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Title: Scalable fabrication of perovskite solar cells

Journal Article · · Nature Reviews. Materials

Perovskite materials use earth-abundant elements, have low formation energies for deposition and are compatible with roll-to-roll and other high-volume manufacturing techniques. These features make perovskite solar cells (PSCs) suitable for terawatt-scale energy production with low production costs and low capital expenditure. Demonstrations of performance comparable to that of other thin-film photovoltaics (PVs) and improvements in laboratory-scale cell stability have recently made scale up of this PV technology an intense area of research focus. Here, we review recent progress and challenges in scaling up PSCs and related efforts to enable the terawatt-scale manufacturing and deployment of this PV technology. We discuss common device and module architectures, scalable deposition methods and progress in the scalable deposition of perovskite and charge-transport layers. We also provide an overview of device and module stability, module-level characterization techniques and techno-economic analyses of perovskite PV modules.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), NREL Laboratory Directed Research and Development (LDRD)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1430821
Report Number(s):
NREL/JA-5900-70427; TRN: US1802503
Journal Information:
Nature Reviews. Materials, Vol. 3, Issue 4; ISSN 2058-8437
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 579 works
Citation information provided by
Web of Science

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Meniscus-assisted solution printing of large-grained perovskite films for high-efficiency solar cells journal July 2017
Low-temperature-processed efficient semi-transparent planar perovskite solar cells for bifacial and tandem applications journal November 2015
Hydrophobic Organic Hole Transporters for Improved Moisture Resistance in Metal Halide Perovskite Solar Cells journal February 2016
A generic interface to reduce the efficiency-stability-cost gap of perovskite solar cells journal November 2017
o -Methoxy Substituents in Spiro-OMeTAD for Efficient Inorganic–Organic Hybrid Perovskite Solar Cells journal May 2014
A simple in situ tubular chemical vapor deposition processing of large-scale efficient perovskite solar cells and the research on their novel roll-over phenomenon in J–V curves journal January 2015
Precise Morphology Control and Continuous Fabrication of Perovskite Solar Cells Using Droplet-Controllable Electrospray Coating System journal February 2017
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journal December 2013
Benefits of very thin PCBM and LiF layers for solution-processed p–i–n perovskite solar cells journal January 2014
Make perovskite solar cells stable journal April 2017
Material nucleation/growth competition tuning towards highly reproducible planar perovskite solar cells with efficiency exceeding 20% journal January 2017
Quantification of spatial inhomogeneity in perovskite solar cells by hyperspectral luminescence imaging journal January 2016
Laser-Scribing Patterning for the Production of Organometallic Halide Perovskite Solar Modules journal July 2015
Low-Temperature Solution-Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells journal May 2015
CuSCN-Based Inverted Planar Perovskite Solar Cell with an Average PCE of 15.6% journal May 2015
A solvent- and vacuum-free route to large-area perovskite films for efficient solar modules journal September 2017
Laminated Carbon Nanotube Networks for Metal Electrode-Free Efficient Perovskite Solar Cells journal June 2014
Efficient planar heterojunction perovskite solar cells by vapour deposition journal September 2013
Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process journal January 2014
A Fast Deposition-Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin-Film Solar Cells journal July 2014
Ion-Exchange-Induced 2D-3D Conversion of HMA 1− x FA x PbI 3 Cl Perovskite into a High-Quality MA 1− x FA x PbI 3 Perovskite journal September 2016
Composition Engineering in Doctor-Blading of Perovskite Solar Cells text January 2017

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Revealing the Dynamics of Hybrid Metal Halide Perovskite Formation via Multimodal In Situ Probes journal December 2019
High‐Performance Flexible Perovskite Solar Cells Enabled by Low‐Temperature ALD‐Assisted Surface Passivation journal October 2018
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The synergistic effect of cooperating solvent vapor annealing for high-efficiency planar inverted perovskite solar cells journal January 2019
Br-containing alkyl ammonium salt-enabled scalable fabrication of high-quality perovskite films for efficient and stable perovskite modules journal January 2019
Nucleation and crystal growth control for scalable solution-processed organic–inorganic hybrid perovskite solar cells journal January 2020
Understanding the impact of C 60 at the interface of perovskite solar cells via drift-diffusion modeling journal March 2019
Meniscus fabrication of halide perovskite thin films at high throughput for large area and low-cost solar panels journal June 2019
Surface Treatment on Nickel Oxide to Enhance the Efficiency of Inverted Perovskite Solar Cells journal November 2019
Recent Advances in Rational Electrode Designs for High-Performance Alkaline Rechargeable Batteries journal January 2019
Improving Charge Transport via Intermediate‐Controlled Crystal Growth in 2D Perovskite Solar Cells journal April 2019
Photoresponsive Transistors Based on Lead‐Free Perovskite and Carbon Nanotubes journal October 2019
Insight into the Interfacial Elastic Contact in Stacking Perovskite Solar Cells journal February 2019
Alkali Chlorides for the Suppression of the Interfacial Recombination in Inverted Planar Perovskite Solar Cells journal March 2019
Additive Engineering for Efficient and Stable Perovskite Solar Cells journal October 2019
Lead‐Free Semiconductors: Soft Chemistry, Dimensionality Control, and Manganese‐Doping of Germanium Halide Perovskites journal January 2019
Chalcogenide Materials and Derivatives for Photovoltaic Applications journal September 2019
Engineering Halide Perovskite Crystals through Precursor Chemistry journal October 2019
Ethanol–water-assisted room temperature synthesis of CsPbBr3/SiO2 nanocomposites with high stability in ethanol journal November 2018
Strain engineering in perovskite solar cells and its impacts on carrier dynamics journal February 2019
Phosphomolybdic acid as an efficient hole injection material in perovskite optoelectronic devices journal January 2019
Stable perovskite solar cells using tin acetylacetonate based electron transporting layers journal January 2019
Novel approaches and scalability prospects of copper based hole transporting materials for planar perovskite solar cells journal January 2019
Reconfigurable electronic devices enabled by laser-sintered liquid metal nanoparticles journal February 2019
Advances in modelling and simulation of halide perovskites for solar cell applications journal January 2019
Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells text January 2019
Environmental Profile of the Manufacturing Process of Perovskite Photovoltaics: Harmonization of Life Cycle Assessment Studies journal September 2019
Synergistic Coassembly of Highly Wettable and Uniform Hole‐Extraction Monolayers for Scaling‐up Perovskite Solar Cells journal December 2019
Rapid Aqueous Spray Fabrication of Robust NiO x : A Simple and Scalable Platform for Efficient Perovskite Solar Cells journal March 2019
A Purified, Solvent‐Intercalated Precursor Complex for Wide‐Process‐Window Fabrication of Efficient Perovskite Solar Cells and Modules journal May 2019
Strategic advantages of reactive polyiodide melts for scalable perovskite photovoltaics journal November 2018
Probing the origins of photodegradation in organic–inorganic metal halide perovskites with time-resolved mass spectrometry journal January 2018
Designing a new family of oxonium-cation based structurally diverse organic–inorganic hybrid iodoantimonate crystals journal January 2019
A mixed solvent for rapid fabrication of large-area methylammonium lead iodide layers by one-step coating at room temperature journal January 2019
Ambient blade coating of mixed cation, mixed halide perovskites without dripping: in situ investigation and highly efficient solar cells journal January 2020
Tailoring solvent coordination for high-speed, room-temperature blading of perovskite photovoltaic films journal December 2019
Solution‐Processable Perovskite Solar Cells toward Commercialization: Progress and Challenges journal April 2019
Functional Oxides for Photoneuromorphic Engineering: Toward a Solar Brain journal June 2019
Gas-solid reaction based over one-micrometer thick stable perovskite films for efficient solar cells and modules journal September 2018
Doping strategies for small molecule organic hole-transport materials: impacts on perovskite solar cell performance and stability journal January 2019
Bridging the Green Gap: Metal–Organic Framework Heteromultilayers Assembled from Porphyrinic Linkers Identified by Using Computational Screening journal April 2019
Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells journal March 2019
Layered Germanium Hybrid Perovskite Bromides: Insights from Experiments and First‐Principles Calculations journal April 2019
Single Crystal Perovskite Solar Cells: Development and Perspectives journal November 2019
Interphases, Interfaces, and Surfaces of Active Materials in Rechargeable Batteries and Perovskite Solar Cells journal January 2020
A Generalized Crystallization Protocol for Scalable Deposition of High‐Quality Perovskite Thin Films for Photovoltaic Applications journal June 2019
Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies journal November 2019
Preparation and Characterization of Mixed Halide MAPbI 3− x Cl x Perovskite Thin Films by Three‐Source Vacuum Deposition journal September 2019
Spiro‐Linked Molecular Hole‐Transport Materials for Highly Efficient Inverted Perovskite Solar Cells journal November 2019
Sacrificial additive-assisted film growth endows self-powered CsPbBr 3 photodetectors with ultra-low dark current and high sensitivity journal January 2020
Recent progress towards roll-to-roll manufacturing of perovskite solar cells using slot-die processing journal January 2020
Enhanced Open-Circuit Voltage in Perovskite Solar Cells with Open-Cage [60]Fullerene Derivatives as Electron-Transporting Materials journal April 2019

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