1002/anie.201004718	journal	September 2010
Synthesis, characterization and surface reactivity of tungsten carbide (WC) PVD films Zellner, Michael B.; Chen, Jingguang G. Surface Science, Vol. 569, Issue 1-3 https://doi.org/10.1016/j.susc.2004.07.029	journal	October 2004
Understanding the Low-Overpotential Production of CH ₄ from CO ₂ on Mo ₂ C Catalysts Kim, Seok Ki; Zhang, Yin-Jia; Bergstrom, Helen ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02424	journal	February 2016
Monolayer platinum supported on tungsten carbides as low-cost electrocatalysts: opportunities and limitations Esposito, Daniel V.; Chen, Jingguang G. Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01851e	journal	January 2011
Comparison of electrochemical stability of transition metal carbides (WC, W2C, Mo2C) over a wide pH range Weidman, Mark C.; Esposito, Daniel V.; Hsu, Yeh-Chun Journal of Power Sources, Vol. 202 https://doi.org/10.1016/j.jpowsour.2011.10.093	journal	March 2012
Methanol Oxidation Reaction on α-Tungsten Carbide Versus Platinum (1 1 1) Surfaces: A DFT Electrochemical Study Di Valentin, Cristiana; Fittipaldi, Diego; Pacchioni, Gianfranco ChemCatChem, Vol. 7, Issue 21 https://doi.org/10.1002/cctc.201500646	journal	September 2015
Molybdenum carbide catalysed hydrogen production from formic acid – A density functional theory study Luo, Qiquan; Wang, Tao; Walther, Guido Journal of Power Sources, Vol. 246 https://doi.org/10.1016/j.jpowsour.2013.07.102	journal	January 2014
The bending machine: CO ₂ activation and hydrogenation on δ-MoC(001) and β-Mo ₂ C(001) surfaces Posada-Pérez, Sergio; Viñes, Francesc; Ramirez, Pedro J. Phys. Chem. Chem. Phys., Vol. 16, Issue 28 https://doi.org/10.1039/C4CP01943A	journal	January 2014
A New Class of Electrocatalysts for Hydrogen Production from Water Electrolysis: Metal Monolayers Supported on Low-Cost Transition Metal Carbides Esposito, Daniel V.; Hunt, Sean T.; Kimmel, Yannick C. Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja208656v	journal	February 2012
Spectroscopic study on the formation of CO−2 on K-promoted Mo2C/Mo(100) surface Bugyi, László; Oszkó, Albert; Solymosi, Frigyes Surface Science, Vol. 461, Issue 1-3 https://doi.org/10.1016/S0039-6028(00)00575-6	journal	August 2000
Extended X-ray Absorption Fine Structure and X-ray Diffraction Examination of Sputtered Nickel Carbon Binary Thin Films for Fuel Cell Applications Ingham, Bridget; Gaston, Nicola; Fahy, Kieran The Journal of Physical Chemistry C, Vol. 116, Issue 10 https://doi.org/10.1021/jp207308g	journal	March 2012
Interaction of CO and NO with WC(0001) Brillo, J.; Sur, R.; Kuhlenbeck, H. Surface Science, Vol. 397, Issue 1-3 https://doi.org/10.1016/S0039-6028(97)00725-5	journal	February 1998
High activity PtPd-WC/C electrocatalyst for hydrogen evolution reaction Wu, Mei; Shen, Pei Kang; Wei, Zidong Journal of Power Sources, Vol. 166, Issue 2, p. 310-316 https://doi.org/10.1016/j.jpowsour.2006.12.108	journal	April 2007
Metal overlayer on metal carbide substrate: unique bimetallic properties for catalysis and electrocatalysis Kelly, Thomas G.; Chen, Jingguang G. Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35165j	journal	January 2012
Potential application of tungsten carbides as electrocatalysts III. Reactions of methanol, water, and hydrogen on Pt-modified C/W(111) surfaces Liu, N. Journal of Catalysis, Vol. 215, Issue 2 https://doi.org/10.1016/S0021-9517(03)00019-8	journal	April 2003
RAIRS and TPD study of CO and NO on β-Mo2C Wang, J.; Castonguay, M.; Deng, J. Surface Science, Vol. 374, Issue 1-3 https://doi.org/10.1016/S0039-6028(96)01228-9	journal	March 1997
Methanol electro-oxidation on platinum modified tungsten carbides in direct methanol fuel cells: a DFT study Sheng, Tian; Lin, Xiao; Chen, Zhao-Yang Physical Chemistry Chemical Physics, Vol. 17, Issue 38 https://doi.org/10.1039/C5CP02072G	journal	January 2015
Pt-modified molybdenum carbide for the hydrogen evolution reaction: From model surfaces to powder electrocatalysts Kelly, Thomas G.; Lee, Kevin X.; Chen, Jingguang G. Journal of Power Sources, Vol. 271 https://doi.org/10.1016/j.jpowsour.2014.07.179	journal	December 2014
Comparative studies of methanol decomposition on carbide-modified V(110) and Ti(0001) Zellner, Michael B.; Hwu, Henry H.; Chen, Jingguang G. Surface Science, Vol. 598, Issue 1-3 https://doi.org/10.1016/j.susc.2005.09.027	journal	December 2005
Effects of adsorbed carbon and oxygen on the chemisorption of H2 and Co on Mo(100) Ko, E. I.; Madix, R. J. Surface Science, Vol. 109, Issue 1 https://doi.org/10.1016/0039-6028(81)90521-5	journal	August 1981
Potential Application of Tungsten Carbides as Electrocatalysts. 1. Decomposition of Methanol over Carbide-Modified W(111) Hwu, Henry H.; Chen, Jingguang G.; Kourtakis, Kostantinos The Journal of Physical Chemistry B, Vol. 105, Issue 41 https://doi.org/10.1021/jp0116196	journal	October 2001
Trends in Electrochemical Stability of Transition Metal Carbides and Their Potential Use As Supports for Low-Cost Electrocatalysts Kimmel, Yannick C.; Xu, Xiaoge; Yu, Weiting ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs500182h	journal	April 2014
Cyclic voltammetry and X-ray photoelectron spectroscopy studies of electrochemical stability of clean and Pt-modified tungsten and molybdenum carbide (WC and Mo2C) electrocatalysts Weigert, Erich C.; Esposito, Daniel V.; Chen, Jingguang G. Journal of Power Sources, Vol. 193, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.04.020	journal	September 2009
Adsorption of methanol on ZrC(100) and (111) surfaces Nakane, T.; Noda, T.; Ozawa, K. Surface Science, Vol. 433-435 https://doi.org/10.1016/S0039-6028(99)00055-2	journal	August 1999
Low loadings of platinum on transition metal carbides for hydrogen oxidation and evolution reactions in alkaline electrolytes Wang, Lu; Mahoney, Elizabeth G.; Zhao, Shen Chemical Communications, Vol. 52, Issue 18 https://doi.org/10.1039/C5CC10439D	journal	January 2016
Pd-Modified Tungsten Carbide for Methanol Electro-oxidation: From Surface Science Studies to Electrochemical Evaluation Mellinger, Zachary J.; Kelly, Thomas G.; Chen, Jingguang G. ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs200620x	journal	April 2012
Decomposition of formic acid on Ni(100)-p(2 × 2)C Ko, E. I.; Madix, R. J. Applications of Surface Science, Vol. 3, Issue 2 https://doi.org/10.1016/0378-5963(79)90023-0	journal	September 1979
Density Functional Theory of Water−Gas Shift Reaction on Molybdenum Carbide Tominaga, Hiroyuki; Nagai, Masatoshi The Journal of Physical Chemistry B, Vol. 109, Issue 43 https://doi.org/10.1021/jp053706u	journal	November 2005
Theoretical Model for CO Adsorption and Dissociation on Clean and K-Doped β-Mo ₂ C Surfaces Pistonesi, Carolina; Pronsato, María Estela; Bugyi, László The Journal of Physical Chemistry C, Vol. 116, Issue 46 https://doi.org/10.1021/jp3069317	journal	November 2012
Potential Application of Tungsten Carbides as Electrocatalysts. 2. Coadsorption of CO and H ₂ O on Carbide-Modified W(111) Hwu, Henry H.; Polizzotti, Brian D.; Chen, Jingguang G. The Journal of Physical Chemistry B, Vol. 105, Issue 41 https://doi.org/10.1021/jp0116205	journal	October 2001
Monolayer palladium supported on molybdenum and tungsten carbide substrates as low-cost hydrogen evolution reaction (HER) electrocatalysts Kelly, Thomas G.; Hunt, Sean T.; Esposito, Daniel V. International Journal of Hydrogen Energy, Vol. 38, Issue 14 https://doi.org/10.1016/j.ijhydene.2013.02.116	journal	May 2013
Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO ₂ Reduction to CO Hansen, Heine A.; Varley, Joel B.; Peterson, Andrew A. The Journal of Physical Chemistry Letters, Vol. 4, Issue 3 https://doi.org/10.1021/jz3021155	journal	January 2013
CO2 hydrogenation on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane Rodriguez, José A.; Evans, Jaime; Feria, Leticia Journal of Catalysis, Vol. 307 https://doi.org/10.1016/j.jcat.2013.07.023	journal	November 2013
The Mechanism of the Cathodic Hydrogen Evolution Reaction Bockris, J. O'M.; Potter, E. C. Journal of The Electrochemical Society, Vol. 99, Issue 4 https://doi.org/10.1149/1.2779692	journal	January 1952
CO ₂ Activation and Methanol Synthesis on Novel Au/TiC and Cu/TiC Catalysts Vidal, Alba B.; Feria, Leticia; Evans, Jaime The Journal of Physical Chemistry Letters, Vol. 3, Issue 16 https://doi.org/10.1021/jz300989e	journal	August 2012
Formation and reactions of CH₃ species over Mo₂C/Mo(111) surface Solymosi, F.; Bugyi, L.; Oszkó, A. Catalysis Letters, Vol. 57, Issue 3, p. 103-107 https://doi.org/10.1023/A:1019095515497	journal	January 1999
Pt/WC as an anode catalyst for PEMFC: Activity and CO tolerance Ham, Dong Jin; Kim, Young Kwon; Han, Seung Hyun Catalysis Today, Vol. 132, Issue 1-4 https://doi.org/10.1016/j.cattod.2007.12.076	journal	March 2008
Potential application of tungsten carbides as electrocatalysts Hwu, Henry H.; Chen, Jiangguang G. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 21, Issue 4 https://doi.org/10.1116/1.1582457	journal	July 2003
Potential Application of Tungsten Carbides as Electrocatalysts: Synergistic Effect by Supporting Pt on C∕W(110) for the Reactions of Methanol, Water, and CO Zellner, Michael B.; Chen, Jingguang G. Journal of The Electrochemical Society, Vol. 152, Issue 8 https://doi.org/10.1149/1.1938107	journal	January 2005
Comparison of O−H, C−H, and C−O Bond Scission Sequence of Methanol on Tungsten Carbide Surfaces Modified by Ni, Rh, and Au Kelly, Thomas G.; Stottlemyer, Alan L.; Ren, Hui The Journal of Physical Chemistry C, Vol. 115, Issue 14 https://doi.org/10.1021/jp112006v	journal	March 2011
Tungsten carbide microsphere as an electrode for cathodic hydrogen evolution from water Ham, D.; Ganesan, R.; Lee, J. International Journal of Hydrogen Energy, Vol. 33, Issue 23 https://doi.org/10.1016/j.ijhydene.2008.05.045	journal	December 2008
Modification of the surface reactivity of Mo(110) upon carbide formation Frühberger, B.; Chen, J. G. Surface Science, Vol. 342, Issue 1-3 https://doi.org/10.1016/0039-6028(95)00837-3	journal	November 1995
Bonding and adsorption structure of CO on W(100)‐(5×1)–C Friend, C. M.; Serafin, J. G.; Baldwin, E. K. The Journal of Chemical Physics, Vol. 87, Issue 3 https://doi.org/10.1063/1.453198	journal	August 1987
Reaction of Methanol with TiC and VC (100) Surfaces Frantz, Peter; Didziulis, Stephen V.; Fernandez-Torres, Luis C. The Journal of Physical Chemistry B, Vol. 106, Issue 25 https://doi.org/10.1021/jp0145311	journal	June 2002
Reactions of oxygen-containing molecules on transition metal carbides: Surface science insight into potential applications in catalysis and electrocatalysis Stottlemyer, Alan L.; Kelly, Thomas G.; Meng, Qinghe Surface Science Reports, Vol. 67, Issue 9-10 https://doi.org/10.1016/j.surfrep.2012.07.001	journal	September 2012
Reactions of formaldehyde on W(100) and W(100)-(5 $times; 1)C Benziger, J. Journal of Catalysis, Vol. 64, Issue 1 https://doi.org/10.1016/0021-9517(80)90486-8	journal	July 1980
Departures from the Adsorption Energy Scaling Relations for Metal Carbide Catalysts Michalsky, Ronald; Zhang, Yin-Jia; Medford, Andrew J. The Journal of Physical Chemistry C, Vol. 118, Issue 24 https://doi.org/10.1021/jp503756g	journal	June 2014
Effects of potassium on the adsorption and dissociation pathways of methanol and ethanol on Mo2C/Mo(100) Farkas, A. P.; Solymosi, F. Surface Science, Vol. 602, Issue 7 https://doi.org/10.1016/j.susc.2008.02.010	journal	April 2008
Alteration in surface reaction selectivity of nitriles. 1. Hydrogen cyanide on tungsten(100) and tungsten(100)-(5.times.1)-carbon Pearlstine, K. A.; Friend, C. M. The Journal of Physical Chemistry, Vol. 90, Issue 18 https://doi.org/10.1021/j100409a024	journal	August 1986
Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis Levy, R. B.; Boudart, M. Science, Vol. 181, Issue 4099 https://doi.org/10.1126/science.181.4099.547	journal	August 1973
Generation and Reactions of CH2 and C2H5 Species on Mo2C/Mo(111) Surface Solymosi, F.; Bugyi, L.; Oszkó, A. Journal of Catalysis, Vol. 185, Issue 1 https://doi.org/10.1006/jcat.1999.2491	journal	July 1999
Is platinum necessary for efficient hydrogen evolution? – DFT study of metal monolayers on tungsten carbide Vasić Anićijević, Dragana D.; Nikolić, Vladimir M.; Marčeta-Kaninski, Milica P. International Journal of Hydrogen Energy, Vol. 38, Issue 36 https://doi.org/10.1016/j.ijhydene.2013.09.079	journal	December 2013
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts Yu, Weiting; Porosoff, Marc D.; Chen, Jingguang G. Chemical Reviews, Vol. 112, Issue 11, p. 5780-5817 https://doi.org/10.1021/cr300096b	journal	August 2012
Adsorption of methanol on TiC(100) and (111) surfaces Edamoto, K.; Nakane, T.; Noda, T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 88-91 https://doi.org/10.1016/S0368-2048(97)00212-0	journal	March 1998
Tungsten Monocarbide as Potential Replacement of Platinum for Methanol Electrooxidation Weigert, Erich C.; Stottlemyer, Alan L.; Zellner, Michael B. The Journal of Physical Chemistry C, Vol. 111, Issue 40 https://doi.org/10.1021/jp075504z	journal	October 2007
Preparation and catalytic properties of transition metal carbides and nitrides Oyama, S. T. Catalysis Today, Vol. 15, Issue 2 https://doi.org/10.1016/0920-5861(92)80175-M	journal	June 1992
Stability of supported and promoted-molybdenum carbide catalysts in dry-methane reforming Darujati, Anna R. S.; Thomson, William J. Applied Catalysis A: General, Vol. 296, Issue 2 https://doi.org/10.1016/j.apcata.2005.07.057	journal	December 2005
Coordination Chemistry of Transition Metal Carbide Surfaces: Detailed Spectroscopic and Theoretical Investigations of CO Adsorption on TiC and VC (100) Surfaces Didziulis, Stephen V.; Frantz, Peter; Fernandez-Torres, Luis C. The Journal of Physical Chemistry B, Vol. 105, Issue 22 https://doi.org/10.1021/jp003249b	journal	June 2001

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