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Chemistry through cocrystals: pressure-induced polymerization of C2H2·C6H6 to an extended crystalline hydrocarbon

Journal Article · · Physical Chemistry Chemical Physics. PCCP (Print)
DOI:https://doi.org/10.1039/C7CP07852H· OSTI ID:1427858
 [1];  [2];  [1];  [3];  [4];  [5];  [1]
  1. Geophysical Laboratory; Carnegie Institution of Washington; Washington; USA
  2. Department of Materials Science and Engineering; Pennsylvania State University; University Park; USA
  3. Department of Chemistry; Pennsylvania State University; University Park; USA
  4. High Pressure Collaborative Access Team (HPCAT); Geophysical Laboratory; Carnegie Institution of Washington; Argonne; USA
  5. Department of Materials Science and Engineering; Pennsylvania State University; University Park; USA; Department of Chemistry
+ Show Author Affiliations

The 1 : 1 acetylene–benzene cocrystal, C2H2·C6H6, was synthesized under pressure in a diamond anvil cell (DAC) and its evolution under pressure was studied with single-crystal X-ray diffraction and Raman spectroscopy.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCESNSFDOE-NNSADARPA
OSTI ID:
1427858
Journal Information:
Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 10; ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

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