Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo -Metalated Amides
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journal
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August 2015 |
Synthesis, Structure, and Reactivity of the Sterically Crowded Th 3+ Complex (C 5 Me 5 ) 3 Th Including Formation of the Thorium Carbonyl, [(C 5 Me 5 ) 3 Th(CO)][BPh 4 ]
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journal
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February 2017 |
Molecular Single-Bond Covalent Radii for Elements 1-118
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journal
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January 2009 |
New vistas in the molecular chemistry of thorium: low oxidation state complexes
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journal
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January 2016 |
Probing the Coordinative Unsaturation and Local Environment of Ti 3+ Sites in an Activated High-Yield Ziegler-Natta Catalyst
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journal
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February 2015 |
Expanding Thorium Hydride Chemistry Through Th 2+ , Including the Synthesis of a Mixed-Valent Th 4+ /Th 3+ Hydride Complex
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journal
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March 2016 |
A Comparison of 4 f vs 5 f Metal−Metal Bonds in (CpSiMe 3 ) 3 M−ECp* (M = Nd, U; E = Al, Ga; Cp* = C 5 Me 5 ): Synthesis, Thermodynamics, Magnetism, and Electronic Structure
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September 2009 |
Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy
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journal
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December 2016 |
Dinitrogen Activation at Iron and Cobalt Metallalumatranes
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July 2013 |
Importance of Energy Level Matching for Bonding in Th 3+ -Am 3+ Actinide Metallocene Amidinates, (C 5 Me 5 ) 2 [ i PrNC(Me)N i Pr]An
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journal
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November 2010 |
Uranium and thorium complexes of the phosphaethynolate ion
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journal
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January 2015 |
Bonding of tris(.eta.5-cyclopentadienyl)-actinide complexes. 3. Interaction of .pi.-neutral, .pi.-acidic, and .pi.-basic ligands with (.eta.5-C5H5)3U
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journal
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April 1989 |
Arene-ligated heteroleptic terphenolate complexes of thorium
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January 2014 |
Si–H addition followed by C–H bond activation induced by a terminal thorium imido metallocene: a combined experimental and computational study
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journal
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January 2014 |
Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals
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journal
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January 2017 |
Sterically Demanding Aryloxides as Supporting Ligands in Organoactinide Chemistry. Synthesis, Structural Characterization, and Reactivity of Th(O-2,6- t -Bu 2 C 6 H 3 ) 2 (CH 2 SiMe 3 ) 2 and Formation of the Trimeric Thorium Hydride Th 3 H 6 (O-2,6- t -Bu 2 C 6 H 3 ) 6
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journal
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January 1996 |
Does covalency really increase across the 5f series? A comparison of molecular orbital, natural population, spin and electron density analyses of AnCp 3 (An = Th–Cm; Cp = η 5 -C 5 H 5 )
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journal
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January 2011 |
Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding
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May 2014 |
Formation of a Bridging Phosphinidene Thorium Complex
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journal
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November 2015 |
Use of 77 Se and 125 Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(E n ){N(SiMe 3 ) 2 } 3 ] − (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners
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journal
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January 2016 |
Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu)
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journal
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November 2001 |
Elucidating bonding preferences in tetrakis(imido)uranate(VI) dianions
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journal
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April 2017 |
Ca(BH4)2 as a simple tool for the preparation of thorium and uranium metallocene borohydride complexes: First synthesis and crystal structure of (C5Me5)2Th(η3-H3BH)2
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journal
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March 2017 |
Photochemical Route to Actinide-Transition Metal Bonds: Synthesis, Characterization and Reactivity of a Series of Thorium and Uranium Heterobimetallic Complexes
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journal
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February 2014 |
Covalency in f-element complexes
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journal
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January 2013 |
Bis(permethylindenyl) Complexes of Thorium: Synthesis, Structure, and Reactivity
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journal
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July 2001 |
Synthesis of the First Tris(pentamethylcyclopentadienyl) Hydride Complex, (C 5 Me 5 ) 3 ThH
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journal
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December 2001 |
Expanding the chemistry of U3+ reducing agents
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journal
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April 2006 |
Revisiting the Chemistry of the Actinocenes [(η 8 -C 8 H 8 ) 2 An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η 8 -C 8 H 8 ) 2 An(L)] with Thorium (L = py, 4,4′-bipy, t BuNC, R 4 phen)
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journal
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June 2013 |
The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C 5 H 3 (SiMe 3 ) 2 } 3 ]; the first thorium( III ) crystal structure
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journal
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January 1986 |
Uranium-mediated activation of small molecules
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journal
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January 2011 |
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning
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journal
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June 2012 |
A Linear, O-Coordinated 1-CO2 Bound to Uranium
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journal
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September 2004 |
Chloro-, methyl-, and (tetrahydroborato)tris((hexamethyldisilyl)amido)thorium(IV) and uranium(IV). Crystal structure of (tetrahydroborato)tris((hexamethyldisilyl)amido)thorium(IV)
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journal
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May 1979 |
Metal–metal bonding in molecular actinide compounds: electronic structure of [M 2 X 8 ] 2− (M = U, Np, Pu; X = Cl, Br, I) complexes and comparison with d-block analogues
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journal
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January 2006 |
Isolation and characterization of a uranium(VI)–nitride triple bond
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journal
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May 2013 |
Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes
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journal
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December 2008 |
[Al t Bu] −6: EPR Spectroscopic Evidence and Ab Initio Calculations
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journal
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October 1993 |
Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory
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journal
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September 2009 |
Electron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (II-III) oxidation potential for each member of the lanthanide and actinide series
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journal
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June 1973 |
A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes
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journal
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August 2016 |
The He-I photoelectron spectra of uranocene and thorocene
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journal
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May 1976 |
Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium: A Structural Comparison with the Uranium Analogue
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journal
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July 1999 |
Molecular Structure of an Unusual Organoactinide Hydride Complex Determined Solely by Neutron Diffraction
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journal
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January 1979 |
Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η 5 -C 5 Me 3 H(CH 2 )- κC ] 2– Tuck-over Ligands in a Tetrathorium Octahydride Complex
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journal
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October 2013 |
Comparison of the Reactivity of 2-Li-C 6 H 4 CH 2 NMe 2 with MCl 4 (M=Th, U): Isolation of a Thorium Aryl Complex or a Uranium Benzyne Complex
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journal
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August 2013 |
Experimental and Computational Studies on the Formation of Thorium-Copper Heterobimetallics
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journal
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August 2016 |
Energy Decomposition Analysis of Metal−Metal Bonding in [M 2 X 8 ] 2- (X = Cl, Br) Complexes of 5f (U, Np, Pu), 5d (W, Re, Os), and 4d (Mo, Tc, Ru) Elements
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journal
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April 2007 |
A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium–Carbon Bonds
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April 2017 |
The vitality of uranium molecular chemistry at the dawn of the XXIst century
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journal
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January 2006 |
Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl 2 (R 2 bpy) 2 (R = Me, t Bu) and U(NAr)Cl 2 (tppo) 3
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journal
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August 2014 |
New evidence for 5f covalency in actinocenes determined from carbon K-edge XAS and electronic structure theory
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journal
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January 2014 |
Metal-metal bonds involving actinides. Synthesis and characterization of a complex having an unsupported actinide to transition metal bond
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December 1985 |
Synthesis, structure, and catalytic activity of an organothorium hydride complex
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journal
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November 2011 |
The electronic structure of actinide-containing molecules: a challenge to applied quantum chemistry
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journal
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July 1991 |
Thorium Triamidoamine Complexes: Synthesis of an Unusual Dinuclear Tuck-in–Tuck-over Thorium Metallacycle Featuring the Longest Known Thorium−σ-Alkyl Bond
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journal
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November 2014 |
The Renaissance of Non-Aqueous Uranium Chemistry
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journal
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June 2015 |
Solution Structure and Behavior of Dimeric Uranium(III) Metallocene Halides
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journal
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March 1999 |
Synthesis and Properties of a Fifteen-Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4]
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journal
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March 2010 |
Is Thorium a d Transition Metal or an Actinide? An Answer from a DFT Study of the Reaction between Pyridine N -Oxide and Cp 2 M(CH 3 ) 2 with M = Zr, Th, and U
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journal
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February 2009 |
Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity
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journal
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January 2017 |
Systematic Investigation of Thorium(IV)– and Uranium(IV)–Ligand Bonding in Dithiophosphonate, Thioselenophosphinate, and Diselenophosphonate Complexes
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journal
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August 2013 |
Manipulation of organoactinide coordinative unsaturation. Synthesis, structures, and reactivity of thorium hydrocarbyls and hydrides with chelating bis(tetramethylcyclopentadienyl) ancillary ligands
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journal
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August 1988 |
[Th(III)[.eta.5-C5H3(SiMe3)2]3], an actinide compound with a 6d1 ground state
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journal
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February 1988 |
Multiple Bonds Between Metal Atoms
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book
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January 2005 |
A delocalized arene-bridged diuranium single-molecule magnet
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journal
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April 2011 |
The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium( iv ) and uranium( iv ) alkyls
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journal
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January 2014 |
A Heterobimetallic Complex With an Unsupported Uranium(III)−Aluminum(I) Bond: (CpSiMe 3 ) 3 U−AlCp* (Cp* = C 5 Me 5 )
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journal
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August 2008 |
Metal–Alane Adducts with Zero-Valent Nickel, Cobalt, and Iron
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journal
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December 2011 |
Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
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journal
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September 2016 |
Synthesis, structure and bonding of hexaphenyl thorium( iv ): observation of a non-octahedral structure
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journal
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January 2016 |
Density Functional Theory Studies of the Electronic Structure of Solid State Actinide Oxides
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journal
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October 2012 |
A comparative study of the reactivity of Zr(IV), Hf(IV) and Th(IV) metallocene complexes: Thorium is not a Group IV metal after all
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journal
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October 2007 |
The Chemistry of the Actinide and Transactinide Elements. 3rd ed., 5 vols. Edited by Lester R. Morss, Norman M. Edelstein, Jean Fuger, and Joseph J. Katz.
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journal
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February 2007 |
Synthesis and x-ray structure of (C5Me5)2Th(.mu.-PPh2)2Pt(PMe3): a complex with a thorium-platinum bond
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journal
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January 1986 |
Probing the Coordinative Unsaturation and Local Environment of Ti 3+ Sites in an Activated High-Yield Ziegler-Natta Catalyst
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journal
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February 2015 |