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Title: Reversible Redox-Induced Modulation of Sterics in an α-Diimine Ligand Coordinated to Gallium

Abstract

The ability to tune the steric envelope through redox events post-synthetically or in tandem with other chemical processes is a powerful tool that could assist in enabling new catalytic methodologies and understanding potential pitfalls in ligand design. The α-diimine ligand, dmp-BIAN, exhibits the peculiar and previously unreported feature of varying steric profiles depending on oxidation state when paired with a main group element. A study of the factors that give rise to this behaviour as well as its impact on the incorporation of other ligands is performed.

Authors:
 [1];  [1];  [2];  [3]
  1. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  2. San Francisco State Univ., CA (United States)
  3. Davidson College, Davidson, NC (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1429813
Report Number(s):
SAND-2017-7860J
655658
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Program Document
Country of Publication:
United States
Language:
English

Citation Formats

Zarkesh, Ryan A., Foster, Michael E., Ichimura, Andrew S., and Anstey, Mitchell R. Reversible Redox-Induced Modulation of Sterics in an α-Diimine Ligand Coordinated to Gallium. United States: N. p., 2017. Web.
Zarkesh, Ryan A., Foster, Michael E., Ichimura, Andrew S., & Anstey, Mitchell R. Reversible Redox-Induced Modulation of Sterics in an α-Diimine Ligand Coordinated to Gallium. United States.
Zarkesh, Ryan A., Foster, Michael E., Ichimura, Andrew S., and Anstey, Mitchell R. Sat . "Reversible Redox-Induced Modulation of Sterics in an α-Diimine Ligand Coordinated to Gallium". United States. doi:.
@article{osti_1429813,
title = {Reversible Redox-Induced Modulation of Sterics in an α-Diimine Ligand Coordinated to Gallium},
author = {Zarkesh, Ryan A. and Foster, Michael E. and Ichimura, Andrew S. and Anstey, Mitchell R.},
abstractNote = {The ability to tune the steric envelope through redox events post-synthetically or in tandem with other chemical processes is a powerful tool that could assist in enabling new catalytic methodologies and understanding potential pitfalls in ligand design. The α-diimine ligand, dmp-BIAN, exhibits the peculiar and previously unreported feature of varying steric profiles depending on oxidation state when paired with a main group element. A study of the factors that give rise to this behaviour as well as its impact on the incorporation of other ligands is performed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jul 01 00:00:00 EDT 2017},
month = {Sat Jul 01 00:00:00 EDT 2017}
}

Program Document:
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