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Title: Element mobilization and immobilization from carbonate rocks between CO 2 storage reservoirs and the overlying aquifers during a potential CO 2 leakage

Abstract

Despite the numerous studies on changes within the reservoir following CO2 injection and the effects of CO2 release into overlying aquifers, little or no literature is available on the effect of CO2 release on rock between the storage reservoirs and subsurface. To address this knowledge gap, relevant rock materials, temperatures and pressures were used to study mineralogical and elemental changes in this intermediate zone. After rocks reacted with CO2, liquid analysis showed an increase of major elements (e.g., Ca, and Mg) and variable concentrations of potential contaminants (e.g., Sr and Ba); lower concentrations were observed in N2 controls. In experiments with As/Cd and/or organic spikes, representing potential contaminants in the CO2 plume originating in the storage reservoir, most or all of these contaminants were removed from the aqueous phase. SEM and Mössbauer spectroscopy results showed the formation of new minerals and Fe oxides in some CO2-reacted samples, indicating potential for contaminant removal through mineral incorporation or adsorption onto Fe oxides. These experiments show the interactions between the CO2-laden plume and the rock between storage reservoirs and overlying aquifers have the potential to affect the level of risk to overlying groundwater, and should be considered during site selection and risk evaluation.

Authors:
ORCiD logo; ; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Sponsoring Org.:
USDOE
OSTI Identifier:
1427909
Report Number(s):
PNNL-SA-125304
Journal ID: ISSN 0045-6535; 49942; AA7050000
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Chemosphere
Additional Journal Information:
Journal Volume: 197; Journal Issue: C; Journal ID: ISSN 0045-6535
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
Environmental Molecular Sciences Laboratory

Citation Formats

Lawter, Amanda R., Qafoku, Nikolla P., Asmussen, R. Matthew, Kukkadapu, Ravi K., Qafoku, Odeta, Bacon, Diana H., and Brown, Christopher F. Element mobilization and immobilization from carbonate rocks between CO 2 storage reservoirs and the overlying aquifers during a potential CO 2 leakage. United States: N. p., 2018. Web. doi:10.1016/j.chemosphere.2017.12.199.
Lawter, Amanda R., Qafoku, Nikolla P., Asmussen, R. Matthew, Kukkadapu, Ravi K., Qafoku, Odeta, Bacon, Diana H., & Brown, Christopher F. Element mobilization and immobilization from carbonate rocks between CO 2 storage reservoirs and the overlying aquifers during a potential CO 2 leakage. United States. https://doi.org/10.1016/j.chemosphere.2017.12.199
Lawter, Amanda R., Qafoku, Nikolla P., Asmussen, R. Matthew, Kukkadapu, Ravi K., Qafoku, Odeta, Bacon, Diana H., and Brown, Christopher F. Sun . "Element mobilization and immobilization from carbonate rocks between CO 2 storage reservoirs and the overlying aquifers during a potential CO 2 leakage". United States. https://doi.org/10.1016/j.chemosphere.2017.12.199.
@article{osti_1427909,
title = {Element mobilization and immobilization from carbonate rocks between CO 2 storage reservoirs and the overlying aquifers during a potential CO 2 leakage},
author = {Lawter, Amanda R. and Qafoku, Nikolla P. and Asmussen, R. Matthew and Kukkadapu, Ravi K. and Qafoku, Odeta and Bacon, Diana H. and Brown, Christopher F.},
abstractNote = {Despite the numerous studies on changes within the reservoir following CO2 injection and the effects of CO2 release into overlying aquifers, little or no literature is available on the effect of CO2 release on rock between the storage reservoirs and subsurface. To address this knowledge gap, relevant rock materials, temperatures and pressures were used to study mineralogical and elemental changes in this intermediate zone. After rocks reacted with CO2, liquid analysis showed an increase of major elements (e.g., Ca, and Mg) and variable concentrations of potential contaminants (e.g., Sr and Ba); lower concentrations were observed in N2 controls. In experiments with As/Cd and/or organic spikes, representing potential contaminants in the CO2 plume originating in the storage reservoir, most or all of these contaminants were removed from the aqueous phase. SEM and Mössbauer spectroscopy results showed the formation of new minerals and Fe oxides in some CO2-reacted samples, indicating potential for contaminant removal through mineral incorporation or adsorption onto Fe oxides. These experiments show the interactions between the CO2-laden plume and the rock between storage reservoirs and overlying aquifers have the potential to affect the level of risk to overlying groundwater, and should be considered during site selection and risk evaluation.},
doi = {10.1016/j.chemosphere.2017.12.199},
url = {https://www.osti.gov/biblio/1427909}, journal = {Chemosphere},
issn = {0045-6535},
number = C,
volume = 197,
place = {United States},
year = {2018},
month = {4}
}

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    Works referencing / citing this record:

    Numerical analysis of CO 2 hydrate growth in a depleted natural gas hydrate formation with free water
    journal, September 2019


    Natural, incidental, and engineered nanomaterials and their impacts on the Earth system
    journal, March 2019