Electrochemical Stability of Li10GeP2S12 and Li7La3Zr2O12 Solid Electrolytes

Han, Fudong; Zhu, Yizhou; He, Xingfeng; Mo, Yifei; Wang, Chunsheng

doi:10.1002/aenm.201501590

Title: Electrochemical Stability of Li₁₀GeP₂S₁₂ and Li₇La₃Zr₂O₁₂ Solid Electrolytes

Journal Article · Thu Jan 21 00:00:00 EST 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201501590· OSTI ID:1433676

Han, Fudong ^[1]; Zhu, Yizhou ^[2]; He, Xingfeng ^[2]; Mo, Yifei ^[2]; Wang, Chunsheng ^[1]

Univ. of Maryland, College Park, MD (United States). Dept. of Chemical and Biomolecular Engineering
Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering

The electrochemical stability window of solid electrolyte is overestimated by the conventional experimental method using a Li/electrolyte/inert metal semiblocking electrode because of the limited contact area between solid electrolyte and inert metal. Since the battery is cycled in the overestimated stability window, the decomposition of the solid electrolyte at the interfaces occurs but has been ignored as a cause for high interfacial resistances in previous studies, limiting the performance improvement of the bulk-type solid-state battery despite the decades of research efforts. Thus, there is an urgent need to identify the intrinsic stability window of the solid electrolyte. The thermodynamic electrochemical stability window of solid electrolytes is calculated using first principles computation methods, and an experimental method is developed to measure the intrinsic electrochemical stability window of solid electrolytes using a Li/electrolyte/electrolyte-carbon cell. The most promising solid electrolytes, Li10GeP2S12 and cubic Li-garnet Li7La3Zr2O12, are chosen as the model materials for sulfide and oxide solid electrolytes, respectively. The results provide valuable insights to address the most challenging problems of the interfacial stability and resistance in high-performance solid-state batteries.

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Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF); US Army Research Office (ARO)

Grant/Contract Number:: EE0006860; 1235719; TG-DMR130142; W911NF1510187

OSTI ID:: 1433676

Alternate ID(s):: OSTI ID: 1433674

Journal Information:: Advanced Energy Materials, Vol. 6, Issue 8; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 642 works

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Strategies Based on Nitride Materials Chemistry to Stabilize Li Metal Anode Zhu, Yizhou; He, Xingfeng; Mo, Yifei Digital Repository at the University of Maryland https://doi.org/10.13016/m2p26q396	text	January 2017
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Space-Charge Layers in All-Solid-State Batteries; Important or Negligible? de Klerk, Niek J. J.; Wagemaker, Marnix ACS Applied Energy Materials https://doi.org/10.1021/acsaem.8b01141	journal	October 2018
7Li NMR Chemical Shift Imaging To Detect Microstructural Growth of Lithium in All-Solid-State Batteries. Marbella, Lauren E.; Zekoll, Stefanie; Kasemchainan, Jitti American Chemical Society (ACS) https://doi.org/10.17863/cam.38208	journalarticle	January 2019

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