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Title: An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes

Abstract

A single electron reduction of an iron bis(verdazyl) complex results in a large change in spin multiplicity resulting from a combination of spin crossover and exceptionally strong ferromagnetic exchange.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [2]; ORCiD logo [2];  [3]; ORCiD logo [4]
  1. Department of Chemistry, San José State University, San José, USA
  2. Department of Physics, University of South Florida, Tampa, USA
  3. Department of Physics and Astronomy, San José State University, San José, USA
  4. Bruker AXS Inc., Madison, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1434164
Grant/Contract Number:
AC02-05CH11231
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 18; Related Information: CHORUS Timestamp: 2018-05-08 04:45:19; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Brook, David J. R., Fleming, Connor, Chung, Dorothy, Richardson, Cardius, Ponce, Servando, Das, Raja, Srikanth, Hariharan, Heindl, Ranko, and Noll, Bruce C. An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT00805A.
Brook, David J. R., Fleming, Connor, Chung, Dorothy, Richardson, Cardius, Ponce, Servando, Das, Raja, Srikanth, Hariharan, Heindl, Ranko, & Noll, Bruce C. An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes. United Kingdom. doi:10.1039/C8DT00805A.
Brook, David J. R., Fleming, Connor, Chung, Dorothy, Richardson, Cardius, Ponce, Servando, Das, Raja, Srikanth, Hariharan, Heindl, Ranko, and Noll, Bruce C. Mon . "An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes". United Kingdom. doi:10.1039/C8DT00805A.
@article{osti_1434164,
title = {An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes},
author = {Brook, David J. R. and Fleming, Connor and Chung, Dorothy and Richardson, Cardius and Ponce, Servando and Das, Raja and Srikanth, Hariharan and Heindl, Ranko and Noll, Bruce C.},
abstractNote = {A single electron reduction of an iron bis(verdazyl) complex results in a large change in spin multiplicity resulting from a combination of spin crossover and exceptionally strong ferromagnetic exchange.},
doi = {10.1039/C8DT00805A},
journal = {Dalton Transactions},
number = 18,
volume = 47,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on April 6, 2019
Publisher's Accepted Manuscript

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