Towards identifying the active sites on RuO 2 (110) in catalyzing oxygen evolution

Rao, Reshma R.; Kolb, Manuel J.; Halck, Niels Bendtsen; Pedersen, Anders Filsoe; Mehta, Apurva; You, Hoydoo; Stoerzinger, Kelsey A.; Feng, Zhenxing; Hansen, Heine A.; Zhou, Hua; Giordano, Livia; Rossmeisl, Jan; Vegge, Tejs; Chorkendorff, Ib; Stephens, Ifan E.  L.; Shao-Horn, Yang

doi:10.1039/c7ee02307c

Title: Towards identifying the active sites on RuO ₂ (110) in catalyzing oxygen evolution

Journal Article · Fri Nov 17 00:00:00 EST 2017 · Energy & Environmental Science

DOI:https://doi.org/10.1039/c7ee02307c· OSTI ID:1419931

^[1];

^[2]; Halck, Niels Bendtsen ^[3];

^[4]; Mehta, Apurva ^[5]; You, Hoydoo ^[6]; Stoerzinger, Kelsey A. ^[7];

^[8]; Hansen, Heine A. ^[3]; Zhou, Hua ^[9]; Giordano, Livia ^[10]; Rossmeisl, Jan ^[11];

^[3];

^[4]; Stephens, Ifan E. L. ^[4];

^[12]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Mechanical Engineering
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Research Lab. of Electronics
Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Energy Conversion and Storage
Technical Univ. of Denmark, Lyngby (Denmark). Section for Surface Physics and Catalysis, Dept. of Physics
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
Oregon State Univ., Corvallis, OR (United States). School of Chemical, Biological, and Environmental Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Mechanical Engineering; Univ. di Milano-Bicocca (Italy). Dipartimento di Scienza dei Materiali
Univ. of Copenhagen (Denmark). Dept. of Chemistry
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Mechanical Engineering; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Research Lab. of Electronics; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering

Surface structural transitions and active sites are identified using X-ray scattering and density functional theory.

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Research Organization:: SLAC National Accelerator Lab., Menlo Park, CA (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: 9455; AC02-06CH11357; AC02-76SF00515; ACI-1548562

OSTI ID:: 1419931

Alternate ID(s):: OSTI ID: 1433005

Journal Information:: Energy & Environmental Science, Vol. 10, Issue 12; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 196 works

Citation information provided by
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References (81)

Theoretical insight of adsorption thermodynamics of multifunctional molecules on metal surfaces Loffreda, David Surface Science, Vol. 600, Issue 10 https://doi.org/10.1016/j.susc.2006.02.045	journal	May 2006
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Oxygen reduction on nanocrystalline ruthenia – local structure effects Abbott, Daniel F.; Mukerjee, Sanjeev; Petrykin, Valery RSC Advances, Vol. 5, Issue 2 https://doi.org/10.1039/C4RA10001H	journal	January 2015
Surface core-level shifts at an oxygen-rich Ru surface: O/Ru(0001) vs. RuO2(110) Reuter, Karsten; Scheffler, Matthias Surface Science, Vol. 490, Issue 1-2 https://doi.org/10.1016/S0039-6028(01)01214-6	journal	September 2001
Effect of a humid environment on the surface structure of ${RuO}_{2} (110)$ Sun, Qiang; Reuter, Karsten; Scheffler, Matthias Physical Review B, Vol. 67, Issue 20 https://doi.org/10.1103/PhysRevB.67.205424	journal	May 2003
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Mineral–water interfacial structures revealed by synchrotron X-ray scattering Fenter, Paul; Sturchio, Neil C. Progress in Surface Science, Vol. 77, Issue 5-8 https://doi.org/10.1016/j.progsurf.2004.12.001	journal	January 2004
Oxygen and hydrogen evolution reactions on Ru, RuO 2 , Ir, and IrO 2 thin film electrodes in acidic and alkaline electrolytes: A comparative study on activity and stability Cherevko, Serhiy; Geiger, Simon; Kasian, Olga Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.08.014	journal	March 2016
Electrochemical Capacitors Using Hydrous Ruthenium Oxide and Hydrogen Inserted Ruthenium Oxide Jow, T. R. Journal of The Electrochemical Society, Vol. 145, Issue 1 https://doi.org/10.1149/1.1838209	journal	January 1998
Structural motifs of water on metal oxide surfaces Mu, Rentao; Zhao, Zhi-jian; Dohnálek, Zdenek Chemical Society Reviews, Vol. 46, Issue 7 https://doi.org/10.1039/C6CS00864J	journal	January 2017
Full Kinetics from First Principles of the Chlorine Evolution Reaction over a RuO ₂ (110) Model Electrode Exner, Kai S.; Anton, Josef; Jacob, Timo Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201511804	journal	May 2016
Oxygen evolution on nanocrystalline RuO2 and Ru0.9Ni0.1O2−δ electrodes – DEMS approach to reaction mechanism determination Macounova, Katerina; Makarova, Marina; Krtil, Petr Electrochemistry Communications, Vol. 11, Issue 10 https://doi.org/10.1016/j.elecom.2009.08.004	journal	October 2009
Mechanism of oxygen reactions at porous oxide electrodes. Part 2—Oxygen evolution at RuO2, IrO2 and IrxRu1−xO2 electrodes in aqueous acid and alkaline solution Lyons, Michael E. G.; Floquet, Stephane Physical Chemistry Chemical Physics, Vol. 13, Issue 12 https://doi.org/10.1039/c0cp02875d	journal	January 2011
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Oxygen evolution on well-characterized mass-selected Ru and RuO ₂ nanoparticles Paoli, Elisa A.; Masini, Federico; Frydendal, Rasmus Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02685C	journal	January 2015
Surface x-ray-scattering measurements of the substrate-induced spatial modulation of an incommensurate adsorbed monolayer Toney, Michael F.; Gordon, Joseph G.; Samant, Mahesh G. Physical Review B, Vol. 42, Issue 9 https://doi.org/10.1103/PhysRevB.42.5594	journal	September 1990
Visualization of Atomic Processes on Ruthenium Dioxide using Scanning Tunneling Microscopy Over, H.; Knapp, M.; Lundgren, E. ChemPhysChem, Vol. 5, Issue 2 https://doi.org/10.1002/cphc.200300833	journal	February 2004
Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting Hisatomi, Takashi; Kubota, Jun; Domen, Kazunari Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60378D	journal	January 2014
Orientation-Dependent Oxygen Evolution Activities of Rutile IrO ₂ and RuO ₂ Stoerzinger, Kelsey A.; Qiao, Liang; Biegalski, Michael D. The Journal of Physical Chemistry Letters, Vol. 5, Issue 10 https://doi.org/10.1021/jz500610u	journal	April 2014
Electrochemical Interfaces of Porous Silicon and Ruthenium Dioxide You, Hoydoo; Chu, Yong S.; Lister, Tedd E. Japanese Journal of Applied Physics, Vol. 38, Issue S1 https://doi.org/10.7567/JJAPS.38S1.239	journal	January 1999
Functional Independent Scaling Relation for ORR/OER Catalysts Christensen, Rune; Hansen, Heine A.; Dickens, Colin F. The Journal of Physical Chemistry C, Vol. 120, Issue 43 https://doi.org/10.1021/acs.jpcc.6b09141	journal	October 2016
XSEDE: Accelerating Scientific Discovery Towns, John; Cockerill, Timothy; Dahan, Maytal Computing in Science & Engineering, Vol. 16, Issue 5 https://doi.org/10.1109/MCSE.2014.80	journal	September 2014
X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111) Liu, Yihua; Barbour, Andi; Komanicky, Vladimir The Journal of Physical Chemistry C, Vol. 120, Issue 29 https://doi.org/10.1021/acs.jpcc.6b00492	journal	March 2016
pH dependence of OER activity of oxides: Current and future perspectives Giordano, Livia; Han, Binghong; Risch, Marcel Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.10.006	journal	March 2016
Oxidation Reactions over RuO2: A Comparative Study of the Reactivity of the (110) Single Crystal and Polycrystalline Surfaces Madhavaram, H.; Idriss, H.; Wendt, S. Journal of Catalysis, Vol. 202, Issue 2 https://doi.org/10.1006/jcat.2001.3281	journal	September 2001
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co²⁺ Kanan, M. W.; Nocera, D. G. Science, Vol. 321, Issue 5892, p. 1072-1075 https://doi.org/10.1126/science.1162018	journal	August 2008
Surface Protonation at the Rutile (110) Interface: Explicit Incorporation of Solvation Structure within the Refined MUSIC Model Framework Machesky, Michael L.; Předota, Milan; Wesolowski, David J. Langmuir, Vol. 24, Issue 21 https://doi.org/10.1021/la801356m	journal	November 2008
Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y. Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr100246c	journal	November 2010
Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes Doyle, Richard L.; Godwin, Ian J.; Brandon, Michael P. Physical Chemistry Chemical Physics, Vol. 15, Issue 33 https://doi.org/10.1039/c3cp51213d	journal	January 2013
Powering the planet with solar fuel Gray, Harry B. Nature Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/nchem.141	journal	April 2009
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong Nature Chemistry, Vol. 9, Issue 5 https://doi.org/10.1038/nchem.2695	journal	January 2017
Interaction of H2O with the RuO2(110) surface studied by HREELS and TDS Lobo, Arun; Conrad, Horst Surface Science, Vol. 523, Issue 3 https://doi.org/10.1016/S0039-6028(02)02459-7	journal	January 2003
Mechanism of oxygen reactions at porous oxide electrodes. Part 1.—Oxygen evolution at RuO2 and RuxSn1–xO2 electrodes in alkaline solution under vigorous electrolysis conditions Lyons, Michael E. G.; Burke, Laurence D. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 83, Issue 2 https://doi.org/10.1039/f19878300299	journal	January 1987
Composition, structure, and stability of ${RuO}_{2} (110)$ as a function of oxygen pressure Reuter, Karsten; Scheffler, Matthias Physical Review B, Vol. 65, Issue 3 https://doi.org/10.1103/PhysRevB.65.035406	journal	December 2001
How to Achieve Maximum Utilization of Hydrous Ruthenium Oxide for Supercapacitors Hu, Chi-Chang; Chen, Wei-Chun; Chang, Kuo-Hsin Journal of The Electrochemical Society, Vol. 151, Issue 2 https://doi.org/10.1149/1.1639020	journal	January 2004
Effect of temperature annealing on capacitive and structural properties of hydrous ruthenium oxides Fang, Wei-Chuan; Huang, Jin-Hua; Chen, Li-Chyong Journal of Power Sources, Vol. 160, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.03.017	journal	October 2006
The Reaction Mechanism with Free Energy Barriers at Constant Potentials for the Oxygen Evolution Reaction at the IrO ₂ (110) Surface Ping, Yuan; Nielsen, Robert J.; Goddard, William A. Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b07557	journal	December 2016
Synthesis and Activities of Rutile IrO ₂ and RuO ₂ Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Lee, Youngmin; Suntivich, Jin; May, Kevin J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016507	journal	January 2012
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico ChemCatChem, Vol. 3, Issue 7 https://doi.org/10.1002/cctc.201000397	journal	March 2011
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Electrolysis of water on oxide surfaces Rossmeisl, J.; Qu, Z. -W.; Zhu, H. Journal of Electroanalytical Chemistry, Vol. 607, Issue 1-2 https://doi.org/10.1016/j.jelechem.2006.11.008	journal	September 2007
The Role of Ru Redox in pH-Dependent Oxygen Evolution on Rutile Ruthenium Dioxide Surfaces Stoerzinger, Kelsey A.; Rao, Reshma R.; Wang, Xiao Renshaw Chem, Vol. 2, Issue 5 https://doi.org/10.1016/j.chempr.2017.04.001	journal	May 2017
Orientation-Dependent Oxygen Evolution on RuO ₂ without Lattice Exchange Stoerzinger, Kelsey A.; Diaz-Morales, Oscar; Kolb, Manuel ACS Energy Letters, Vol. 2, Issue 4 https://doi.org/10.1021/acsenergylett.7b00135	journal	March 2017
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Ion Adsorption at the Rutile−Water Interface: Linking Molecular and Macroscopic Properties Zhang, Z.; Fenter, P.; Cheng, L. Langmuir, Vol. 20, Issue 12 https://doi.org/10.1021/la0353834	journal	June 2004
Commensurate Water Monolayer at the ${RuO}_{2} (110)$ /Water Interface Chu, Y. S.; Lister, T. E.; Cullen, W. G. Physical Review Letters, Vol. 86, Issue 15 https://doi.org/10.1103/PhysRevLett.86.3364	journal	April 2001
Surface Chemistry of Late Transition Metal Oxides Weaver, Jason F. Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300323w	journal	December 2012
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Cathodic activation of RuO 2 single crystal surfaces for hydrogen-evolution reaction Lister, T. E.; Tolmachev, Y. V.; Chu, Y. Journal of Electroanalytical Chemistry, Vol. 554-555 https://doi.org/10.1016/S0022-0728(03)00048-2	journal	September 2003
Catalytic Oxidation of Ammonia on RuO ₂ (110) Surfaces: Mechanism and Selectivity Wang, Y.; Jacobi, K.; Schöne, W. -D. The Journal of Physical Chemistry B, Vol. 109, Issue 16 https://doi.org/10.1021/jp045735v	journal	April 2005
Characterization of Various Oxygen Species on an Oxide Surface: RuO ₂ (110) ^† Kim, Y. D.; Seitsonen, A. P.; Wendt, S. The Journal of Physical Chemistry B, Vol. 105, Issue 18 https://doi.org/10.1021/jp003213j	journal	May 2001
In situ x-ray-diffraction and -reflectivity studies of the Au(111)/electrolyte interface: Reconstruction and anion adsorption Wang, Jia; Ocko, B. M.; Davenport, Alison J. Physical Review B, Vol. 46, Issue 16 https://doi.org/10.1103/PhysRevB.46.10321	journal	October 1992
Ruthenium dioxide-based film electrodes: III. Effect of chemical composition and surface morphology on oxygen evolution in acid solutions Lodi, G.; Sivieri, E.; De Battisti, A. Journal of Applied Electrochemistry, Vol. 8, Issue 2 https://doi.org/10.1007/BF00617671	journal	March 1978
Electrocatalytic Oxygen Evolution Reaction in Acidic Environments - Reaction Mechanisms and Catalysts Reier, Tobias; Nong, Hong Nhan; Teschner, Detre Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601275	journal	October 2016
Deprotonated Water Dimers: The Building Blocks of Segmented Water Chains on Rutile RuO ₂ (110) Mu, Rentao; Cantu, David C.; Glezakou, Vassiliki-Alexandra The Journal of Physical Chemistry C, Vol. 119, Issue 41 https://doi.org/10.1021/acs.jpcc.5b07158	journal	August 2015
Surface X-ray diffraction studies of single crystal electrocatalysts Gründer, Yvonne; Lucas, Christopher A. Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.05.043	journal	November 2016
Voltage-Controlled Interfacial Layering in an Ionic Liquid on SrTiO ₃ Petach, Trevor A.; Mehta, Apurva; Marks, Ronald ACS Nano, Vol. 10, Issue 4 https://doi.org/10.1021/acsnano.6b00645	journal	March 2016
Atomic-Scale Structure and Catalytic Reactivity of the RuO2(110) Surface Over, H. Science, Vol. 287, Issue 5457 https://doi.org/10.1126/science.287.5457.1474	journal	February 2000
Spectroscopic characterization of catalytically active surface sites of a metallic oxide Over, H.; Seitsonen, Ari P.; Lundgren, E. Chemical Physics Letters, Vol. 342, Issue 5-6 https://doi.org/10.1016/S0009-2614(01)00627-3	journal	July 2001
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
Interaction of NO with the Stoichiometric RuO ₂ (110) Surface Wang, Y.; Jacobi, K.; Ertl, G. The Journal of Physical Chemistry B, Vol. 107, Issue 50 https://doi.org/10.1021/jp0308108	journal	December 2003
Electrocatalysis in the anodic evolution of oxygen and chlorine Trasatti, S. Electrochimica Acta, Vol. 29, Issue 11, p. 1503-1512 https://doi.org/10.1016/0013-4686(84)85004-5	journal	November 1984
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II Duan, Lele; Bozoglian, Fernando; Mandal, Sukanta Nature Chemistry, Vol. 4, Issue 5 https://doi.org/10.1038/nchem.1301	journal	March 2012
Oxygen evolution on Ru and RuO2 electrodes studied using isotope labelling and on-line mass spectrometry Wohlfahrt-Mehrens, M.; Heitbaum, J. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 237, Issue 2 https://doi.org/10.1016/0022-0728(87)85237-3	journal	November 1987
Surface Chemistry of Ruthenium Dioxide in Heterogeneous Catalysis and Electrocatalysis: From Fundamental to Applied Research Over, Herbert Chemical Reviews, Vol. 112, Issue 6 https://doi.org/10.1021/cr200247n	journal	March 2012
Influence of Surface Adsorption on the Oxygen Evolution Reaction on IrO ₂ (110) Kuo, Ding-Yuan; Kawasaki, Jason K.; Nelson, Jocienne N. Journal of the American Chemical Society, Vol. 139, Issue 9 https://doi.org/10.1021/jacs.6b11932	journal	February 2017
Hydrogen production by advanced proton exchange membrane (PEM) water electrolysers—Reduced energy consumption by improved electrocatalysis Marshall, A.; Børresen, B.; Hagen, G. Energy, Vol. 32, Issue 4 https://doi.org/10.1016/j.energy.2006.07.014	journal	April 2007
Stable Deacon Process for HCl Oxidation over RuO2 Crihan, Daniela; Knapp, Marcus; Zweidinger, Stefan Angewandte Chemie International Edition, Vol. 47, Issue 11 https://doi.org/10.1002/anie.200705124	journal	February 2008
Electrochemical and X-ray scattering study of well defined RuO2 single crystal surfaces Lister, T. E.; Chu, Y.; Cullen, W. Journal of Electroanalytical Chemistry, Vol. 524-525 https://doi.org/10.1016/S0022-0728(02)00744-1	journal	May 2002
Stable Deacon Process for HCl Oxidation over RuO2 Crihan, Daniela; Knapp, Marcus; Zweidinger, Stefan Angewandte Chemie, Vol. 120, Issue 11 https://doi.org/10.1002/ange.200705124	journal	February 2008
Full Kinetics from First Principles of the Chlorine Evolution Reaction over a RuO ₂ (110) Model Electrode Exner, Kai S.; Anton, Josef; Jacob, Timo Angewandte Chemie, Vol. 128, Issue 26 https://doi.org/10.1002/ange.201511804	journal	May 2016
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
Key role of chemistry versus bias in electrocatalytic oxygen evolution Nong, Hong Nhan; Falling, Lorenz J.; Bergmann, Arno Nature, Vol. 587, Issue 7834 https://doi.org/10.1038/s41586-020-2908-2	journal	November 2020
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020
Visualization of atomic processes on ruthenium dioxide using scanning tunneling microscopy Over, H.; Knapp, M.; Lundgren, E. Wiley-Blackwell https://doi.org/10.5167/uzh-3440	text	January 2004
Commensurate Water Monolayer at the RuO2(110)/Water Interface Chu, Y. S.; Cullen, W. G.; Lister, T. E. The American Physical Society https://doi.org/10.17877/de290r-7055	text	January 2001
Voltage Controlled Interfacial Layering in an Ionic Liquid on SrTiO$_3$ Petach, Trevor A.; Mehta, Apurva; Marks, Ronald arXiv https://doi.org/10.48550/arxiv.1603.08285	text	January 2016
Surface Core-Level Shifts at an oxygen-rich Ru Surface: O/Ru(0001) vs. RuO_2(110) Reuter, Karsten; Scheffler, Matthias arXiv https://doi.org/10.48550/arxiv.cond-mat/0104306	text	January 2001

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Optimization of oxygen evolution dynamics on RuO ₂ via controlling of spontaneous dissociation equilibrium Sun, Yu; Yuan, Long; Liu, Zhongyuan Materials Chemistry Frontiers, Vol. 3, Issue 9 https://doi.org/10.1039/c9qm00346k	journal	January 2019
Non-redox doping boosts oxygen evolution electrocatalysis on hematite Nguyën, Huu Chuong; Garcés-Pineda, Felipe Andrés; de Fez-Febré, Mabel Chemical Science, Vol. 11, Issue 9 https://doi.org/10.1039/c9sc05669f	journal	January 2020
A template-directed bifunctional NiS _x /nitrogen-doped mesoporous carbon electrocatalyst for rechargeable Zn–air batteries Wan, Kai; Luo, Jiangshui; Zhang, Xuan Journal of Materials Chemistry A, Vol. 7, Issue 34 https://doi.org/10.1039/c9ta06446j	journal	January 2019
Chlorine evolution reaction electrocatalysis on RuO ₂ (110) and IrO ₂ (110) grown using molecular-beam epitaxy Kuo, Ding-Yuan; Paik, Hanjong; Nelson, Jocienne N. The Journal of Chemical Physics, Vol. 150, Issue 4 https://doi.org/10.1063/1.5051429	journal	January 2019
Short O–O separation in layered oxide Na _0.67 CoO ₂ enables an ultrafast oxygen evolution reaction Wang, Hao; Wu, Jinpeng; Dolocan, Andrei Proceedings of the National Academy of Sciences, Vol. 116, Issue 47 https://doi.org/10.1073/pnas.1901046116	journal	November 2019

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Title: Towards identifying the active sites on RuO ₂ (110) in catalyzing oxygen evolution