Polyethylene-Glycol-Mediated Self-Assembly of Magnetite Nanoparticles at the Liquid/Vapor Interface

Vaknin, David; Wang, Wenjie; Islam, Farhan; Zhang, Honghu

doi:10.1002/admi.201701149

Title: Polyethylene-Glycol-Mediated Self-Assembly of Magnetite Nanoparticles at the Liquid/Vapor Interface

Journal Article · Fri Mar 23 00:00:00 EDT 2018 · Advanced Materials Interfaces

DOI:https://doi.org/10.1002/admi.201701149· OSTI ID:1433669

^[1]; Wang, Wenjie ^[2]; Islam, Farhan ^[1]; Zhang, Honghu ^[3]

Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy
Ames Lab., Ames, IA (United States). Division of Materials Sciences and Engineering
Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering

Abstract It is shown that magnetite nanoparticles (MagNPs) grafted with polyethylene glycol (PEG) self‐assemble and short‐range‐order as 2D films at surfaces of aqueous suspensions by manipulating salt concentrations. Synchrotron X‐ray reflectivity and grazing‐incidence small angle X‐ray scattering studies reveal that K ₂ CO ₃ induces the migration of the PEG‐MagNPs to the liquid/vapor interface to form a Gibbs layer of monoparticle in thickness. As the salt concentration and/or nanoparticle concentration increase, the surface‐adsorbed nanoparticles become more organized. And further increase in salt concentration leads to the growth of an additional incomplete nanoparticle layer contiguous to the first one at the vapor/liquid interface that remains intact.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE

Grant/Contract Number:: AC02-07CH11358; AC02-06CH11357; DE‐AC02‐06CH11357

OSTI ID:: 1433669

Alternate ID(s):: OSTI ID: 1417716

Report Number(s):: IS-J-9629

Journal Information:: Advanced Materials Interfaces, Vol. 5, Issue 6; ISSN 2196-7350

Publisher:: Wiley-VCHCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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Title: Polyethylene-Glycol-Mediated Self-Assembly of Magnetite Nanoparticles at the Liquid/Vapor Interface

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