In Situ Investigations of Li-MoS2 with Planar Batteries

Wan, Jiayu; Bao, Wenzhong; Liu, Yang; Dai, Jiaqi; Shen, Fei; Zhou, Lihui; Cai, Xinghan; Urban, Daniel; Li, Yuanyuan; Jungjohann, Katherine; Fuhrer, Michael S.; Hu, Liangbing

doi:10.1002/aenm.201401742

Title: In Situ Investigations of Li-MoS₂ with Planar Batteries

Journal Article · Tue Nov 25 00:00:00 EST 2014 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201401742· OSTI ID:1426880

Wan, Jiayu ^[1]; Bao, Wenzhong ^[2]; Liu, Yang ^[3]; Dai, Jiaqi ^[1]; Shen, Fei ^[1]; Zhou, Lihui ^[1]; Cai, Xinghan ^[4]; Urban, Daniel ^[1]; Li, Yuanyuan ^[1]; Jungjohann, Katherine ^[3]; Fuhrer, Michael S. ^[5]; Hu, Liangbing ^[1]

Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering
Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering and Dept. of Physics
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies (CINT)
Univ. of Maryland, College Park, MD (United States). Dept. of Physics
Univ. of Maryland, College Park, MD (United States). Dept. of Physics; Monash Univ., Melbourne, VIC (Australia). School of Physics

For this study, a planar microbattery that enables various in situ measurements of lithiation of 2D materials on the individual-flake scale is developed. A large conductivity increase of thick MoS₂ crystallite lithiation due to the formation of a percolative Mo nanoparticle network embedded in a Li₂S matrix is observed. The nanoscale study leads to the development of a novel charging strategy for batteries that largely improves the capacity and cycling performance confirmed in bulk MoS₂/Li coin cells.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Univ. of Maryland, College Park, MD (United States); US Department of the Navy, Office of Naval Research (ONR); Australian Research Council

DOE Contract Number:: AC04-94AL85000

OSTI ID:: 1426880

Report Number(s):: SAND-2014-17791J; 537578

Journal Information:: Advanced Energy Materials, Vol. 5, Issue 5; ISSN 1614-6832

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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Title: In Situ Investigations of Li-MoS2 with Planar Batteries

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Title: In Situ Investigations of Li-MoS₂ with Planar Batteries