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Title: A Carbon-Cotton Cathode with Ultrahigh-Loading Capability for Statically and Dynamically Stable Lithium–Sulfur Batteries

Journal Article · · ACS Nano
 [1];  [1];  [1]
  1. Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program, and Texas Materials Inst.

Sulfur exhibits a high theoretical capacity of 1675 mA h g–1 via a distinct conversion reaction, which is different from the insertion reactions in commercial lithium-ion batteries. In consideration of its conversion-reaction battery chemistry, a custom design for electrode materials could establish the way for attaining high-loading capability while simultaneously maintaining high electrochemical utilization and stability.

Research Organization:
Univ. of Texas, Austin, TX (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
EE0007218
OSTI ID:
1430182
Alternate ID(s):
OSTI ID: 1429342; OSTI ID: 1487237
Journal Information:
ACS Nano, Vol. 10, Issue 11; ISSN 1936-0851
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 214 works
Citation information provided by
Web of Science

References (48)

Li-ion battery materials: present and future journal June 2015
Progress Towards Commercially Viable Li-S Battery Cells journal April 2015
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects journal November 2013
Lithium-Sulfur Batteries: Progress and Prospects journal February 2015
Polysulfide Shuttle Study in the Li/S Battery System journal January 2004
Capacity Fading Mechanisms on Cycling a High-Capacity Secondary Sulfur Cathode journal January 2004
Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification journal April 2012
Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells journal April 2015
Cell energy density and electrolyte/sulfur ratio in Li–S cells journal October 2014
Understanding the Lithium Sulfur Battery System at Relevant Scales journal August 2015
Reversibility of electrochemical reactions of sulfur supported on inverse opal carbon in glyme–Li salt molten complex electrolytes journal January 2011
The Lithium/Sulfur Rechargeable Cell journal January 2002
New insights into the limiting parameters of the Li/S rechargeable cell journal February 2012
Robust, Ultra-Tough Flexible Cathodes for High-Energy Li-S Batteries journal December 2015
Surface-enhanced redox chemistry of polysulphides on a metallic and polar host for lithium-sulphur batteries journal August 2014
Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries journal February 2015
3D Interconnected Electrode Materials with Ultrahigh Areal Sulfur Loading for Li-S Batteries journal March 2016
Enhanced Electrochemical Kinetics on Conductive Polar Mediators for Lithium-Sulfur Batteries journal October 2016
Ionic shield for polysulfides towards highly-stable lithium–sulfur batteries journal January 2014
A Polyethylene Glycol-Supported Microporous Carbon Coating as a Polysulfide Trap for Utilizing Pure Sulfur Cathodes in Lithium-Sulfur Batteries journal September 2014
Multi-functional separator/interlayer system for high-stable lithium-sulfur batteries: Progress and prospects journal November 2015
Permselective Graphene Oxide Membrane for Highly Stable and Anti-Self-Discharge Lithium–Sulfur Batteries journal February 2015
Electrochemically Stable Rechargeable Lithium-Sulfur Batteries with a Microporous Carbon Nanofiber Filter for Polysulfide journal July 2015
A Polysulfide-Trapping Interface for Electrochemically Stable Sulfur Cathode Development journal February 2016
Functional Mesoporous Carbon-Coated Separator for Long-Life, High-Energy Lithium-Sulfur Batteries journal July 2015
A hierarchical carbonized paper with controllable thickness as a modulable interlayer system for high performance Li–S batteries journal January 2014
Porous Carbon Mat as an Electrochemical Testing Platform for Investigating the Polysulfide Retention of Various Cathode Configurations in Li–S Cells journal May 2015
Mesoporous Carbon Interlayers with Tailored Pore Volume as Polysulfide Reservoir for High-Energy Lithium–Sulfur Batteries journal February 2015
A Lightweight TiO 2 /Graphene Interlayer, Applied as a Highly Effective Polysulfide Absorbent for Fast, Long-Life Lithium-Sulfur Batteries journal March 2015
Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries journal November 2011
Novel positive electrode architecture for rechargeable lithium/sulfur batteries journal August 2012
Carbonized Eggshell Membrane as a Natural Polysulfide Reservoir for Highly Reversible Li-S Batteries journal November 2013
Three-dimensional aluminum foam/carbon nanotube scaffolds as long- and short-range electron pathways with improved sulfur loading for high energy density lithium–sulfur batteries journal September 2014
Recent Advances in Electrolytes for Lithium-Sulfur Batteries journal April 2015
Toward More Reliable Lithium–Sulfur Batteries: An All-Graphene Cathode Structure journal August 2016
Hierarchical sulfur electrodes as a testing platform for understanding the high-loading capability of Li-S batteries journal December 2016
A lithium–sulfur cathode with high sulfur loading and high capacity per area: a binder-free carbon fiber cloth–sulfur material journal January 2014
High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes journal March 2015
3D Carbonaceous Current Collectors: The Origin of Enhanced Cycling Stability for High-Sulfur-Loading Lithium-Sulfur Batteries journal June 2016
Self-discharge of lithium–sulfur cells using stainless-steel current-collectors journal February 2005
Self-discharge characteristics of lithium/sulfur batteries using TEGDME liquid electrolyte journal December 2006
Bifunctional Separator with a Light-Weight Carbon-Coating for Dynamically and Statically Stable Lithium-Sulfur Batteries journal June 2014
Structural Design of Cathodes for Li-S Batteries journal April 2015
3D Graphene-Foam-Reduced-Graphene-Oxide Hybrid Nested Hierarchical Networks for High-Performance Li-S Batteries journal December 2015
Highly Reversible Lithium/Dissolved Polysulfide Batteries with Carbon Nanotube Electrodes journal May 2013
Aligned carbon nanotube/sulfur composite cathodes with high sulfur content for lithium–sulfur batteries journal March 2014
Investigation of the Self-Discharge Behavior of Lithium-Sulfur Batteries journal January 2016
A study of the electrochemical processes in lithium–sulphur cells by impedance spectroscopy journal February 2011

Cited By (49)

Designing Safe Electrolyte Systems for a High-Stability Lithium-Sulfur Battery journal January 2018
3D Ferroconcrete-Like Aminated Carbon Nanotubes Network Anchoring Sulfur for Advanced Lithium-Sulfur Battery journal July 2018
Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application journal June 2018
A simple and general approach for in situ synthesis of sulfur–porous carbon composites for lithium–sulfur batteries journal January 2019
Fructose-Derived Hollow Carbon Nanospheres with Ultrathin and Ordered Mesoporous Shells as Cathodes in Lithium-Sulfur Batteries for Fast Energy Storage journal July 2017
A Nacre-Like Carbon Nanotube Sheet for High Performance Li-Polysulfide Batteries with High Sulfur Loading journal April 2018
Advanced Li 2 S/Si Full Battery Enabled by TiN Polysulfide Immobilizer journal October 2019
Dual confinement of sulphur with rGO-wrapped microporous carbon from β-cyclodextrin nanosponges as a cathode material for Li–S batteries journal June 2017
Nanostructured Host Materials for Trapping Sulfur in Rechargeable Li-S Batteries: Structure Design and Interfacial Chemistry journal November 2017
A carbon foam-supported high sulfur loading composite as a self-supported cathode for flexible lithium–sulfur batteries journal January 2018
Fast electrochemical kinetics and strong polysulfide adsorption by a highly oriented MoS 2 nanosheet@N-doped carbon interlayer for lithium–sulfur batteries journal January 2019
Review on High-Loading and High-Energy Lithium-Sulfur Batteries journal May 2017
Carbon Quantum Dots-Modified Interfacial Interactions and Ion Conductivity for Enhanced High Current Density Performance in Lithium-Sulfur Batteries journal December 2018
Pyrrolic‐Type Nitrogen‐Doped Hierarchical Macro/Mesoporous Carbon as a Bifunctional Host for High‐Performance Thick Cathodes for Lithium‐Sulfur Batteries journal March 2019
Popcorn Inspired Porous Macrocellular Carbon: Rapid Puffing Fabrication from Rice and Its Applications in Lithium-Sulfur Batteries journal September 2017
Revisiting the Role of Polysulfides in Lithium-Sulfur Batteries journal March 2018
Review—Li Metal Anode in Working Lithium-Sulfur Batteries journal June 2017
Sulfur-Immobilized Nitrogen and Oxygen Co-Doped Hierarchically Porous Biomass Carbon for Lithium-Sulfur Batteries: Influence of Sulfur Content and Distribution on Its Performance journal November 2017
Review of Carbon Materials for Lithium-Sulfur Batteries journal February 2018
Multi-functional nanowall arrays with unrestricted Li + transport channels and an integrated conductive network for high-areal-capacity Li–S batteries journal January 2018
Recent Advances in Hollow Porous Carbon Materials for Lithium–Sulfur Batteries journal February 2019
Nitrogen-doped carbon nanotube sponge with embedded Fe/Fe 3 C nanoparticles as binder-free cathodes for high capacity lithium–sulfur batteries journal January 2018
Lightweight and Flexible Cotton Aerogel Composites for Electromagnetic Absorption and Shielding Applications journal November 2019
An in situ element permeation constructed high endurance Li–LLZO interface at high current densities journal January 2018
Rational Design of Statically and Dynamically Stable Lithium-Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio journal December 2017
Current Status and Future Prospects of Metal–Sulfur Batteries journal May 2019
Large-Area Preparation of Crack-Free Crystalline Microporous Conductive Membrane to Upgrade High Energy Lithium-Sulfur Batteries journal September 2018
A 3D Nitrogen-Doped Graphene/TiN Nanowires Composite as a Strong Polysulfide Anchor for Lithium-Sulfur Batteries with Enhanced Rate Performance and High Areal Capacity journal September 2018
Recent Progress in Liquid Electrolyte-Based Li–S Batteries: Shuttle Problem and Solutions journal November 2018
Progress on the Critical Parameters for Lithium-Sulfur Batteries to be Practically Viable journal May 2018
A Facile, Low-Cost Hot-Pressing Process for Fabricating Lithium-Sulfur Cells with Stable Dynamic and Static Electrochemistry journal October 2018
Rational Design of a Dual-Function Hybrid Cathode Substrate for Lithium-Sulfur Batteries journal June 2018
Enhanced Cycling Performance for Lithium–Sulfur Batteries by a Laminated 2D g‐C 3 N 4 /Graphene Cathode Interlayer journal November 2018
SiO 2 @MoS 2 core–shell nanocomposite layers with high lithium ion diffusion as a triple polysulfide shield for high performance lithium–sulfur batteries journal January 2019
Nonlithium Metal-Sulfur Batteries: Steps Toward a Leap journal November 2018
Cyclic Voltammetry in Lithium–Sulfur Batteries—Challenges and Opportunities journal April 2019
Pyridinic and pyrrolic nitrogen-enriched carbon as a polysulfide blocker for high-performance lithium–sulfur batteries journal January 2019
A Flexible 3D Multifunctional MgO-Decorated Carbon Foam@CNTs Hybrid as Self-Supported Cathode for High-Performance Lithium-Sulfur Batteries journal August 2017
Recent research trends in Li–S batteries journal January 2018
A review of biomass materials for advanced lithium–sulfur batteries journal January 2019
Polyethylenimine Expanded Graphite Oxide Enables High Sulfur Loading and Long‐Term Stability of Lithium–Sulfur Batteries journal January 2019
A High-Volumetric-Capacity Cathode Based on Interconnected Close-Packed N-Doped Porous Carbon Nanospheres for Long-Life Lithium-Sulfur Batteries journal August 2017
A lightweight and binder-free electrode enabled by lignin fibers@carbon-nanotubes and graphene for ultrastable lithium–sulfur batteries journal January 2018
A high-efficiency N/P co-doped graphene/CNT@porous carbon hybrid matrix as a cathode host for high performance lithium–sulfur batteries journal January 2017
A review of flexible lithium–sulfur and analogous alkali metal–chalcogen rechargeable batteries journal January 2017
3D Ferroconcrete-Like Aminated Carbon Nanotubes Network Anchoring Sulfur for Advanced Lithium–Sulfur Battery text January 2018
MOF-derived Cobalt Sulfide Grown on 3D Graphene Foam as an Efficient Sulfur Host for Long-Life Lithium-Sulfur Batteries journal June 2018
An Outlook on Lithium Ion Battery Technology journal September 2017
A Polysulfide-Infiltrated Carbon Cloth Cathode for High-Performance Flexible Lithium–Sulfur Batteries journal February 2018

Figures / Tables (5)