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Title: Designing solution chemistries for the low-temperature synthesis of sulfide-based solid electrolytes

Journal Article · · Journal of Materials Chemistry A
DOI:https://doi.org/10.1039/C8TA01800F· OSTI ID:1434149

A new solution-based synthesis method to produce a high quality Li 2 S–P 2 S 5 solid electrolyte was developed by using a strong nucleophile of LiC 2 H 5 .

Sponsoring Organization:
USDOE
Grant/Contract Number:
AR0000781
OSTI ID:
1434149
Journal Information:
Journal of Materials Chemistry A, Journal Name: Journal of Materials Chemistry A Vol. 6 Journal Issue: 17; ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 40 works
Citation information provided by
Web of Science

References (25)

Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries journal November 2004
A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries journal January 2014
Preparation of sulfide solid electrolytes in the Li 2 S–P 2 S 5 system by a liquid phase process journal January 2018
Design principles for solid-state lithium superionic conductors journal August 2015
Microwave-Assisted Cleavage of Aryl Methyl Ethers with Lithium Thioethoxide (LiSEt) journal July 2008
Preparation of Li 7 P 3 S 11 glass-ceramic electrolyte by dissolution-evaporation method for all-solid-state lithium ion batteries journal November 2016
Liquid-phase synthesis of a Li3PS4 solid electrolyte using N-methylformamide for all-solid-state lithium batteries journal January 2014
Highly lithium-ion conductive thio-LISICON thin film processed by low-temperature solution method journal February 2013
A lithium superionic conductor journal July 2011
Preparation of Li2S–P2S5 solid electrolyte from N-methylformamide solution and application for all-solid-state lithium battery journal February 2014
Structural transformation of non-oxide chalcogenide glasses. The short-range order of lithium sulfide (Li2S)-phosphorus pentasulfide (P2S5) glasses studied by quantitative phosphorus-31, lithium-6, and lithium-7 high-resolution solid-state NMR journal May 1990
Instantaneous preparation of high lithium-ion conducting sulfide solid electrolyte Li 7 P 3 S 11 by a liquid phase process journal January 2017
High-power all-solid-state batteries using sulfide superionic conductors journal March 2016
Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries journal June 2013
Structural Evolution and Li Dynamics in Nanophase Li 3 PS 4 by Solid-State and Pulsed-Field Gradient NMR journal May 2014
Nucleophile- or Light-Induced Synthesis of 3-Substituted Phthalides from 2-Formylarylketones journal April 2012
New Lithium-Ion Conducting Crystal Obtained by Crystallization of the Li[sub 2]S–P[sub 2]S[sub 5] Glasses journal January 2005
A synthesis of crystalline Li7P3S11 solid electrolyte from 1,2-dimethoxyethane solvent journal December 2014
Formation of Li 2 S–P 2 S 5 Solid Electrolyte from N -Methylformamide Solution journal November 2013
Fabrication of ultrathin solid electrolyte membranes of β-Li 3 PS 4 nanoflakes by evaporation-induced self-assembly for all-solid-state batteries journal January 2016
An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal journal December 2017
New, Highly Ion-Conductive Crystals Precipitated from Li2S-P2S5 Glasses journal April 2005
Chemical synthesis of Li3PS4 precursor suspension by liquid-phase shaking journal February 2016
Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4 journal January 2013
Lithium battery chemistries enabled by solid-state electrolytes journal February 2017

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