Perspective: Highly stable vapor-deposited glasses

Ediger, M. D.

doi:10.1063/1.5006265

Title: Perspective: Highly stable vapor-deposited glasses

Journal Article · Thu Dec 07 00:00:00 EST 2017 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5006265· OSTI ID:1434038

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Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry

This paper describes recent progress in understanding highly stable glasses prepared by physical vapor deposition and provides perspective on further research directions for the field. For a given molecule, vapor-deposited glasses can have higher density and lower enthalpy than any glass that can be prepared by the more traditional route of cooling a liquid, and such glasses also exhibit greatly enhanced kinetic stability. Because vapor-deposited glasses can approach the bottom of the amorphous part of the potential energy landscape, they provide insights into the properties expected for the “ideal glass”. Connections between vapor-deposited glasses, liquid-cooled glasses, and deeply supercooled liquids are explored. The generality of stable glass formation for organic molecules is discussed along with the prospects for stable glasses of other types of materials.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Science Foundation (NSF)

Grant/Contract Number:: SC0002161; CHE-1564663; DMR-1720415

OSTI ID:: 1434038

Alternate ID(s):: OSTI ID: 1410887

Journal Information:: Journal of Chemical Physics, Vol. 147, Issue 21; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 135 works

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Enthalpy and high temperature relaxation kinetics of stable vapor-deposited glasses of toluene Bhattacharya, Deepanjan; Sadtchenko, Vlad arXiv https://doi.org/10.48550/arxiv.1406.4562	text	January 2014
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Perspective: Searching for simplicity rather than universality in glass-forming liquids Niss, Kristine; Hecksher, Tina The Journal of Chemical Physics, Vol. 149, Issue 23 https://doi.org/10.1063/1.5048093	journal	December 2018
Tenfold increase in the photostability of an azobenzene guest in vapor-deposited glass mixtures Qiu, Yue; Antony, Lucas W.; Torkelson, John M. The Journal of Chemical Physics, Vol. 149, Issue 20 https://doi.org/10.1063/1.5052003	journal	November 2018
Configurational entropy of glass-forming liquids Berthier, Ludovic; Ozawa, Misaki; Scalliet, Camille The Journal of Chemical Physics, Vol. 150, Issue 16 https://doi.org/10.1063/1.5091961	journal	April 2019
Tracer transport in attractive and repulsive supercooled liquids and glasses Roberts, Ryan C.; Poling-Skutvik, Ryan; Conrad, Jacinta C. The Journal of Chemical Physics, Vol. 151, Issue 19 https://doi.org/10.1063/1.5121851	journal	November 2019
Relationship between aged and vapor-deposited organic glasses: Secondary relaxations in methyl- m -toluate Kasting, B. J.; Beasley, M. S.; Guiseppi-Elie, A. The Journal of Chemical Physics, Vol. 151, Issue 14 https://doi.org/10.1063/1.5123305	journal	October 2019
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Marginally stable phases in mean-field structural glasses Scalliet, Camille; Berthier, Ludovic; Zamponi, Francesco Physical Review E, Vol. 99, Issue 1 https://doi.org/10.1103/physreve.99.012107	journal	January 2019
Ultrastable and polyamorphic states of vapor-deposited 2-methyltetrahydrofuran Riechers, Birte; Guiseppi-Elie, A.; Ediger, M. D. The Journal of Chemical Physics, Vol. 150, Issue 21 https://doi.org/10.1063/1.5091796	journal	June 2019
Gaseous “nanoprobes” for detecting gas-trapping environments in macroscopic films of vapor-deposited amorphous ice Talewar, Sukhpreet K.; Halukeerthi, Siriney O.; Riedlaicher, Regina The Journal of Chemical Physics, Vol. 151, Issue 13 https://doi.org/10.1063/1.5113505	journal	October 2019
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Testing the paradigm of an ideal glass transition: Dynamics of an ultrastable polymeric glass Yoon, Heedong; McKenna, Gregory B. Science Advances, Vol. 4, Issue 12 https://doi.org/10.1126/sciadv.aau5423	journal	December 2018
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Nucleation instability in supercooled Cu–Zr–Al glass-forming liquids Ryltsev, R. E.; Klumov, B. A.; Chtchelkatchev, N. M. The Journal of Chemical Physics, Vol. 149, Issue 16 https://doi.org/10.1063/1.5054631	journal	October 2018
Pressure densified 1,3,5-tri(1-naphthyl)benzene glass. I. Volume recovery and physical aging Holt, A. P.; Fragiadakis, D.; Roland, C. M. The Journal of Chemical Physics, Vol. 151, Issue 18 https://doi.org/10.1063/1.5122765	journal	November 2019
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Variability of mesoscopic mechanical disorder in disordered solids González-López, Karina; Bouchbinder, Eran; Lerner, Edan Journal of Non-Crystalline Solids, Vol. 604 https://doi.org/10.1016/j.jnoncrysol.2023.122137	journal	March 2023
Deep-Glassy Ice VI Revealed with a Combination of Neutron Spectroscopy and Diffraction Rosu-Finsen, Alexander; Amon, Alfred; Armstrong, Jeff The Journal of Physical Chemistry Letters, Vol. 11, Issue 3 https://doi.org/10.1021/acs.jpclett.0c00125	journal	January 2020
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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
stable glasses
kinetic stability
physical vapor deposition
dielectrics
enthalpy
entropy
phase transitions
thermodynamic properties
organic semiconductors
chemical compounds
amorphous solids

Title: Perspective: Highly stable vapor-deposited glasses

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