Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework

Kim, In Soo; Li, Zhanyong; Zheng, Jian; Platero-Prats, Ana E.; Mavrandonakis, Andreas; Pellizzeri, Steven; Ferrandon, Magali; Vjunov, Aleksei; Gallington, Leighanne C.; Webber, Thomas E.; Vermeulen, Nicolaas A.; Penn, R. Lee; Getman, Rachel B.; Cramer, Christopher J.; Chapman, Karena W.; Camaioni, Donald M.; Fulton, John L.; Lercher, Johannes A.; Farha, Omar K.; Hupp, Joseph T.; Martinson, Alex B.  F.

doi:10.1002/anie.201708092

Title: Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework

Journal Article · Tue Jan 02 00:00:00 EST 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201708092· OSTI ID:1433888

Kim, In Soo ^[1]; Li, Zhanyong ^[2]; Zheng, Jian ^[3]; Platero-Prats, Ana E. ^[4];

^[5]; Pellizzeri, Steven ^[6]; Ferrandon, Magali ^[7]; Vjunov, Aleksei ^[3]; Gallington, Leighanne C. ^[4]; Webber, Thomas E. ^[5]; Vermeulen, Nicolaas A. ^[2]; Penn, R. Lee ^[5]; Getman, Rachel B. ^[6]; Cramer, Christopher J. ^[5]; Chapman, Karena W. ^[4]; Camaioni, Donald M. ^[3]; Fulton, John L. ^[3]; Lercher, Johannes A. ^[3]; Farha, Omar K. ^[2]; Hupp, Joseph T. ^[8] more »

Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Inst. for Integrated Catalysis
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemistry
Clemson Univ., SC (United States). Chemical and Biomolecular Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry

Installed on the zirconia nodes of a metal-organic framework (MOF) NU-1000 via targeted vapor-phase synthesis. The catalytic Pt clusters, site-isolated by organic linkers, are shown to exhibit high catalytic activity for ethylene hydrogenation while exhibiting resistance to sintering up to 200 degrees C. In situ IR spectroscopy reveals the presence of both single atoms and few-atom clusters that depend upon synthesis conditions. Operando X-ray absorption spectroscopy and Xray pair distribution analyses reveal unique changes in chemical bonding environment and cluster size stability while on stream. Density functional theory calculations elucidate a favorable reaction pathway for ethylene hydrogenation with the novel catalyst. Lastly, these results provide evidence that atomic layer deposition (ALD) in MOFs is a versatile approach to the rational synthesis of size-selected clusters, including noble metals, on a high surface area support.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC05-76RL01830; SC0012702

OSTI ID:: 1433888

Alternate ID(s):: OSTI ID: 1415321; OSTI ID: 1842983

Report Number(s):: PNNL-SA-136025; 140426

Journal Information:: Angewandte Chemie (International Edition), Vol. 57, Issue 4; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 80 works

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Related Subjects

36 MATERIALS SCIENCE
atomic layer deposition (ALD)
heterogeneous catalysis
metal-organic framworks (MOFs)
platinum
sinter-resistance
Atomic layer deposition
heterogeneous catalysis
metal-organic frameworks
platinum
sinter-resistance