Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance
Abstract
For miniaturized capacitive energy storage, volumetric and areal capacitances are more important metrics than gravimetric ones because of the constraints imposed by device volume and chip area. Typically used in commercial supercapacitors, porous carbons, although they provide a stable and reliable performance, lack volumetric performance because of their inherently low density and moderate capacitances. Here we report a high-performing electrode based on conductive hexaaminobenzene (HAB)-derived two-dimensional metal-organic frameworks (MOFs). In addition to possessing a high packing density and hierarchical porous structure, these MOFs also exhibit excellent chemical stability in both acidic and basic aqueous solutions, which is in sharp contrast to conventional MOFs. Submillimetre-thick pellets of HAB MOFs showed high volumetric capacitances up to 760 F cm(-3) and high areal capacitances over 20 F cm(-2). Furthermore, the HAB MOF electrodes exhibited highly reversible redox behaviours and good cycling stability with a capacitance retention of 90% after 12,000 cycles. These promising results demonstrate the potential of using redox-active conductive MOFs in energy-storage applications.
- Authors:
-
- Stanford Univ., CA (United States). Department of Chemical Engineering
- Stockholm Univ. (Sweden). Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division, Advanced Photon Source
- Stanford Univ., CA (United States). Department of Chemical Engineering, SUNCAT Center for Interface Science and Catalysis
- Stanford Univ., CA (United States). Department of Materials Science and Engineering
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES); Knut and Alice Wallenberg Foundation; Swedish Research Council (SRC)
- OSTI Identifier:
- 1426494
- Alternate Identifier(s):
- OSTI ID: 1461332
- Grant/Contract Number:
- AC02-76SF00515; AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Nature Energy
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 1; Journal ID: ISSN 2058-7546
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Batteries; Metal-organic frameworks
Citation Formats
Feng, Dawei, Lei, Ting, Lukatskaya, Maria R., Park, Jihye, Huang, Zhehao, Lee, Minah, Shaw, Leo, Chen, Shucheng, Yakovenko, Andrey A., Kulkarni, Ambarish, Xiao, Jianping, Fredrickson, Kurt, Tok, Jeffrey B., Zou, Xiaodong, Cui, Yi, and Bao, Zhenan. Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance. United States: N. p., 2018.
Web. doi:10.1038/s41560-017-0044-5.
Feng, Dawei, Lei, Ting, Lukatskaya, Maria R., Park, Jihye, Huang, Zhehao, Lee, Minah, Shaw, Leo, Chen, Shucheng, Yakovenko, Andrey A., Kulkarni, Ambarish, Xiao, Jianping, Fredrickson, Kurt, Tok, Jeffrey B., Zou, Xiaodong, Cui, Yi, & Bao, Zhenan. Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance. United States. https://doi.org/10.1038/s41560-017-0044-5
Feng, Dawei, Lei, Ting, Lukatskaya, Maria R., Park, Jihye, Huang, Zhehao, Lee, Minah, Shaw, Leo, Chen, Shucheng, Yakovenko, Andrey A., Kulkarni, Ambarish, Xiao, Jianping, Fredrickson, Kurt, Tok, Jeffrey B., Zou, Xiaodong, Cui, Yi, and Bao, Zhenan. 2018.
"Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance". United States. https://doi.org/10.1038/s41560-017-0044-5. https://www.osti.gov/servlets/purl/1426494.
@article{osti_1426494,
title = {Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance},
author = {Feng, Dawei and Lei, Ting and Lukatskaya, Maria R. and Park, Jihye and Huang, Zhehao and Lee, Minah and Shaw, Leo and Chen, Shucheng and Yakovenko, Andrey A. and Kulkarni, Ambarish and Xiao, Jianping and Fredrickson, Kurt and Tok, Jeffrey B. and Zou, Xiaodong and Cui, Yi and Bao, Zhenan},
abstractNote = {For miniaturized capacitive energy storage, volumetric and areal capacitances are more important metrics than gravimetric ones because of the constraints imposed by device volume and chip area. Typically used in commercial supercapacitors, porous carbons, although they provide a stable and reliable performance, lack volumetric performance because of their inherently low density and moderate capacitances. Here we report a high-performing electrode based on conductive hexaaminobenzene (HAB)-derived two-dimensional metal-organic frameworks (MOFs). In addition to possessing a high packing density and hierarchical porous structure, these MOFs also exhibit excellent chemical stability in both acidic and basic aqueous solutions, which is in sharp contrast to conventional MOFs. Submillimetre-thick pellets of HAB MOFs showed high volumetric capacitances up to 760 F cm(-3) and high areal capacitances over 20 F cm(-2). Furthermore, the HAB MOF electrodes exhibited highly reversible redox behaviours and good cycling stability with a capacitance retention of 90% after 12,000 cycles. These promising results demonstrate the potential of using redox-active conductive MOFs in energy-storage applications.},
doi = {10.1038/s41560-017-0044-5},
url = {https://www.osti.gov/biblio/1426494},
journal = {Nature Energy},
issn = {2058-7546},
number = 1,
volume = 3,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
Web of Science
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Metal−Organic Frameworks for High‐Energy Lithium Batteries with Enhanced Safety: Recent Progress and Future Perspectives
journal, April 2019
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- Batteries & Supercaps, Vol. 2, Issue 7
How to efficiently utilize electrode materials in supercapattery?
journal, January 2019
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- Functional Materials Letters, Vol. 12, Issue 01
Conductive Metal–Organic Frameworks Selectively Grown on Laser‐Scribed Graphene for Electrochemical Microsupercapacitors
journal, April 2019
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- Advanced Energy Materials, Vol. 9, Issue 21
A One‐Dimensional π–d Conjugated Coordination Polymer for Sodium Storage with Catalytic Activity in Negishi Coupling
journal, September 2019
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- Angewandte Chemie International Edition, Vol. 58, Issue 41
Fully Conjugated Phthalocyanine Copper Metal–Organic Frameworks for Sodium–Iodine Batteries with Long‐Time‐Cycling Durability
journal, December 2019
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- Advanced Materials, Vol. 32, Issue 4
Synthesis and solar cell application of a Ti (metal)-organic framework/carbon nanotube composite
journal, November 2019
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- Materials Research Express, Vol. 6, Issue 12
Solid–solid interface growth of conductive metal–organic framework nanowire arrays and their supercapacitor application
journal, January 2020
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- Materials Chemistry Frontiers, Vol. 4, Issue 1
Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry
journal, January 2019
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- Chemical Science, Vol. 10, Issue 5
Ultrathin two-dimensional π–d conjugated coordination polymer Co 3 (hexaaminobenzene) 2 nanosheets for highly efficient oxygen evolution
journal, January 2020
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- Journal of Materials Chemistry A, Vol. 8, Issue 1
A Dual‐Ligand Porous Coordination Polymer Chemiresistor with Modulated Conductivity and Porosity
journal, January 2020
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- Angewandte Chemie International Edition, Vol. 59, Issue 1
Secondary‐Component Incorporated Hollow MOFs and Derivatives for Catalytic and Energy‐Related Applications
journal, July 2018
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- Advanced Materials, Vol. 31, Issue 38
Robust heterostructures of a bimetallic sodium–zinc metal–organic framework and reduced graphene oxide for high-performance supercapacitors
journal, January 2019
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- Journal of Materials Chemistry A, Vol. 7, Issue 4
A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, July 2019
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- Angewandte Chemie, Vol. 131, Issue 31
Nano-sandwiched metal hexacyanoferrate/graphene hybrid thin films for in-plane asymmetric micro-supercapacitors with ultrahigh energy density
journal, January 2019
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- Materials Horizons, Vol. 6, Issue 5
Synergistic effects of engineered spinel hetero-metallic cobaltites on electrochemical pseudo-capacitive behaviors
journal, January 2018
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- Journal of Materials Chemistry A, Vol. 6, Issue 31
Origin of the Chemiresistive Response of Ultrathin Films of Conductive Metal–Organic Frameworks
journal, November 2018
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Electroactive Metalorganic Frameworks
journal, October 2018
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- Israel Journal of Chemistry, Vol. 58, Issue 9-10
Catalytic Metal Nanoparticles Embedded in Conductive Metal–Organic Frameworks for Chemiresistors: Highly Active and Conductive Porous Materials
journal, August 2019
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- Advanced Science, Vol. 6, Issue 21
Core–shell assembly of carbon nanofibers and a 2D conductive metal–organic framework as a flexible free-standing membrane for high-performance supercapacitors
journal, January 2019
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Recent Development and Application of Conductive MOFs
journal, August 2018
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Theoretical Investigation of 2D Conductive Microporous Coordination Polymers as Li-S Battery Cathode with Ultrahigh Energy Density
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- Advanced Energy Materials, Vol. 8, Issue 25
Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal–organic framework with a porphyrinic skeleton
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Titelbild: A Redox‐Active 2D Metal–Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity (Angew. Chem. 13/2020)
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A Phthalocyanine-Based Layered Two-Dimensional Conjugated Metal-Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction
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Strain Redistribution in Metal‐Sulfide‐Composite Anode for Enhancing Volumetric Lithium Storage
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- ChemElectroChem, Vol. 5, Issue 24
Graphene-like metal-organic frameworks: Morphology control, optimization of thin film electrical conductivity and fast sensing applications
other, January 2018
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- Cambridge : Royal Society of Chemistry
Conductive Co-based metal–organic framework nanowires: a competitive high-rate anode towards advanced Li-ion capacitors
journal, January 2019
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- Journal of Materials Chemistry A, Vol. 7, Issue 43
Interweaving metal–organic framework-templated Co–Ni layered double hydroxide nanocages with nanocellulose and carbon nanotubes to make flexible and foldable electrodes for energy storage devices
journal, January 2018
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- Journal of Materials Chemistry A, Vol. 6, Issue 47
Hydrogen storage mechanism and diffusion in metal–organic frameworks
journal, January 2019
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- Physical Chemistry Chemical Physics, Vol. 21, Issue 15
Synaptic Plasticity and Filtering Emulated in Metal–Organic Frameworks Nanosheets Based Transistors
journal, November 2019
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Porous Ultrathin NiSe Nanosheet Networks on Nickel Foam for High‐Performance Hybrid Supercapacitors
journal, October 2019
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- ChemSusChem, Vol. 13, Issue 1
Engineering Bimetal Synergistic Electrocatalysts Based on Metal–Organic Frameworks for Efficient Oxygen Evolution
journal, September 2019
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Interfacial Approach toward Benzene‐Bridged Polypyrrole Film–Based Micro‐Supercapacitors with Ultrahigh Volumetric Power Density
journal, December 2019
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- Advanced Functional Materials, Vol. 30, Issue 7
Interlayer Hydrogen‐Bonded Metal Porphyrin Frameworks/MXene Hybrid Film with High Capacitance for Flexible All‐Solid‐State Supercapacitors
journal, March 2019
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- Small, Vol. 15, Issue 18
Assembling laminated films via the synchronous reduction of graphene oxide and formation of copper-based metal organic frameworks
journal, January 2019
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- Journal of Materials Chemistry A, Vol. 7, Issue 1
Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes
journal, February 2020
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- Nature Materials, Vol. 19, Issue 5
Shape‐Assisted 2D MOF/Graphene Derived Hybrids as Exceptional Lithium‐Ion Battery Electrodes
journal, July 2019
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- Advanced Functional Materials, Vol. 29, Issue 38
Superior Electrochemical Performance of Pristine Nickel Hexaaminobenzene MOF Supercapacitors Fabricated by Electrophoretic Deposition
journal, March 2020
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- ChemSusChem, Vol. 13, Issue 6
Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis
journal, January 2020
- Zhao, Kuangmin; Zhu, Weiwei; Liu, Suqin
- Nanoscale Advances, Vol. 2, Issue 2
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