In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries

Glazer, Matthew P. B.; Wang, Junjie; Cho, Jiung; Almer, Jonathan D.; Okasinski, John S.; Braun, Paul V.; Dunand, David C.

doi:10.1016/j.jpowsour.2017.09.040

Title: In operando X-ray diffraction strain measurement in Ni₃Sn₂ – Coated inverse opal nanoscaffold anodes for Li-ion batteries

Journal Article · Wed Nov 01 00:00:00 EDT 2017 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2017.09.040· OSTI ID:1432952

^[1]; Wang, Junjie ^[2]; Cho, Jiung ^[3]; Almer, Jonathan D. ^[4]; Okasinski, John S. ^[4]; Braun, Paul V. ^[2]; Dunand, David C. ^[5]

Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering; Exponent Inc., Menlo Park, CA (United States). Materials and Corrosion Engineering Practice
Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science and Engineering
Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science and Engineering; Korea Basic Science Inst., Gangneung (Korea, Republic of). Gangneung Center
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering

Volume changes associated with the (de)lithiation of a nanostructured Ni₃Sn₂ coated nickel inverse opal scaffold anode create mismatch stresses and strains between the Ni₃Sn₂ anode material and its mechanically supporting Ni scaffold. By using in operando synchrotron x-ray diffraction measurements, elastic strains in the Ni scaffold are determined during cyclic (dis)charging of the Ni₃Sn₂ anode. These strains are characterized using both the center position of the Ni diffraction peaks, to quantify the average strain, and the peak breadth, which describes the distribution of strain in the measured volume. Upon lithiation (half-cell discharging) or delithiation (half-cell charging), compressive strains and peak breadth linearly increase or decrease, respectively, with charge. The evolution of the average strains and peak breadths suggests that some irreversible plastic deformation and/or delamination occurs during cycling, which can result in capacity fade in the anode. The strain behavior associated with cycling of the Ni₃Sn₂ anode is similar to that observed in recent studies on a Ni inverse-opal supported amorphous Si anode and demonstrates that the (de)lithiation-induced deformation and damage mechanisms are likely equivalent in both anodes, even though the magnitude of mismatch strain in the Ni₃Sn₂ is lower due to the lower (de)lithiation-induced contraction/expansion.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; FG02-07ER46471

OSTI ID:: 1432952

Alternate ID(s):: OSTI ID: 1549316; OSTI ID: 1875504

Journal Information:: Journal of Power Sources, Vol. 367, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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References (46)

Rechargeable lithium batteries and beyond: Progress, challenges, and future directions Amine, Khalil; Kanno, Ryoji; Tzeng, Yonhua MRS Bulletin, Vol. 39, Issue 5 https://doi.org/10.1557/mrs.2014.62	journal	May 2014
Three-dimensional electrodes and battery architectures Arthur, Timothy S.; Bates, Daniel J.; Cirigliano, Nicolas MRS Bulletin, Vol. 36, Issue 7 https://doi.org/10.1557/mrs.2011.156	journal	July 2011
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
History, Evolution, and Future Status of Energy Storage Whittingham, M. S. Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue https://doi.org/10.1109/JPROC.2012.2190170	journal	May 2012
A review of the electrochemical performance of alloy anodes for lithium-ion batteries Zhang, Wei-Jun Journal of Power Sources, Vol. 196, Issue 1 https://doi.org/10.1016/j.jpowsour.2010.07.020	journal	January 2011
Nanostructured electrodes for lithium-ion and lithium-air batteries: the latest developments, challenges, and perspectives Song, Min-Kyu; Park, Soojin; Alamgir, Faisal M. Materials Science and Engineering: R: Reports, Vol. 72, Issue 11 https://doi.org/10.1016/j.mser.2011.06.001	journal	November 2011
25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium-Ion Batteries McDowell, Matthew T.; Lee, Seok Woo; Nix, William D. Advanced Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adma.201301795	journal	August 2013
Nanomaterials for lithium ion batteries Jiang, Chunhai; Hosono, Eiji; Zhou, Haoshen Nano Today, Vol. 1, Issue 4 https://doi.org/10.1016/S1748-0132(06)70114-1	journal	November 2006
Structuring materials for lithium-ion batteries: advancements in nanomaterial structure, composition, and defined assembly on cell performance Osiak, Michal; Geaney, Hugh; Armstrong, Eileen Journal of Materials Chemistry A, Vol. 2, Issue 25 https://doi.org/10.1039/c4ta00534a	journal	January 2014
Porous Electrode Materials for Lithium-Ion Batteries - How to Prepare Them and What Makes Them Special Vu, Anh; Qian, Yuqiang; Stein, Andreas Advanced Energy Materials, Vol. 2, Issue 9 https://doi.org/10.1002/aenm.201200320	journal	August 2012
Monodisperse Sn Nanocrystals as a Platform for the Study of Mechanical Damage during Electrochemical Reactions with Li Xu, Linping; Kim, Chunjoong; Shukla, Alpesh K. Nano Letters, Vol. 13, Issue 4 https://doi.org/10.1021/nl400418c	journal	March 2013
Lithium alloy negative electrodes Huggins, Robert A. Journal of Power Sources, Vol. 81-82, p. 13-19 https://doi.org/10.1016/S0378-7753(99)00124-X	journal	September 1999
Metallic Negative Electrode Materials for Rechargeable Nonaqueous Batteries Ehrlich, G. M.; Durand, C.; Chen, X. Journal of The Electrochemical Society, Vol. 147, Issue 3 https://doi.org/10.1149/1.1393287	journal	January 2000
Tin-based composite materials as anode materials for Li-ion batteries Ahn, J. -H.; Wang, G. X.; Yao, J. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00122-8	journal	June 2003
Lithium insertion/extraction mechanism in alloy anodes for lithium-ion batteries Zhang, Wei-Jun Journal of Power Sources, Vol. 196, Issue 3 https://doi.org/10.1016/j.jpowsour.2010.08.114	journal	February 2011
Alloy Design for Lithium-Ion Battery Anodes Obrovac, M. N.; Christensen, Leif; Le, Dinh Ba Journal of The Electrochemical Society, Vol. 154, Issue 9, p. A849-A855 https://doi.org/10.1149/1.2752985	journal	January 2007
Plastic deformation associated with phase transformations during lithiation/delithiation of Sn Mukhopadhyay, Amartya; Kali, Ravi; Badjate, Shubham Scripta Materialia, Vol. 92 https://doi.org/10.1016/j.scriptamat.2014.08.011	journal	December 2014
Mechanical analysis and in situ structural and morphological evaluation of Ni–Sn alloy anodes for Li ion batteries Chen, J.; Bull, S. J.; Roy, S. Journal of Physics D: Applied Physics, Vol. 41, Issue 2 https://doi.org/10.1088/0022-3727/41/2/025302	journal	December 2007
In situ TEM electrochemistry of anode materials in lithium ion batteries Liu, Xiao Hua; Huang, Jian Yu Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01918j	journal	January 2011
The Electrochemical Reaction of Lithium with Tin Studied By In Situ AFM Beaulieu, L. Y.; Beattie, S. D.; Hatchard, T. D. Journal of The Electrochemical Society, Vol. 150, Issue 4 https://doi.org/10.1149/1.1556595	journal	January 2003
In Situ Transmission X-ray Microscopy Study on Working SnO Anode Particle of Li-Ion Batteries Chao, Sung-Chieh; Yen, Yu-Chan; Song, Yen-Fang Journal of The Electrochemical Society, Vol. 158, Issue 12 https://doi.org/10.1149/2.043112jes	journal	January 2011
Study on Microstructural Deformation of Working Sn and SnSb Anode Particles for Li-Ion Batteries by in Situ Transmission X-ray Microscopy Chao, Sung-Chieh; Song, Yen-Fang; Wang, Chun-Chieh The Journal of Physical Chemistry C, Vol. 115, Issue 44 https://doi.org/10.1021/jp206829q	journal	October 2011
A study on the interior microstructures of working Sn particle electrode of Li-ion batteries by in situ X-ray transmission microscopy Chao, Sung-Chieh; Yen, Yu-Chan; Song, Yen-Fang Electrochemistry Communications, Vol. 12, Issue 2 https://doi.org/10.1016/j.elecom.2009.12.002	journal	February 2010
Visualization and Quantification of Electrochemical and Mechanical Degradation in Li Ion Batteries Ebner, M.; Marone, F.; Stampanoni, M. Science, Vol. 342, Issue 6159 https://doi.org/10.1126/science.1241882	journal	October 2013
Deformation and stress in electrode materials for Li-ion batteries Mukhopadhyay, Amartya; Sheldon, Brian W. Progress in Materials Science, Vol. 63 https://doi.org/10.1016/j.pmatsci.2014.02.001	journal	June 2014
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Load partitioning during compressive loading of a Mg/MgB2 composite Young, M. L.; DeFouw, J.; Almer, J. D. Acta Materialia, Vol. 55, Issue 10 https://doi.org/10.1016/j.actamat.2007.01.046	journal	June 2007
Internal strains and stresses measured in cortical bone via high-energy X-ray diffraction Almer, J. D.; Stock, S. R. Journal of Structural Biology, Vol. 152, Issue 1 https://doi.org/10.1016/j.jsb.2005.08.003	journal	October 2005
Through-thickness determination of phase composition and residual stresses in thermal barrier coatings using high-energy X-rays Weyant, C. M.; Almer, J.; Faber, K. T. Acta Materialia, Vol. 58, Issue 3 https://doi.org/10.1016/j.actamat.2009.10.010	journal	February 2010
In Operando Strain Measurement of Bicontinuous Silicon-Coated Nickel Inverse Opal Anodes for Li-Ion Batteries Glazer, Matthew P. B.; Cho, Jiung; Almer, Jonathan Advanced Energy Materials, Vol. 5, Issue 14 https://doi.org/10.1002/aenm.201500466	journal	May 2015
Sn buffered by shape memory effect of NiTi alloys as high-performance anodes for lithium ion batteries Hu, Renzong; Zhu, Min; Wang, Hui Acta Materialia, Vol. 60, Issue 12 https://doi.org/10.1016/j.actamat.2012.05.015	journal	July 2012
A combined Mössbauer spectroscopy and x-ray diffraction operando study of Sn-based composite anode materials for Li-ion accumulators Conte, Donato E.; Mouyane, Mohamed; Stievano, Lorenzo Journal of Solid State Electrochemistry, Vol. 16, Issue 12 https://doi.org/10.1007/s10008-012-1824-2	journal	July 2012
The phase transformations and cycling performance of copper–tin alloy anode materials synthesized by sputtering Lin, Yu-Sheng; Duh, Jenq-Gong; Sheu, Hwo-Shuenn Journal of Alloys and Compounds, Vol. 509, Issue 1 https://doi.org/10.1016/j.jallcom.2010.08.148	journal	January 2011
TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations by operando-XRD and Mössbauer techniques Sougrati, M. T.; Fullenwarth, J.; Debenedetti, A. Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c1jm10710k	journal	January 2011
High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes Pikul, James H.; Gang Zhang, Hui; Cho, Jiung Nature Communications, Vol. 4, Article No. 1732 https://doi.org/10.1038/ncomms2747	journal	April 2013
Calibration and correction of distortions in two‐dimensional detector systems ^a) Hammersley, A. P.; Svensson, S. O.; Thompson, A. Review of Scientific Instruments, Vol. 66, Issue 3 https://doi.org/10.1063/1.1145618	journal	March 1995
Structural Characterization of Nanostructured Nickel Coated Carbon Fibers by X-Ray Line Broadening Fares, M.; Debili, M. Y. e-Journal of Surface Science and Nanotechnology, Vol. 6 https://doi.org/10.1380/ejssnt.2008.258	journal	January 2008
A comparison between different X-ray diffraction line broadening analysis methods for nanocrystalline ball-milled FCC powders Soleimanian, V.; Mojtahedi, M. Applied Physics A, Vol. 119, Issue 3 https://doi.org/10.1007/s00339-015-9054-y	journal	February 2015
The contrast factors of dislocations in cubic crystals: the dislocation model of strain anisotropy in practice Ungár, T.; Dragomir, I.; Révész, Á. Journal of Applied Crystallography, Vol. 32, Issue 5 https://doi.org/10.1107/S0021889899009334	journal	October 1999
Deformation and fracture of electrodeposited copper Ebrahimi, F.; Zhai, Q.; Kong, D. Scripta Materialia, Vol. 39, Issue 3 https://doi.org/10.1016/S1359-6462(98)00164-X	journal	July 1998
Stress measurements in nanocrystalline Ni electrodeposits El-Sherik, A. M.; Shirokoff, J.; Erb, U. Journal of Alloys and Compounds, Vol. 389, Issue 1-2 https://doi.org/10.1016/j.jallcom.2004.08.010	journal	March 2005
Residual stresses in electrodeposits of nickel and nickel–iron alloys Hadian, S. E.; Gabe, D. R. Surface and Coatings Technology, Vol. 122, Issue 2-3 https://doi.org/10.1016/S0257-8972(99)00328-X	journal	December 1999
Mechanical properties of nanocrystalline nickel produced by electrodeposition Ebrahimi, F.; Bourne, G. R.; Kelly, M. S. Nanostructured Materials, Vol. 11, Issue 3 https://doi.org/10.1016/S0965-9773(99)00050-1	journal	May 1999
A finite strain model of stress, diffusion, plastic flow, and electrochemical reactions in a lithium-ion half-cell Bower, A. F.; Guduru, P. R.; Sethuraman, V. A. Journal of the Mechanics and Physics of Solids, Vol. 59, Issue 4 https://doi.org/10.1016/j.jmps.2011.01.003	journal	April 2011
A simple finite element model of diffusion, finite deformation, plasticity and fracture in lithium ion insertion electrode materials Bower, A. F.; Guduru, P. R. Modelling and Simulation in Materials Science and Engineering, Vol. 20, Issue 4 https://doi.org/10.1088/0965-0393/20/4/045004	journal	April 2012
An X-ray diffraction study of the residual stress-strain distributions in shot-peened two-phase brass Noyan, I. C.; Cohen, J. B. Materials Science and Engineering, Vol. 75, Issue 1-2 https://doi.org/10.1016/0025-5416(85)90188-0	journal	November 1985

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Title: In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries

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Title: In operando X-ray diffraction strain measurement in Ni₃Sn₂ – Coated inverse opal nanoscaffold anodes for Li-ion batteries