Surface transformation by a “cocktail” solvent enables stable cathode materials for sodium ion batteries

Mu, Linqin; Rahman, Muhammad Mominur; Zhang, Yan; Feng, Xu; Du, Xi-Wen; Nordlund, Dennis; Lin, Feng

doi:10.1039/c7ta08410b

Title: Surface transformation by a “cocktail” solvent enables stable cathode materials for sodium ion batteries

Journal Article · Tue Jan 09 00:00:00 EST 2018 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c7ta08410b· OSTI ID:1425931

Mu, Linqin ^[1]; Rahman, Muhammad Mominur ^[1]; Zhang, Yan ^[2]; Feng, Xu ^[1];

^[2]; Nordlund, Dennis ^[3];

^[1]

Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Tianjin Univ., Tianjin (China). School of Materials Science and Engineering
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)

Coating the surfaces of active materials has become an effective and indispensable path towards the stable operation of practical rechargeable batteries. Improving the affordability of coating processes can bring enormous manufacturing advantages to battery applications. Here in this paper, we report a cheap, simple and efficient method to create conformal coating layers on the primary particles of sodium layered oxide materials for improving battery performance. Mimicking the cathode–electrolyte interfacial reaction in practical cells, we create conformal coating layers via the spontaneous reaction between the oxidative cathode surfaces and a cocktail of reductive organic solvents. The conformal coating layers consist of metal–organic compounds with reduced transition metal cations, i.e., artificial cathode–electrolyte interphases (CEIs). The cells containing these coated cathode materials deliver much improved cycle life while maintaining reasonably high reversible capacity and rate capability. Furthermore, the structural stability and water resistance are enhanced, which can practically help simplify the storage protocol of cathode powders prior to battery manufacturing. The surfaces of most oxide cathode materials (e.g., lithium cathodes and sodium cathodes) are highly oxidative, and thus we expect that the present method, with tailored experimental parameters, can be readily applied to most battery systems.

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Research Organization:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1425931

Journal Information:: Journal of Materials Chemistry. A, Vol. 6, Issue 6; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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References (66)

Electrochemical investigation of the P2–NaxCoO2 phase diagram Berthelot, R.; Carlier, D.; Delmas, C. Nature Materials, Vol. 10, Issue 1 https://doi.org/10.1038/nmat2920	journal	December 2010
In Situ Multitechnical Investigation into Capacity Fading of High-Voltage LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Shen, Chong-Heng; Wang, Qi; Chen, Hong-Jiang ACS Applied Materials & Interfaces, Vol. 8, Issue 51 https://doi.org/10.1021/acsami.6b12597	journal	December 2016
In Operando XRD and TXM Study on the Metastable Structure Change of NaNi _1/3 Fe _1/3 Mn _1/3 O ₂ under Electrochemical Sodium-Ion Intercalation Xie, Yingying; Wang, Hong; Xu, Guiliang Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601306	journal	September 2016
Transition metal oxides for sodium-ion batteries Su, Heng; Jaffer, Saddique; Yu, Haijun Energy Storage Materials, Vol. 5 https://doi.org/10.1016/j.ensm.2016.06.005	journal	October 2016
Highly Stable Na _2/3 (Mn _0.54 Ni _0.13 Co _0.13 )O ₂ Cathode Modified by Atomic Layer Deposition for Sodium-Ion Batteries Kaliyappan, Karthikeyan; Liu, Jian; Lushington, Andrew ChemSusChem, Vol. 8, Issue 15 https://doi.org/10.1002/cssc.201500155	journal	June 2015
Study on the Reversible Electrode Reaction of Na _{1– x} Ni _0.5 Mn _0.5 O ₂ for a Rechargeable Sodium-Ion Battery Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri Inorganic Chemistry, Vol. 51, Issue 11 https://doi.org/10.1021/ic300357d	journal	May 2012
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
Understanding the Stability for Li-Rich Layered Oxide Li ₂ RuO ₃ Cathode Li, Biao; Shao, Ruiwen; Yan, Huijun Advanced Functional Materials, Vol. 26, Issue 9 https://doi.org/10.1002/adfm.201504836	journal	February 2016
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage Guo, Shaohua; Liu, Pan; Sun, Yang Angewandte Chemie International Edition, Vol. 54, Issue 40 https://doi.org/10.1002/anie.201505215	journal	August 2015
The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries Saubanère, M.; McCalla, E.; Tarascon, J. -M. Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03048J	journal	January 2016
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems Palomares, Verónica; Serras, Paula; Villaluenga, Irune Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee02781j	journal	January 2012
High Voltage Mg-Doped Na _0.67 Ni _{0.3– x} Mg _x Mn _0.7 O ₂ ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability Singh, Gurpreet; Tapia-Ruiz, Nuria; Lopez del Amo, Juan Miguel Chemistry of Materials, Vol. 28, Issue 14 https://doi.org/10.1021/acs.chemmater.6b01935	journal	July 2016
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan Energy & Environmental Science, Vol. 6, Issue 8 https://doi.org/10.1039/c3ee40847g	journal	January 2013
Enhanced Performance of P2-Na _0.66 (Mn _0.54 Co _0.13 Ni _0.13 )O ₂ Cathode for Sodium-Ion Batteries by Ultrathin Metal Oxide Coatings via Atomic Layer Deposition Kaliyappan, Karthikeyan; Liu, Jian; Xiao, Biwei Advanced Functional Materials, Vol. 27, Issue 37 https://doi.org/10.1002/adfm.201701870	journal	August 2017
Synthesis and Stoichiometry of Different Layered Sodium Cobalt Oxides Lei, Yuechuan; Li, Xin; Liu, Lei Chemistry of Materials, Vol. 26, Issue 18 https://doi.org/10.1021/cm5021788	journal	September 2014
Influence of synthesis conditions on the surface passivation and electrochemical behavior of layered cathode materials Lin, Feng; Nordlund, Dennis; Pan, Taijun J. Mater. Chem. A, Vol. 2, Issue 46 https://doi.org/10.1039/C4TA04497E	journal	January 2014
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Intrinsic Origins of Crack Generation in Ni-rich LiNi0.8Co0.1Mn0.1O2 Layered Oxide Cathode Material Lim, Jin-Myoung; Hwang, Taesoon; Kim, Duho Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep39669	journal	January 2017
O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries Li, Xin; Wu, Di; Zhou, Yong-Ning Electrochemistry Communications, Vol. 49 https://doi.org/10.1016/j.elecom.2014.10.003	journal	December 2014
Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Han, Xiaogang; Liu, Yang; Jia, Zheng Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl4035626	journal	December 2013
P2-Na _x Mn _1/2 Fe _1/2 O ₂ Phase Used as Positive Electrode in Na Batteries: Structural Changes Induced by the Electrochemical (De)intercalation Process Mortemard de Boisse, Benoit; Carlier, Dany; Guignard, Marie Inorganic Chemistry, Vol. 53, Issue 20 https://doi.org/10.1021/ic5017802	journal	September 2014
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries Lin, Feng; Nordlund, Dennis; Markus, Isaac M. Energy & Environmental Science, Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01400F	journal	January 2014
Synthesis of metal ion substituted P2-Na2/3Ni1/3Mn2/3O2 cathode material with enhanced performance for Na ion batteries Zhao, Wenwen; Kirie, Hideyuki; Tanaka, Akinobu Materials Letters, Vol. 135 https://doi.org/10.1016/j.matlet.2014.07.153	journal	November 2014
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721 https://doi.org/10.1002/aenm.201200026	journal	May 2012
Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells Zheng, Honghe; Sun, Qingna; Liu, Gao Journal of Power Sources, Vol. 207 https://doi.org/10.1016/j.jpowsour.2012.01.122	journal	June 2012
Exploring reversible oxidation of oxygen in a manganese oxide Du, Ke; Zhu, Jinyou; Hu, Guorong Energy & Environmental Science, Vol. 9, Issue 8 https://doi.org/10.1039/C6EE01367H	journal	January 2016
Artificial Solid Electrolyte Interphase-Protected Li _x Si Nanoparticles: An Efficient and Stable Prelithiation Reagent for Lithium-Ion Batteries Zhao, Jie; Lu, Zhenda; Wang, Haotian Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b04526	journal	June 2015
Layered Na-Ion Cathodes with Outstanding Performance Resulting from the Synergetic Effect of Mixed P- and O-Type Phases Keller, Marlou; Buchholz, Daniel; Passerini, Stefano Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501555	journal	November 2015
Pursuit of Sustainable Iron-Based Sodium Battery Cathodes: Two Case Studies Barpanda, Prabeer Chemistry of Materials, Vol. 28, Issue 4 https://doi.org/10.1021/acs.chemmater.5b03926	journal	February 2016
New Insight into Structural Evolution in Layered NaCrO ₂ during Electrochemical Sodium Extraction Kubota, Kei; Ikeuchi, Issei; Nakayama, Tetsuri The Journal of Physical Chemistry C, Vol. 119, Issue 1 https://doi.org/10.1021/jp5105888	journal	December 2014
Thin-film Materials for Solid-State Rechargeable Lithium Batteries Ribeiro, J. F. R.; Sousa, R.; Silva, M. ECS Transactions, Vol. 45, Issue 29 https://doi.org/10.1149/04529.0139ecst	journal	April 2013
Update on Na-based battery materials. A growing research path Palomares, Verónica; Casas-Cabanas, Montse; Castillo-Martínez, Elizabeth Energy & Environmental Science, Vol. 6, Issue 8 https://doi.org/10.1039/c3ee41031e	journal	January 2013
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410376	journal	February 2015
Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode Mu, Linqin; Xu, Shuyin; Li, Yunming Advanced Materials, Vol. 27, Issue 43 https://doi.org/10.1002/adma.201502449	journal	October 2015
Structural and Electrochemical Characterizations of P2 and New O3-Na _x Mn _1-y Fe _y O ₂ Phases Prepared by Auto-Combustion Synthesis for Na-Ion Batteries Mortemard de Boisse, B.; Carlier, D.; Guignard, M. Journal of The Electrochemical Society, Vol. 160, Issue 4 https://doi.org/10.1149/2.032304jes	journal	January 2013
New layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries Mu, Lin-Qin; Hu, Yong-Sheng; Chen, Li-Quan Chinese Physics B, Vol. 24, Issue 3 https://doi.org/10.1088/1674-1056/24/3/038202	journal	February 2015
Unexpected Improved Performance of ALD Coated LiCoO ₂ /Graphite Li-Ion Batteries Jung, Yoon Seok; Lu, Peng; Cavanagh, Andrew S. Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200370	journal	September 2012
Synthesis and Electrode Performance of O3-Type NaFeO ₂ -NaNi _1/2 Mn _1/2 O ₂ Solid Solution for Rechargeable Sodium Batteries Yabuuchi, Naoaki; Yano, Masaya; Yoshida, Hiroaki Journal of The Electrochemical Society, Vol. 160, Issue 5 https://doi.org/10.1149/2.018305jes	journal	January 2013
O3-type layered transition metal oxide Na(NiCoFeTi) _1/4 O ₂ as a high rate and long cycle life cathode material for sodium ion batteries Yue, Ji-Li; Zhou, Yong-Ning; Yu, Xiqian Journal of Materials Chemistry A, Vol. 3, Issue 46 https://doi.org/10.1039/C5TA05769H	journal	January 2015
Artificial Solid Electrolyte Interphase To Address the Electrochemical Degradation of Silicon Electrodes Li, Juchuan; Dudney, Nancy J.; Nanda, Jagjit ACS Applied Materials & Interfaces, Vol. 6, Issue 13 https://doi.org/10.1021/am5009419	journal	June 2014
Feasibility of Cathode Surface Coating Technology for High-Energy Lithium-ion and Beyond-Lithium-ion Batteries Kalluri, Sujith; Yoon, Moonsu; Jo, Minki Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201605807	journal	March 2017
Layered P2-Na2/3[Ni1/3Mn2/3]O2 as high-voltage cathode for sodium-ion batteries: The capacity decay mechanism and Al2O3 surface modification Liu, Yihang; Fang, Xin; Zhang, Anyi Nano Energy, Vol. 27 https://doi.org/10.1016/j.nanoen.2016.06.026	journal	September 2016
Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries Yabuuchi, Naoaki; Komaba, Shinichi Science and Technology of Advanced Materials, Vol. 15, Issue 4 https://doi.org/10.1088/1468-6996/15/4/043501	journal	August 2014
Role of Ligand-to-Metal Charge Transfer in O3-Type NaFeO ₂ –NaNiO ₂ Solid Solution for Enhanced Electrochemical Properties Wang, Xianfen; Liu, Guandong; Iwao, Tatsumi The Journal of Physical Chemistry C, Vol. 118, Issue 6 https://doi.org/10.1021/jp411382r	journal	January 2014
Long-Life Nickel-Rich Layered Oxide Cathodes with a Uniform Li ₂ ZrO ₃ Surface Coating for Lithium-Ion Batteries Song, Bohang; Li, Wangda; Oh, Seung-Min ACS Applied Materials & Interfaces, Vol. 9, Issue 11 https://doi.org/10.1021/acsami.7b00070	journal	March 2017
Exploring Oxygen Activity in the High Energy P2-Type Na _0.78 Ni _0.23 Mn _0.69 O ₂ Cathode Material for Na-Ion Batteries Ma, Chuze; Alvarado, Judith; Xu, Jing Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.7b00164	journal	March 2017
Recent Progress in Electrode Materials for Sodium-Ion Batteries Kim, Hyungsub; Kim, Haegyeom; Ding, Zhang Advanced Energy Materials, Vol. 6, Issue 19 https://doi.org/10.1002/aenm.201600943	journal	July 2016
Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Cathode materials modified by surface coating for lithium ion batteries Li, C.; Zhang, H. P.; Fu, L. J. Electrochimica Acta, Vol. 51, Issue 19 https://doi.org/10.1016/j.electacta.2005.11.015	journal	May 2006
Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries Xiang, Xingde; Zhang, Kai; Chen, Jun Advanced Materials, Vol. 27, Issue 36 https://doi.org/10.1002/adma.201501527	journal	August 2015
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries Yan, Pengfei; Zheng, Jianming; Gu, Meng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14101	journal	January 2017
Atomic layer deposition of solid-state electrolyte coated cathode materials with superior high-voltage cycling behavior for lithium ion battery application Li, Xifei; Liu, Jian; Banis, Mohammad Norouzi Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE42704H	journal	January 2014
Improvement of the Cathode Electrolyte Interphase on P2-Na _2/3 Ni _1/3 Mn _2/3 O ₂ by Atomic Layer Deposition Alvarado, Judith; Ma, Chuze; Wang, Shen ACS Applied Materials & Interfaces, Vol. 9, Issue 31 https://doi.org/10.1021/acsami.7b05326	journal	July 2017
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
Layered oxides as positive electrode materials for Na-ion batteries Kubota, Kei; Yabuuchi, Naoaki; Yoshida, Hiroaki MRS Bulletin, Vol. 39, Issue 5 https://doi.org/10.1557/mrs.2014.85	journal	May 2014
Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries Aurbach, Doron; Markovsky, Boris; Salitra, Gregory Journal of Power Sources, Vol. 165, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.10.025	journal	March 2007
High Capacity Positive Electrode Material for Room Temperature Na Ion Battery: Na _x Mn _2/3 Co _1/6 Ni _1/6 O ₂ Kataoka, Riki; Mukai, Takashi; Yoshizawa, Akihiro Journal of The Electrochemical Society, Vol. 162, Issue 4 https://doi.org/10.1149/2.0181504jes	journal	January 2015
Strong Oxygen Participation in the Redox Governing the Structural and Electrochemical Properties of Na-Rich Layered Oxide Na ₂ IrO ₃ Perez, Arnaud J.; Batuk, Dmitry; Saubanère, Matthieu Chemistry of Materials, Vol. 28, Issue 22 https://doi.org/10.1021/acs.chemmater.6b03338	journal	October 2016
Structural classification and properties of the layered oxides Delmas, C.; Fouassier, C.; Hagenmuller, P. Physica B+C, Vol. 99, Issue 1-4 https://doi.org/10.1016/0378-4363(80)90214-4	journal	January 1980
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Phase evolution for conversion reaction electrodes in lithium-ion batteries Lin, Feng; Nordlund, Dennis; Weng, Tsu-Chien Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4358	journal	February 2014
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage Guo, Shaohua; Liu, Pan; Sun, Yang Angewandte Chemie, Vol. 127, Issue 40 https://doi.org/10.1002/ange.201505215	journal	August 2015
Layered Na-Ion Cathodes with Outstanding Performance Resulting from the Synergetic Effect of Mixed P- and O-Type Phases Keller, Marlou; Buchholz, Daniel; Passerini, Stefano Advanced Energy Materials, Vol. 7, Issue 18 https://doi.org/10.1002/aenm.201702305	journal	September 2017
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450271	journal	December 2004
Layered Na-Ion Cathodes with Outstanding Performance Resulting from the Synergetic Effect of Mixed P- and O-Type Phases Keller, M.; Buchholz, D.; Passerini, S. Karlsruhe https://doi.org/10.5445/ir/1000053111	text	January 2016

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