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Title: Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All‐Solid‐State Batteries

Abstract

Abstract Owing to the ever‐increasing safety concerns about conventional lithium‐ion batteries, whose applications have expanded to include electric vehicles and grid‐scale energy storage, batteries with solidified electrolytes that utilize nonflammable inorganic materials are attracting considerable attention. In particular, owing to their superionic conductivities (as high as ≈10 −2 S cm −1 ) and deformability, sulfide materials as the solid electrolytes (SEs) are considered the enabling material for high‐energy bulk‐type all‐solid‐state batteries. Herein the authors provide a brief review on recent progress in sulfide Li‐ and Na‐ion SEs for all‐solid‐state batteries. After the basic principles in designing SEs are considered, the experimental exploration of multicomponent systems and ab initio calculations that accelerate the search for stronger candidates are discussed. Next, other issues and challenges that are critical for practical applications, such as instability in air, electrochemical stability, and compatibility with active materials, are discussed. Then, an emerging progress in liquid‐phase synthesis and solution process of SEs and its relevant prospects in ensuring intimate ionic contacts and fabricating sheet‐type electrodes is highlighted. Finally, an outlook on the future research directions for all‐solid‐state batteries employing sulfide superionic conductors is provided.

Authors:
 [1];  [2];  [3];  [3];  [2];  [2]; ORCiD logo [1]
  1. Department of Energy Engineering Hanyang University Seoul 04763 South Korea
  2. Department of Materials Science and Engineering University of Maryland College Park MD 20742 USA
  3. Department of Energy Engineering Hanyang University Seoul 04763 South Korea, School of Energy and Chemical Engineering UNIST (Ulsan National Institute of Science and Technology) Ulsan 44919 South Korea
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1434220
Grant/Contract Number:  
DE‐EE0006860; DE‐EE0007807
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 8 Journal Issue: 18; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Park, Kern Ho, Bai, Qiang, Kim, Dong Hyeon, Oh, Dae Yang, Zhu, Yizhou, Mo, Yifei, and Jung, Yoon Seok. Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All‐Solid‐State Batteries. Germany: N. p., 2018. Web. doi:10.1002/aenm.201800035.
Park, Kern Ho, Bai, Qiang, Kim, Dong Hyeon, Oh, Dae Yang, Zhu, Yizhou, Mo, Yifei, & Jung, Yoon Seok. Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All‐Solid‐State Batteries. Germany. https://doi.org/10.1002/aenm.201800035
Park, Kern Ho, Bai, Qiang, Kim, Dong Hyeon, Oh, Dae Yang, Zhu, Yizhou, Mo, Yifei, and Jung, Yoon Seok. 2018. "Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All‐Solid‐State Batteries". Germany. https://doi.org/10.1002/aenm.201800035.
@article{osti_1434220,
title = {Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All‐Solid‐State Batteries},
author = {Park, Kern Ho and Bai, Qiang and Kim, Dong Hyeon and Oh, Dae Yang and Zhu, Yizhou and Mo, Yifei and Jung, Yoon Seok},
abstractNote = {Abstract Owing to the ever‐increasing safety concerns about conventional lithium‐ion batteries, whose applications have expanded to include electric vehicles and grid‐scale energy storage, batteries with solidified electrolytes that utilize nonflammable inorganic materials are attracting considerable attention. In particular, owing to their superionic conductivities (as high as ≈10 −2 S cm −1 ) and deformability, sulfide materials as the solid electrolytes (SEs) are considered the enabling material for high‐energy bulk‐type all‐solid‐state batteries. Herein the authors provide a brief review on recent progress in sulfide Li‐ and Na‐ion SEs for all‐solid‐state batteries. After the basic principles in designing SEs are considered, the experimental exploration of multicomponent systems and ab initio calculations that accelerate the search for stronger candidates are discussed. Next, other issues and challenges that are critical for practical applications, such as instability in air, electrochemical stability, and compatibility with active materials, are discussed. Then, an emerging progress in liquid‐phase synthesis and solution process of SEs and its relevant prospects in ensuring intimate ionic contacts and fabricating sheet‐type electrodes is highlighted. Finally, an outlook on the future research directions for all‐solid‐state batteries employing sulfide superionic conductors is provided.},
doi = {10.1002/aenm.201800035},
url = {https://www.osti.gov/biblio/1434220}, journal = {Advanced Energy Materials},
issn = {1614-6832},
number = 18,
volume = 8,
place = {Germany},
year = {Mon Apr 23 00:00:00 EDT 2018},
month = {Mon Apr 23 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at https://doi.org/10.1002/aenm.201800035

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Cited by: 343 works
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