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Title: A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water

Abstract

An artificial metalloenzyme reduces CO 2 to CO using light, suggesting intramolecular electron transfer and secondary sphere effects modulate catalytic selectivity.

Authors:
 [1];  [1];  [2]; ORCiD logo [3]
  1. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA
  2. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, USA
  3. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA, Department of Chemistry and Biochemistry
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1434123
Grant/Contract Number:
SC0018020
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Volume: 54; Journal Issue: 37; Related Information: CHORUS Timestamp: 2018-05-03 05:27:04; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Schneider, Camille R., Manesis, Anastasia C., Stevenson, Michael J., and Shafaat, Hannah S. A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water. United Kingdom: N. p., 2018. Web. doi:10.1039/C8CC01297K.
Schneider, Camille R., Manesis, Anastasia C., Stevenson, Michael J., & Shafaat, Hannah S. A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water. United Kingdom. doi:10.1039/C8CC01297K.
Schneider, Camille R., Manesis, Anastasia C., Stevenson, Michael J., and Shafaat, Hannah S. Mon . "A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water". United Kingdom. doi:10.1039/C8CC01297K.
@article{osti_1434123,
title = {A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water},
author = {Schneider, Camille R. and Manesis, Anastasia C. and Stevenson, Michael J. and Shafaat, Hannah S.},
abstractNote = {An artificial metalloenzyme reduces CO 2 to CO using light, suggesting intramolecular electron transfer and secondary sphere effects modulate catalytic selectivity.},
doi = {10.1039/C8CC01297K},
journal = {Chemical Communications},
number = 37,
volume = 54,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on April 10, 2019
Publisher's Accepted Manuscript

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