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Title: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications

Abstract

A mixed metal strategy, in which two different metal nodes coexist in one MOF framework, was examined using MOF-74. The Ni salt precursor for the MOF-74(Ni) analogue was partially replaced during synthesis with relatively inexpensive Zn salt. These bimetallic MOFs were developed and examined for water sorption for potential use in adsorption cooling/chiller applications. Varying concentration ratios of Ni:Zn in MOF-74 achieved using this mixed metal strategy were shown to provide unique impacts on H2O uptake while significantly mitigating the costs of synthesis

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2];  [3]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Pacific Northwest National Laboratory, 99352 Richland WA USA
  2. Pacific Northwest National Laboratory, 99352 Richland WA USA; P.G. Department of Chemistry, Jaysingpur College, 416101 Jaysingpur Maharashtra India
  3. Environmental Molecular Sciences Laboratory (EMSL), Pacific Northwest National Laboratory, 99352 Richland WA USA
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Geothermal Technologies Office (EE-4G)
OSTI Identifier:
1427910
Report Number(s):
PNNL-SA-129916
Journal ID: ISSN 1434-1948; 830403000
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
European Journal of Inorganic Chemistry
Additional Journal Information:
Journal Volume: 2018; Journal Issue: 7; Journal ID: ISSN 1434-1948
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

Citation Formats

Liu, Jian, Zheng, Jian, Barpaga, Dushyant, Sabale, Sandip, Arey, Bruce, Derewinski, Miroslaw A., McGrail, B. Peter, and Motkuri, Radha Kishan. A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications. United States: N. p., 2018. Web. doi:10.1002/ejic.201800042.
Liu, Jian, Zheng, Jian, Barpaga, Dushyant, Sabale, Sandip, Arey, Bruce, Derewinski, Miroslaw A., McGrail, B. Peter, & Motkuri, Radha Kishan. A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications. United States. doi:10.1002/ejic.201800042.
Liu, Jian, Zheng, Jian, Barpaga, Dushyant, Sabale, Sandip, Arey, Bruce, Derewinski, Miroslaw A., McGrail, B. Peter, and Motkuri, Radha Kishan. Mon . "A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications". United States. doi:10.1002/ejic.201800042.
@article{osti_1427910,
title = {A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications},
author = {Liu, Jian and Zheng, Jian and Barpaga, Dushyant and Sabale, Sandip and Arey, Bruce and Derewinski, Miroslaw A. and McGrail, B. Peter and Motkuri, Radha Kishan},
abstractNote = {A mixed metal strategy, in which two different metal nodes coexist in one MOF framework, was examined using MOF-74. The Ni salt precursor for the MOF-74(Ni) analogue was partially replaced during synthesis with relatively inexpensive Zn salt. These bimetallic MOFs were developed and examined for water sorption for potential use in adsorption cooling/chiller applications. Varying concentration ratios of Ni:Zn in MOF-74 achieved using this mixed metal strategy were shown to provide unique impacts on H2O uptake while significantly mitigating the costs of synthesis},
doi = {10.1002/ejic.201800042},
journal = {European Journal of Inorganic Chemistry},
issn = {1434-1948},
number = 7,
volume = 2018,
place = {United States},
year = {2018},
month = {2}
}

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