Synchrotron-based ambient pressure X-ray photoelectron spectroscopy of hydrogen and helium

Zhong, Jian-Qiang; Wang, Mengen; Hoffmann, William H.; van Spronsen, Matthijs A.; Lu, Deyu; Boscoboinik, J. Anibal

doi:10.1063/1.5022479

Title: Synchrotron-based ambient pressure X-ray photoelectron spectroscopy of hydrogen and helium

Journal Article · Thu Mar 01 00:00:00 EST 2018 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.5022479· OSTI ID:1430858

^[1]; Wang, Mengen ^[2]; Hoffmann, William H. ^[3];

^[4];

^[1];

^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering
North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemical and Biomolecular Engineering
Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry and Chemical Biology

Contrary to popular belief, it is possible to obtain X-ray photoelectron spectra for elements lighter than lithium, namely hydrogen and helium. The literature is plagued with claims of this impossibility, which holds true for lab-based X-ray sources. However, this limitation is merely technical and is related mostly to the low X-ray photoionization cross-sections of the 1s orbitals of hydrogen and helium. Here, we show that, using ambient pressure X-ray photoelectron spectroscopy (XPS), a bright-enough X-ray source allows the study of these elusive elements. This has important implications in the understanding of the limitations of one of the most useful techniques in materials science, and moreover, it potentially opens the possibility of using XPS to directly study the most abundant element in the universe.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS)

Grant/Contract Number:: SC0012704; SC0012573; AC02-05CH11231

OSTI ID:: 1430858

Alternate ID(s):: OSTI ID: 1423385

Report Number(s):: BNL-203379-2018-JAAM; TRN: US1802506

Journal Information:: Applied Physics Letters, Vol. 112, Issue 9; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

References (34)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
A Comparison of the Adsorption and Diffusion of Hydrogen on the {111} Surfaces of Ni, Pd, and Pt from Density Functional Theory Calculations Watson, Graeme W.; Wells, Richard P. K.; Willock, David J. The Journal of Physical Chemistry B, Vol. 105, Issue 21 https://doi.org/10.1021/jp002864c	journal	May 2001
A review on clean energy solutions for better sustainability: A review on clean energy solutions for better sustainability Dincer, Ibrahim; Acar, Canan International Journal of Energy Research, Vol. 39, Issue 5 https://doi.org/10.1002/er.3329	journal	March 2015
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy Starr, D. E.; Liu, Z.; Hävecker, M. Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60057b	journal	January 2013
Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103 Yeh, J. J.; Lindau, I. Atomic Data and Nuclear Data Tables, Vol. 32, Issue 1 https://doi.org/10.1016/0092-640X(85)90016-6	journal	January 1985
985. Molecular photoelectron spectroscopy. Part I. The hydrogen and nitrogen molecules Al-Joboury, M. I.; Turner, D. W. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9630005141	journal	January 1963
Why Can’t We See Hydrogen in X-ray Photoelectron Spectroscopy? Stojilovic, Nenad Journal of Chemical Education, Vol. 89, Issue 10 https://doi.org/10.1021/ed300057j	journal	July 2012
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
The nature of hydrogen in x‐ray photoelectron spectroscopy: General patterns from hydroxides to hydrogen bonding Kerber, S. J.; Bruckner, J. J.; Wozniak, K. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 14, Issue 3 https://doi.org/10.1116/1.579947	journal	May 1996
Hydrogen and Deuterium Exchange on Pt(111) and Its Poisoning by Carbon Monoxide Studied by Surface Sensitive High-Pressure Techniques Montano, Max; Bratlie, Kaitlin; Salmeron, Miquel Journal of the American Chemical Society, Vol. 128, Issue 40 https://doi.org/10.1021/ja063703a	journal	October 2006
The dissociative adsorption of hydrogen on defect-‘free’ Pt(111) Poelsema, Bene; Lenz, Klaus; Comsa, George Journal of Physics: Condensed Matter, Vol. 22, Issue 30 https://doi.org/10.1088/0953-8984/22/30/304006	journal	July 2010
A differentially pumped electrostatic lens system for photoemission studies in the millibar range Ogletree, D. Frank; Bluhm, Hendrik; Lebedev, Gennadi Review of Scientific Instruments, Vol. 73, Issue 11 https://doi.org/10.1063/1.1512336	journal	November 2002
Direct Work Function Measurement by Gas Phase Photoelectron Spectroscopy and Its Application on PbS Nanoparticles Axnanda, Stephanus; Scheele, Marcus; Crumlin, Ethan Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403524a	journal	November 2013
Dissociative photoionization of H ₂ from 18 to 124 eV Chung, Y. M.; Lee, E. ‐M.; Masuoka, T. The Journal of Chemical Physics, Vol. 99, Issue 2 https://doi.org/10.1063/1.465352	journal	July 1993
In situ X-ray photoelectron spectroscopy study of complex oxides under gas and vacuum environments Paloukis, F.; Papazisi, K. M.; Balomenou, S. P. Applied Surface Science, Vol. 423 https://doi.org/10.1016/j.apsusc.2017.06.219	journal	November 2017
Adsorption of hydrogen on a Pt(111) surface Christmann, K.; Ertl, G.; Pignet, T. Surface Science, Vol. 54, Issue 2 https://doi.org/10.1016/0039-6028(76)90232-6	journal	February 1976
Synchrotron-based Ambient Pressure X-ray Photoelectron Spectroscopy Shavorskiy, Andrey; Karslioglu, Osman; Zegkinoglou, Ioannis Synchrotron Radiation News, Vol. 27, Issue 2 https://doi.org/10.1080/08940886.2014.889547	journal	March 2014
The dissociative adsorption of hydrogen on Pt(111): Actuation and acceleration by atomic defects Poelsema, Bene; Lenz, Klaus; Comsa, George The Journal of Chemical Physics, Vol. 134, Issue 7 https://doi.org/10.1063/1.3530286	journal	February 2011
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Electron Spectroscopy for Chemical Analysis (E.S.C.A.) Siegbahn, K. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 268, Issue 1184 https://doi.org/10.1098/rsta.1970.0060	journal	November 1970
Graphene Membranes for Atmospheric Pressure Photoelectron Spectroscopy Weatherup, Robert S.; Eren, Baran; Hao, Yibo The Journal of Physical Chemistry Letters, Vol. 7, Issue 9 https://doi.org/10.1021/acs.jpclett.6b00640	journal	April 2016
Numerical investigation of the validity of the Slater-Janak transition-state model in metallic systems Göransson, C.; Olovsson, W.; Abrikosov, I. A. Physical Review B, Vol. 72, Issue 13 https://doi.org/10.1103/PhysRevB.72.134203	journal	October 2005
High coherent flux at the NSLS-II coherent soft x-ray beamline Sánchez-Hanke, C.; Hulbert, S. L.; Shapiro, D. Journal of Physics: Conference Series, Vol. 425, Issue 15 https://doi.org/10.1088/1742-6596/425/15/152017	journal	March 2013
A surface core-level shift study of hydrogen interaction with Rh(111) Weststrate, C. J.; Baraldi, A.; Rumiz, L. Surface Science, Vol. 566-568 https://doi.org/10.1016/j.susc.2004.05.089	journal	September 2004
Ambient pressure photoelectron spectroscopy: A new tool for surface science and nanotechnology Salmeron, M.; Schlogl, R. Surface Science Reports, Vol. 63, Issue 4 https://doi.org/10.1016/j.surfrep.2008.01.001	journal	April 2008
Probing the effect of the Pt–Ni–Pt(111) bimetallic surface electronic structures on the ammonia decomposition reaction Zhong, Jian-Qiang; Zhou, Xiong; Yuan, Kaidi Nanoscale, Vol. 9, Issue 2 https://doi.org/10.1039/C6NR08311K	journal	January 2017
ESCA applied to liquids Siegbahn, Hans; Siegbahn, Kai Journal of Electron Spectroscopy and Related Phenomena, Vol. 2, Issue 3 https://doi.org/10.1016/0368-2048(73)80023-4	journal	January 1973
Towards the computational design of solid catalysts Nørskov, J.; Bligaard, T.; Rossmeisl, J. Nature Chemistry, Vol. 1, Issue 1, p. 37-46 https://doi.org/10.1038/nchem.121	journal	April 2009
Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001) Zhong, Jian-Qiang; Kestell, John; Waluyo, Iradwikanari The Journal of Physical Chemistry C, Vol. 120, Issue 15 https://doi.org/10.1021/acs.jpcc.6b02851	journal	April 2016
Vibrational States of the Hydrogen Molecular Ion Cohen, Stanley; Hiskes, John R.; Riddell, Robert J. Physical Review, Vol. 119, Issue 3 https://doi.org/10.1103/PhysRev.119.1025	journal	August 1960
Energetics and Vibrational States for Hydrogen on Pt(111) Bădescu, Ş. C.; Salo, P.; Ala-Nissila, T. Physical Review Letters, Vol. 88, Issue 13 https://doi.org/10.1103/PhysRevLett.88.136101	journal	March 2002
HeI α photoelectron modulation spectroscopy of H ₂ and D ₂ van der Meer, W. J.; van Lonkhuyzen, H.; Butselaar, R. J. The Journal of Chemical Physics, Vol. 83, Issue 12 https://doi.org/10.1063/1.449613	journal	December 1985
The survey of key technologies in hydrogen energy storage Zhang, Fan; Zhao, Pengcheng; Niu, Meng International Journal of Hydrogen Energy, Vol. 41, Issue 33 https://doi.org/10.1016/j.ijhydene.2016.05.293	journal	September 2016
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021

Cited By (1)

Nondipole effects in helium ionization by intense soft x-ray laser pulses Bachau, Henri; Dieng, Matabara The European Physical Journal D, Vol. 73, Issue 6 https://doi.org/10.1140/epjd/e2019-100061-x	journal	June 2019

Similar Records

Carbon monoxide, CO(g), by high-resolution near-ambient-pressure x-ray photoelectron spectroscopy

Journal Article · Tue Feb 25 00:00:00 EST 2020 · Surface Science Spectra · OSTI ID:1430858

O’Connor, Christopher R.; Boscoboinik, Jorge Anibal; Karatok, Mustafa; +1 more

In-situ X-ray photoelectron spectroscopy studies of water on metals and oxides at ambient conditions

Journal Article · Mon Oct 29 00:00:00 EDT 2007 · Journal of Physics: Condensed Matter · OSTI ID:1430858

Salmeron, Miquel; Yamamoto, S; Bluhm, H; +5 more

Ambient pressure x-ray photoelectron spectroscopy study of water formation and adsorption under two-dimensional silica and aluminosilicate layers on Pd(111)

Journal Article · Tue Feb 25 00:00:00 EST 2020 · Journal of Chemical Physics · OSTI ID:1430858

Jhang, Jin-Hao; Boscoboinik, Jorge Anibal; Altman, Eric I.

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
Spectroscopy
Condensed matter properties
X-ray spectroscopy
Chemical analysis
Surface collisions
Photoionization
Optical sources
Materials analysis
Physical optics
X-ray photoelectron spectroscopy

Title: Synchrotron-based ambient pressure X-ray photoelectron spectroscopy of hydrogen and helium

Citation Formats

References (34)

Cited By (1)

Similar Records

Related Subjects