2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)

Urbankowski, Patrick; Anasori, Babak; Hantanasirisakul, Kanit; Yang, Long; Zhang, Lihua; Haines, Bernard; May, Steven J.; Billinge, Simon J.  L.; Gogotsi, Yury

doi:10.1039/C7NR06721F

Title: 2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)

Journal Article · Wed Nov 08 00:00:00 EST 2017 · Nanoscale

DOI:https://doi.org/10.1039/C7NR06721F· OSTI ID:1433989

^[1];

^[2]; Zhang, Lihua ^[3]; Haines, Bernard ^[1];

^[1];

^[4];

^[1]

Drexel Univ., Philadelphia, PA (United States). A. J. Drexel Nanotechnology Inst., and Dept. of Materials Science & Engineering
Columbia Univ., New York, NY (United States). Dept. of Applied Physics and Applied Mathematics
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Columbia Univ., New York, NY (United States). Dept. of Applied Physics and Applied Mathematics; Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.

MXenes are a rapidly growing class of 2D transition metal carbides and nitrides, finding applications in fields ranging from energy storage to electromagnetic interference shielding and transparent conductive coatings. However, while more than 20 carbide MXenes have already been synthesized, Ti₄N₃ and Ti₂N are the only nitride MXenes reported so far. Here by ammoniation of Mo₂CT_x and V₂CT_x MXenes at 600 °C, we report on their transformation to 2D metal nitrides. Carbon atoms in the precursor MXenes are replaced with N atoms, resulting from the decomposition of ammonia molecules. The crystal structures of the resulting Mo₂N and V₂N were determined with transmission electron microscopy and X-ray pair distribution function analysis. Our results indicate that Mo₂N retains the MXene structure and V₂C transforms to a mixed layered structure of trigonal V₂N and cubic VN. Temperature-dependent resistivity measurements of the nitrides reveal that they exhibit metallic conductivity, as opposed to semiconductor-like behavior of their parent carbides. As important, room-temperature electrical conductivity values of Mo2N and V2N are three and one order of magnitude larger than those of the Mo₂CT_x and V₂CT_x precursors, respectively. In conclusion, this study shows how gas treatment synthesis such as ammoniation can transform carbide MXenes into 2D nitrides with higher electrical conductivities and metallic behavior, opening a new avenue in 2D materials synthesis.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; DMR-1310245; DMR-1420634

OSTI ID:: 1433989

Report Number(s):: BNL-203531-2018-JAAM; NANOHL

Journal Information:: Nanoscale, Vol. 9, Issue 45; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 209 works

Citation information provided by
Web of Science

References (59)

Photocatalytic and Photoelectrochemical Properties of Nitrogen-Doped Titanium Dioxide Sakthivel, Shanmugasundaram; Kisch, Horst ChemPhysChem, Vol. 4, Issue 5 https://doi.org/10.1002/cphc.200200554	journal	May 2003
Investigations on V ₂ C and V ₂ CX ₂ (X = F, OH) Monolayer as a Promising Anode Material for Li Ion Batteries from First-Principles Calculations Hu, Junping; Xu, Bo; Ouyang, Chuying The Journal of Physical Chemistry C, Vol. 118, Issue 42 https://doi.org/10.1021/jp507336x	journal	October 2014
Two-dimensional gallium nitride realized via graphene encapsulation Al Balushi, Zakaria Y.; Wang, Ke; Ghosh, Ram Krishna Nature Materials, Vol. 15, Issue 11 https://doi.org/10.1038/nmat4742	journal	August 2016
Hydrophobic, Flexible, and Lightweight MXene Foams for High-Performance Electromagnetic-Interference Shielding Liu, Ji; Zhang, Hao-Bin; Sun, Renhui Advanced Materials, Vol. 29, Issue 38 https://doi.org/10.1002/adma.201702367	journal	August 2017
Study on the electrochemical behavior of vanadium nitride as a promising supercapacitor material Zhou, Xiaoping; Chen, Hongyu; Shu, Dong Journal of Physics and Chemistry of Solids, Vol. 70, Issue 2 https://doi.org/10.1016/j.jpcs.2008.12.004	journal	February 2009
PDFFIT , a program for full profile structural refinement of the atomic pair distribution function Proffen, Th.; Billinge, S. J. L. Journal of Applied Crystallography, Vol. 32, Issue 3 https://doi.org/10.1107/S0021889899003532	journal	June 1999
Synthesis of two-dimensional molybdenum carbide, Mo 2 C, from the gallium based atomic laminate Mo 2 Ga 2 C Meshkian, Rahele; Näslund, Lars-Åke; Halim, Joseph Scripta Materialia, Vol. 108 https://doi.org/10.1016/j.scriptamat.2015.07.003	journal	November 2015
Atomically-thin molybdenum nitride nanosheets with exposed active surface sites for efficient hydrogen evolution Xie, Junfeng; Li, Shuang; Zhang, Xiaodong Chem. Sci., Vol. 5, Issue 12 https://doi.org/10.1039/C4SC02019G	journal	January 2014
Nitrogen-doped Ti 3 C 2 T x MXene electrodes for high-performance supercapacitors Wen, Yangyang; Rufford, Thomas E.; Chen, Xingzhu Nano Energy, Vol. 38 https://doi.org/10.1016/j.nanoen.2017.06.009	journal	August 2017
Salt-Templated Synthesis of 2D Metallic MoN and Other Nitrides Xiao, Xu; Yu, Huimin; Jin, Huanyu ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.6b08534	journal	February 2017
Synthesis and Characterization of 2D Molybdenum Carbide (MXene) Halim, Joseph; Kota, Sankalp; Lukatskaya, Maria R. Advanced Functional Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adfm.201505328	journal	February 2016
Zerstreuung von Röntgenstrahlen Debye, P. Annalen der Physik, Vol. 351, Issue 6 https://doi.org/10.1002/andp.19153510606	journal	January 1915
Transition Metal Carbides and Nitrides in Energy Storage and Conversion Zhong, Yu; Xia, Xinhui; Shi, Fan Advanced Science, Vol. 3, Issue 5 https://doi.org/10.1002/advs.201500286	journal	February 2016
Highly Flexible, Freestanding Supercapacitor Electrode with Enhanced Performance Obtained by Hybridizing Polypyrrole Chains with MXene Zhu, Minshen; Huang, Yang; Deng, Qihuang Advanced Energy Materials, Vol. 6, Issue 21 https://doi.org/10.1002/aenm.201600969	journal	August 2016
Complex modeling: a strategy and software program for combining multiple information sources to solve ill posed structure and nanostructure inverse problems Juhás, Pavol; Farrow, Christopher L.; Yang, Xiaohao Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 6, p. 562-568 https://doi.org/10.1107/S2053273315014473	journal	September 2015
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Structure of Nanocrystalline ${Ti}_{3} C_{2}$ MXene Using Atomic Pair Distribution Function Shi, Chenyang; Beidaghi, Majid; Naguib, Michael Physical Review Letters, Vol. 112, Issue 12 https://doi.org/10.1103/PhysRevLett.112.125501	journal	March 2014
Direct Synthesis of Large-Area 2D Mo ₂ C on In Situ Grown Graphene Geng, Dechao; Zhao, Xiaoxu; Chen, Zhongxin Advanced Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adma.201700072	journal	July 2017
Band-to-Band Visible-Light Photon Excitation and Photoactivity Induced by Homogeneous Nitrogen Doping in Layered Titanates Liu, Gang; Wang, Lianzhou; Sun, Chenghua Chemistry of Materials, Vol. 21, Issue 7 https://doi.org/10.1021/cm802986r	journal	April 2009
Fabrication of Ti ₃ C ₂ T _x MXene Transparent Thin Films with Tunable Optoelectronic Properties Hantanasirisakul, Kanit; Zhao, Meng-Qiang; Urbankowski, Patrick Advanced Electronic Materials, Vol. 2, Issue 6 https://doi.org/10.1002/aelm.201600050	journal	April 2016
Synthesis of Ti3AuC2, Ti3Au2C2 and Ti3IrC2 by noble metal substitution reaction in Ti3SiC2 for high-temperature-stable Ohmic contacts to SiC Fashandi, Hossein; Dahlqvist, Martin; Lu, Jun Nature Materials, Vol. 16, Issue 8 https://doi.org/10.1038/nmat4896	journal	May 2017
Deposition of molybdenum nitride thin films by r.f. reactive magnetron sputtering Anitha, V. P.; Major, S.; Chandrashekharam, D. Surface and Coatings Technology, Vol. 79, Issue 1-3 https://doi.org/10.1016/0257-8972(95)02425-5	journal	February 1996
Scalable salt-templated synthesis of two-dimensional transition metal oxides Xiao, Xu; Song, Huaibing; Lin, Shizhe Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11296	journal	April 2016
Effects of Applied Potential and Water Intercalation on the Surface Chemistry of Ti ₂ C and Mo ₂ C MXenes Fredrickson, Kurt D.; Anasori, Babak; Seh, Zhi Wei The Journal of Physical Chemistry C, Vol. 120, Issue 50 https://doi.org/10.1021/acs.jpcc.6b09109	journal	December 2016
Highly Conductive Optical Quality Solution-Processed Films of 2D Titanium Carbide Dillon, Andrew D.; Ghidiu, Michael J.; Krick, Alex L. Advanced Functional Materials, Vol. 26, Issue 23 https://doi.org/10.1002/adfm.201600357	journal	April 2016
Exploring the potential of exfoliated ternary ultrathin Ti ₄ AlN ₃ nanosheets for fabricating hybrid patterned polymer brushes Ye, Qun; Xiao, Peng; Liu, Wulong RSC Advances, Vol. 5, Issue 86 https://doi.org/10.1039/C5RA09227B	journal	January 2015
Organic adlayer on inorganic materials: XPS analysis selectivity to cope with adventitious contamination Landoulsi, Jessem; Genet, Michel J.; Fleith, Sandrine Applied Surface Science, Vol. 383 https://doi.org/10.1016/j.apsusc.2016.04.147	journal	October 2016
Thermoelectric Properties of Two-Dimensional Molybdenum-Based MXenes Kim, Hyunho; Anasori, Babak; Gogotsi, Yury Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b02056	journal	July 2017
Ultrathin MXene-Micropattern-Based Field-Effect Transistor for Probing Neural Activity Xu, Bingzhe; Zhu, Minshen; Zhang, Wencong Advanced Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adma.201504657	journal	February 2016
Electromagnetic interference shielding with 2D transition metal carbides (MXenes) Shahzad, F.; Alhabeb, M.; Hatter, C. B. Science, Vol. 353, Issue 6304 https://doi.org/10.1126/science.aag2421	journal	September 2016
Titanium nitride as a plasmonic material for visible and near-infrared wavelengths Naik, Gururaj V.; Schroeder, Jeremy L.; Ni, Xingjie Optical Materials Express, Vol. 2, Issue 4 https://doi.org/10.1364/OME.2.000478	journal	January 2012
Charge- and Size-Selective Ion Sieving Through Ti ₃ C ₂ T _x MXene Membranes Ren, Chang E.; Hatzell, Kelsey B.; Alhabeb, Mohamed The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01895	journal	September 2015
Suitable Conditions for the Use of Vanadium Nitride as an Electrode for Electrochemical Capacitor Morel, Alban; Borjon-Piron, Yann; Porto, Raúl Lucio Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.1221606jes	journal	January 2016
Antibacterial Activity of Ti ₃ C ₂ T _x MXene Rasool, Kashif; Helal, Mohamed; Ali, Adnan ACS Nano, Vol. 10, Issue 3 https://doi.org/10.1021/acsnano.6b00181	journal	February 2016
Monolayer MXenes: promising half-metals and spin gapless semiconductors Gao, Guoying; Ding, Guangqian; Li, Jie Nanoscale, Vol. 8, Issue 16 https://doi.org/10.1039/C6NR01333C	journal	January 2016
Study of Electron State in Vanadium Nitride by Intensity Measurements of X-Ray Diffraction Hosoya, Sukeaki; Yamagishi, Tomoe; Tokonami, Masayasu Journal of the Physical Society of Japan, Vol. 24, Issue 2 https://doi.org/10.1143/JPSJ.24.363	journal	February 1968
Synthesis and Characterization of Few-layer Nanosheets of GaN and Other Metal Nitrides: Few-layer Nanosheets of GaN and Other Metal Nitrides Sreedhara, M. B.; Vasu, K.; Rao, C. N. R. Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 14 https://doi.org/10.1002/zaac.201400386	journal	October 2014
Flexible MXene/Carbon Nanotube Composite Paper with High Volumetric Capacitance Zhao, Meng-Qiang; Ren, Chang E.; Ling, Zheng Advanced Materials, Vol. 27, Issue 2 https://doi.org/10.1002/adma.201404140	journal	November 2014
Synthesis of two-dimensional titanium nitride Ti ₄ N ₃ (MXene) Urbankowski, Patrick; Anasori, Babak; Makaryan, Taron Nanoscale, Vol. 8, Issue 22 https://doi.org/10.1039/C6NR02253G	journal	January 2016
Rapid-acquisition pair distribution function (RA-PDF) analysis Chupas, Peter J.; Qiu, Xiangyun; Hanson, Jonathan C. Journal of Applied Crystallography, Vol. 36, Issue 6, p. 1342-1347 https://doi.org/10.1107/S0021889803017564	journal	November 2003
Graphene-like titanium carbides and nitrides Tin+1Cn, Tin+1Nn (n=1, 2, and 3) from de-intercalated MAX phases: First-principles probing of their structural, electronic properties and relative stability Shein, I. R.; Ivanovskii, A. L. Computational Materials Science, Vol. 65 https://doi.org/10.1016/j.commatsci.2012.07.011	journal	December 2012
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
Two-Dimensional Titanium Nitride (Ti ₂ N) MXene: Synthesis, Characterization, and Potential Application as Surface-Enhanced Raman Scattering Substrate Soundiraraju, Bhuvaneswari; George, Benny Kattikkanal ACS Nano, Vol. 11, Issue 9 https://doi.org/10.1021/acsnano.7b03129	journal	September 2017
Large-area high-quality 2D ultrathin Mo2C superconducting crystals Xu, Chuan; Wang, Libin; Liu, Zhibo Nature Materials, Vol. 14, Issue 11 https://doi.org/10.1038/nmat4374	journal	August 2015
The structure of β-vanadium nitride Christensen, A. N.; Lebech, B. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 35, Issue 11 https://doi.org/10.1107/S0567740879010141	journal	November 1979
Hydrothermal synthesis of vanadium nitride and modulation of its catalytic performance for oxygen reduction reaction Huang, Taizhong; Mao, Shun; Zhou, Guihua Nanoscale, Vol. 6, Issue 16 https://doi.org/10.1039/C4NR02646B	journal	January 2014
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M. Chemistry of Materials, Vol. 26, Issue 7 https://doi.org/10.1021/cm500641a	journal	March 2014
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries Naguib, Michael; Halim, Joseph; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja405735d	journal	October 2013
A Two-Dimensional Zirconium Carbide by Selective Etching of Al ₃ C ₃ from Nanolaminated Zr ₃ Al ₃ C ₅ Zhou, Jie; Zha, Xianhu; Chen, Fan Y. Angewandte Chemie, Vol. 128, Issue 16 https://doi.org/10.1002/ange.201510432	journal	March 2016
Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance Zhang, Chuanfang John; Anasori, Babak; Seral-Ascaso, Andrés Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201702678	journal	July 2017
Synthesis and Electrochemical Properties of Two-Dimensional Hafnium Carbide Zhou, Jie; Zha, Xianhu; Zhou, Xiaobing ACS Nano, Vol. 11, Issue 4 https://doi.org/10.1021/acsnano.7b00030	journal	April 2017
Direct Synthesis of Carbon–Molybdenum Carbide Nanosheet Composites via a Pseudotopotactic Solid-State Reaction Fukuda, Katsutoshi; Morita, Masahito; Toyoda, Satoshi Chemistry of Materials, Vol. 28, Issue 24 https://doi.org/10.1021/acs.chemmater.6b03095	journal	December 2016
2D metal carbides and nitrides (MXenes) for energy storage Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.98	journal	January 2017
Layered ternary M _{n +1} AX _n phases and their 2D derivative MXene: an overview from a thin-film perspective Eklund, Per; Rosen, Johanna; Persson, Per O. Å Journal of Physics D: Applied Physics, Vol. 50, Issue 11 https://doi.org/10.1088/1361-6463/aa57bc	journal	February 2017
Optoelectronic and spectroscopic characterization of vapour-transport grown Cu ₂ ZnSnS ₄ single crystals Ng, Tat Ming; Weller, Mark T.; Kissling, Gabriela P. Journal of Materials Chemistry A, Vol. 5, Issue 3 https://doi.org/10.1039/C6TA09817G	journal	January 2017
Two-dimensional Mo1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering Tao, Quanzheng; Dahlqvist, Martin; Lu, Jun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14949	journal	April 2017
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang Nature, Vol. 516, Issue 7529 https://doi.org/10.1038/nature13970	journal	November 2014
Transition Metal Carbides and Nitrides in Energy Storage and Conversion Zhong, Yu; Xia, Xinhui; Shi, Fan Advanced Science, Vol. 4, Issue 3 https://doi.org/10.1002/advs.201700047	journal	February 2017
PDFgetX3: A rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions Juhas, Pavol; Davis, Timur; Farrow, Christopher L. arXiv https://doi.org/10.48550/arxiv.1211.7126	text	January 2012

Cited By (18)

Tuning Thermal Transport Through Atomically Thin Ti ₃ C ₂ T _z MXene by Current Annealing in Vacuum Hemmat, Zahra; Yasaei, Poya; Schultz, Jeremy F. Advanced Functional Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adfm.201805693	journal	March 2019
Scalable Synthesis of Ultrathin Mn ₃ N ₂ Exhibiting Room‐Temperature Antiferromagnetism Xiao, Xu; Urbankowski, Patrick; Hantanasirisakul, Kanit Advanced Functional Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adfm.201809001	journal	February 2019
Promoting Role of MXene Nanosheets in Biomedical Sciences: Therapeutic and Biosensing Innovations Soleymaniha, Mohammadreza; Shahbazi, Mohammad-Ali; Rafieerad, Ali Reza Advanced Healthcare Materials, Vol. 8, Issue 1 https://doi.org/10.1002/adhm.201801137	journal	October 2018
Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes) Hantanasirisakul, Kanit; Gogotsi, Yury Advanced Materials, Vol. 30, Issue 52 https://doi.org/10.1002/adma.201804779	journal	November 2018
Atmospheric-Pressure Synthesis of 2D Nitrogen-Rich Tungsten Nitride Yu, Huimin; Yang, Xin; Xiao, Xu Advanced Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adma.201805655	journal	October 2018
Sandwich‐Like Ultrathin TiS ₂ Nanosheets Confined within N, S Codoped Porous Carbon as an Effective Polysulfide Promoter in Lithium‐Sulfur Batteries Huang, Xia; Tang, Jiayong; Luo, Bin Advanced Energy Materials, Vol. 9, Issue 32 https://doi.org/10.1002/aenm.201901872	journal	July 2019
Two‐Dimensional Electrocatalysts for Efficient Reduction of Carbon Dioxide Zhang, Ying; Li, Linbo; Guo, Si‐Xuan ChemSusChem, Vol. 13, Issue 1 https://doi.org/10.1002/cssc.201901794	journal	October 2019
Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications Zhang, Chuanfang (John); Ma, Yonglu; Zhang, Xuetao ENERGY & ENVIRONMENTAL MATERIALS, Vol. 3, Issue 1 https://doi.org/10.1002/eem2.12058	journal	March 2020
Two‐dimensional MXenes for lithium‐sulfur batteries Zhang, Chuanfang (John); Cui, Linfan; Abdolhosseinzadeh, Sina InfoMat, Vol. 2, Issue 4 https://doi.org/10.1002/inf2.12080	journal	January 2020
Control of MXenes’ electronic properties through termination and intercalation Hart, James L.; Hantanasirisakul, Kanit; Lang, Andrew C. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-08169-8	journal	January 2019
Metallic MoN ultrathin nanosheets boosting high performance photocatalytic H ₂ production Ran, Jingrun; Wang, Hailong; Jin, Huanyu Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/c8ta09358j	journal	January 2018
Novel two-dimensional tetragonal vanadium carbides and nitrides as promising materials for Li-ion batteries Wu, Yi-Yuan; Bo, Tao; Zhang, Junrong Physical Chemistry Chemical Physics, Vol. 21, Issue 35 https://doi.org/10.1039/c9cp03954f	journal	January 2019
Synergetic enhancement of polysulfide chemisorption and electrocatalysis over bicontinuous MoN@N-rich carbon porous nano-octahedra for Li–S batteries Wang, Peng; Li, Na; Zhang, Zhian Journal of Materials Chemistry A, Vol. 7, Issue 38 https://doi.org/10.1039/c9ta05517g	journal	January 2019
Recent developments in emerging two-dimensional materials and their applications Khan, Karim; Tareen, Ayesha Khan; Aslam, Muhammad Journal of Materials Chemistry C, Vol. 8, Issue 2 https://doi.org/10.1039/c9tc04187g	journal	January 2020
Strain-tunable electronic structures and optical properties of semiconducting MXenes Cui, Jingjing; Peng, Qiong; Zhou, Jian Nanotechnology, Vol. 30, Issue 34 https://doi.org/10.1088/1361-6528/ab1f22	journal	June 2019
A low‐cost and efficient pathway for preparation of 2D MoN nanosheets via Na ₂ CO ₃ ‐assisted nitridation of MoS ₂ with NH ₃ Sun, Guo‐Dong; Chang, He‐Qiang; Zhang, Guo‐Hua Journal of the American Ceramic Society, Vol. 102, Issue 12 https://doi.org/10.1111/jace.16649	journal	June 2019
Realization of 2D crystalline metal nitrides via selective atomic substitution Cao, Jun; Li, Tianshu; Gao, Hongze Science Advances, Vol. 6, Issue 2 https://doi.org/10.1126/sciadv.aax8784	journal	January 2020
Realization of 2D Crystalline Metal Nitrides via Selective Atomic Substitution Cao, Jun; Li, Tianshu; Gao, Hongze arXiv https://doi.org/10.48550/arxiv.1910.01695	preprint	January 2019

Similar Records

Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers

Journal Article · Wed Feb 24 00:00:00 EST 2016 · Nanoscale Horizons · OSTI ID:1433989

Anasori, Babak; Shi, Chenyang; Moon, Eun Ju; +7 more

Synthesis of Mo₄VAlC₄ MAX Phase and Two-Dimensional Mo₄VC₄ MXene with Five Atomic Layers of Transition Metals

Journal Article · Thu Dec 05 00:00:00 EST 2019 · ACS Nano · OSTI ID:1433989

Deysher, Grayson; Shuck, Christopher Eugene; Hantanasirisakul, Kanit; +8 more

Guidelines for Synthesis and Processing of Two-Dimensional [2D] Titanium Carbide (Ti₃C₂T_x MXene)

Journal Article · Fri Aug 25 00:00:00 EDT 2017 · Chemistry of Materials · OSTI ID:1433989

Alhabeb, Mohamed; Maleski, Kathleen; Anasori, Babak; +4 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY

Title: 2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)

Citation Formats

References (59)

Cited By (18)

Similar Records

Related Subjects