Electromagnon with Sensitive Terahertz Magnetochromism in a Room-Temperature Magnetoelectric Hexaferrite

Chun, Sae Hwan; Shin, Kwang Woo; Kim, Hyung Joon; Jung, Seonghoon; Park, Jaehun; Bahk, Young-Mi; Park, Hyeong-Ryeol; Kyoung, Jisoo; Choi, Da-Hye; Kim, Dai-Sik; Park, Gun-Sik; Mitchell, J. F.; Kim, Kee Hoon

doi:10.1103/PhysRevLett.120.027202

Title: Electromagnon with Sensitive Terahertz Magnetochromism in a Room-Temperature Magnetoelectric Hexaferrite

Journal Article · Fri Jan 12 00:00:00 EST 2018 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.120.027202· OSTI ID:1425289

Chun, Sae Hwan ^[1]; Shin, Kwang Woo ^[1]; Kim, Hyung Joon ^[1]; Jung, Seonghoon ^[2]; Park, Jaehun ^[2]; Bahk, Young-Mi ^[3]; Park, Hyeong-Ryeol ^[3]; Kyoung, Jisoo ^[3]; Choi, Da-Hye ^[4]; Kim, Dai-Sik ^[3]; Park, Gun-Sik ^[4]; Mitchell, J. F. ^[5]; Kim, Kee Hoon ^[1]

Seoul National Univ. (Korea, Republic of). CeNSCMR, Dept. of Physics and Astronomy
Pohang Accelerator Lab., Pohang (South Korea)
Seoul National Univ. (Korea, Republic of). Dept. of Physics and Astronomy, Nano Optics Group
Seoul National Univ. (Korea, Republic of). Center for THz-Bio Application systems, Dept. of Physics and Astronomy
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division

An electromagnon in the magnetoelectric (ME) hexaferrite Ba_0.5Sr_2.5Co₂Fe₂₄O₄₁ (Co₂ Z-type) single cystal is identified by time-domain terahertz (THz) spectroscopy. The associated THz resonance is active on the electric field (E^ω) of the THz light parallel to the c axis (∥ [001]), whose spectral weight develops at a markedly high temperature, coinciding with a transverse conical magnetic order below 410 K. The resonance frequency of 1.03 THz at 20 K changes -8.7% and +5.8% under external magnetic field (H) of 2 kOe along [001] and [120], respectively. A model Hamiltonian describing the conical magnetic order elucidates that the dynamical ME effect arises from antiphase motion of spins which are coupled with modulating electric dipoles through the exchange striction mechanism. Moreover, the calculated frequency shift points to the key role of the Dzyaloshinskii-Moriya interaction that is altered by static electric polarization change under different H.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Research Foundation of Korea (NRF)

Contributing Organization:: Magnetoelectric effect; Multiferroics

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1425289

Alternate ID(s):: OSTI ID: 1416836

Journal Information:: Physical Review Letters, Vol. 120, Issue 2; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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References (46)

Theory of Electromagnons in the Multiferroic Mn Perovskites: The Vital Role of Higher Harmonic Components of the Spiral Spin Order Mochizuki, Masahito; Furukawa, Nobuo; Nagaosa, Naoto Physical Review Letters, Vol. 104, Issue 17 https://doi.org/10.1103/PhysRevLett.104.177206	journal	April 2010
Magnetic Ordering in Relation to the Room-Temperature Magnetoelectric Effect of ${Sr}_{3} {Co}_{2} {Fe}_{24} O_{41}$ Soda, Minoru; Ishikura, Taishi; Nakamura, Hiroyuki Physical Review Letters, Vol. 106, Issue 8 https://doi.org/10.1103/PhysRevLett.106.087201	journal	February 2011
Magnetic structures and excitations in a multiferroic Y-type hexaferrite ${BaSrCo}_{2} {Fe}_{11} {AlO}_{22}$ Nakajima, Taro; Tokunaga, Yusuke; Matsuda, Masaaki Physical Review B, Vol. 94, Issue 19 https://doi.org/10.1103/PhysRevB.94.195154	journal	November 2016
Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites Sergienko, I. A.; Dagotto, E. Physical Review B, Vol. 73, Issue 9 https://doi.org/10.1103/PhysRevB.73.094434	journal	March 2006
Origin of Electromagnon Excitations in Multiferroic $R {MnO}_{3}$ Valdés Aguilar, R.; Mostovoy, M.; Sushkov, A. B. Physical Review Letters, Vol. 102, Issue 4 https://doi.org/10.1103/PhysRevLett.102.047203	journal	January 2009
Magnetic control of ferroelectric polarization Kimura, T.; Goto, T.; Shintani, H. Nature, Vol. 426, Issue 6962 https://doi.org/10.1038/nature02018	journal	November 2003
Gigantic terahertz magnetochromism via electromagnons in the hexaferrite magnet Ba $_{2}$ Mg $_{2}$ Fe $_{12}$ O $_{22}$ Kida, N.; Kumakura, S.; Ishiwata, S. Physical Review B, Vol. 83, Issue 6 https://doi.org/10.1103/PhysRevB.83.064422	journal	February 2011
Ferroelectricity in Spiral Magnets Mostovoy, Maxim Physical Review Letters, Vol. 96, Issue 6 https://doi.org/10.1103/PhysRevLett.96.067601	journal	February 2006
Electromagnons in the Spin Collinear State of a Triangular Lattice Antiferromagnet Seki, S.; Kida, N.; Kumakura, S. Physical Review Letters, Vol. 105, Issue 9 https://doi.org/10.1103/PhysRevLett.105.097207	journal	August 2010
Dynamical Magnetoelectric Coupling in Helical Magnets Katsura, Hosho; Balatsky, Alexander V.; Nagaosa, Naoto Physical Review Letters, Vol. 98, Issue 2 https://doi.org/10.1103/PhysRevLett.98.027203	journal	January 2007
Detection of Coherent Magnons via Ultrafast Pump-Probe Reflectance Spectroscopy in Multiferroic ${Ba}_{0.6} {Sr}_{1.4} {Zn}_{2} {Fe}_{12} O_{22}$ Talbayev, D.; Trugman, S. A.; Balatsky, A. V. Physical Review Letters, Vol. 101, Issue 9 https://doi.org/10.1103/PhysRevLett.101.097603	journal	August 2008
Electromagnons in Multiferroic ${YMn}_{2} O_{5}$ and ${TbMn}_{2} O_{5}$ Sushkov, A. B.; Aguilar, R. Valdés; Park, S. Physical Review Letters, Vol. 98, Issue 2 https://doi.org/10.1103/PhysRevLett.98.027202	journal	January 2007
Low-field magnetoelectric effect at room temperature Kitagawa, Yutaro; Hiraoka, Yuji; Honda, Takashi Nature Materials, Vol. 9, Issue 10 https://doi.org/10.1038/nmat2826	journal	August 2010
Possible Observation of Cycloidal Electromagnons in ${BiFeO}_{3}$ Cazayous, M.; Gallais, Y.; Sacuto, A. Physical Review Letters, Vol. 101, Issue 3 https://doi.org/10.1103/PhysRevLett.101.037601	journal	July 2008
Electric Field Control of Nonvolatile Four-State Magnetization at Room Temperature Chun, Sae Hwan; Chai, Yi Sheng; Jeon, Byung-Gu Physical Review Letters, Vol. 108, Issue 17 https://doi.org/10.1103/PhysRevLett.108.177201	journal	April 2012
High-temperature electromagnons in the magnetically induced multiferroic cupric oxide driven by intersublattice exchange Jones, S. P. P.; Gaw, S. M.; Doig, K. I. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4787	journal	April 2014
Ferroelectricity Induced by Proper-Screw Type Magnetic Order Arima, Taka-hisa Journal of the Physical Society of Japan, Vol. 76, Issue 7 https://doi.org/10.1143/JPSJ.76.073702	journal	July 2007
Heliconical magnetic order and field-induced multiferroicity of the Co $_{2}$ Y-type hexaferrite Ba $_{0.3}$ Sr $_{1.7}$ Co $_{2}$ Fe $_{12}$ O $_{22}$ Lee, Hak Bong; Chun, Sae Hwan; Shin, Kwang Woo Physical Review B, Vol. 86, Issue 9 https://doi.org/10.1103/PhysRevB.86.094435	journal	September 2012
Magnetoelectric resonance with electromagnons in a perovskite helimagnet Takahashi, Youtarou; Shimano, Ryo; Kaneko, Yoshio Nature Physics, Vol. 8, Issue 2 https://doi.org/10.1038/nphys2161	journal	December 2011
Electric-dipole-active magnetic resonance in the conical-spin magnet ${Ba}_{2} {Mg}_{2} {Fe}_{12} O_{22}$ Kida, N.; Okuyama, D.; Ishiwata, S. Physical Review B, Vol. 80, Issue 22 https://doi.org/10.1103/PhysRevB.80.220406	journal	December 2009
Long-wavelength magnetic and magnetoelectric excitations in the ferroelectric antiferromagnet BiFeO $_{3}$ Talbayev, D.; Trugman, S. A.; Lee, Seongsu Physical Review B, Vol. 83, Issue 9 https://doi.org/10.1103/PhysRevB.83.094403	journal	March 2011
Electromagnon in the $Z$ -type hexaferrite ${({Ba}_{x} {Sr}_{1 - x})}_{3} {Co}_{2} {Fe}_{24} O_{41}$ Kadlec, Filip; Kadlec, Christelle; Vít, Jakub Physical Review B, Vol. 94, Issue 2 https://doi.org/10.1103/PhysRevB.94.024419	journal	July 2016
Structural Anomalies and Multiferroic Behavior in Magnetically Frustrated ${T b M n}_{2} O_{5}$ Chapon, L. C.; Blake, G. R.; Gutmann, M. J. Physical Review Letters, Vol. 93, Issue 17 https://doi.org/10.1103/PhysRevLett.93.177402	journal	October 2004
Possible evidence for electromagnons in multiferroic manganites Pimenov, A.; Mukhin, A. A.; Ivanov, V. Yu. Nature Physics, Vol. 2, Issue 2 https://doi.org/10.1038/nphys212	journal	January 2006
Terahertz time-domain spectroscopy of electromagnons in multiferroic perovskite manganites [Invited] Kida, N.; Takahashi, Y.; Lee, J. S. Journal of the Optical Society of America B, Vol. 26, Issue 9 https://doi.org/10.1364/JOSAB.26.000A35	journal	January 2009
Cutting-edge terahertz technology Tonouchi, Masayoshi Nature Photonics, Vol. 1, Issue 2 https://doi.org/10.1038/nphoton.2007.3	journal	February 2007
Field-induced incommensurate-to-commensurate phase transition in the magnetoelectric hexaferrite Ba $_{0.5}$ Sr $_{1.5}$ Zn $_{2}$ (Fe $_{1 - x}$ Al $_{x}$ ) $_{12}$ O $_{22}$ Lee, Hak Bong; Song, Young-Sang; Chung, Jae-Ho Physical Review B, Vol. 83, Issue 14 https://doi.org/10.1103/PhysRevB.83.144425	journal	April 2011
Magnetic Excitations in Multiferroic ${TbMnO}_{3}$ : Evidence for a Hybridized Soft Mode Senff, D.; Link, P.; Hradil, K. Physical Review Letters, Vol. 98, Issue 13 https://doi.org/10.1103/PhysRevLett.98.137206	journal	March 2007
Enhanced Directional Dichroism of Terahertz Light in Resonance with Magnetic Excitations of the Multiferroic ${Ba}_{2} {CoGe}_{2} O_{7}$ Oxide Compound Kézsmárki, I.; Kida, N.; Murakawa, H. Physical Review Letters, Vol. 106, Issue 5 https://doi.org/10.1103/PhysRevLett.106.057403	journal	February 2011
Revival of the magnetoelectric effect Fiebig, Manfred Journal of Physics D: Applied Physics, Vol. 38, Issue 8 https://doi.org/10.1088/0022-3727/38/8/R01	journal	April 2005
Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides Jia, Chenglong; Onoda, Shigeki; Nagaosa, Naoto Physical Review B, Vol. 76, Issue 14 https://doi.org/10.1103/PhysRevB.76.144424	journal	October 2007
Spin Current and Magnetoelectric Effect in Noncollinear Magnets Katsura, Hosho; Nagaosa, Naoto; Balatsky, Alexander V. Physical Review Letters, Vol. 95, Issue 5 https://doi.org/10.1103/PhysRevLett.95.057205	journal	July 2005
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Multiferroic and magnetoelectric materials Eerenstein, W.; Mathur, N. D.; Scott, J. F. Nature, Vol. 442, Issue 7104 https://doi.org/10.1038/nature05023	journal	August 2006
Large-Amplitude Spin Dynamics Driven by a THz Pulse in Resonance with an Electromagnon Kubacka, T.; Johnson, J. A.; Hoffmann, M. C. Science, Vol. 343, Issue 6177 https://doi.org/10.1126/science.1242862	journal	March 2014
Electric polarization reversal and memory in a multiferroic material induced by magnetic fields Hur, N.; Park, S.; Sharma, P. A. Nature, Vol. 429, Issue 6990 https://doi.org/10.1038/nature02572	journal	May 2004
Multiferroic and Magnetoelectric Materials Eerenstein, W.; Mathur, N. D.; Scott, J. F. ChemInform, Vol. 37, Issue 44 https://doi.org/10.1002/chin.200644216	journal	October 2006
Revival of the Magnetoelectric Effect Fiebig, Manfred ChemInform, Vol. 36, Issue 33 https://doi.org/10.1002/chin.200533283	journal	August 2005
Terahertz time-domain spectroscopy of electromagnons in multiferroic perovskite manganites Kida, N.; Takahashi, Y.; Lee, J. S. arXiv https://doi.org/10.48550/arxiv.0904.4796	text	January 2009
Electromagnons in the spin collinear state of a triangular lattice antiferromagnet Seki, S.; Kida, N.; Kumakura, S. arXiv https://doi.org/10.48550/arxiv.1008.4709	text	January 2010
Electric field control of nonvolatile four-state magnetization at room temperature Chun, Sae Hwan; Chai, Yi Sheng; Jeon, Byung-Gu arXiv https://doi.org/10.48550/arxiv.1111.4525	text	January 2011
Spin current and magneto-electric effect in non-collinear magnets Katsura, Hosho; Nagaosa, Naoto; Balatsky, Alexander V. arXiv https://doi.org/10.48550/arxiv.cond-mat/0412319	text	January 2004
Ferroelectricity in spiral magnets Mostovoy, Maxim arXiv https://doi.org/10.48550/arxiv.cond-mat/0510692	text	January 2005
Possible evidence for electromagnons in multiferroic manganites Pimenov, A.; Mukhin, A. A.; Ivanov, V. Yu. arXiv https://doi.org/10.48550/arxiv.cond-mat/0602173	text	January 2006
Dynamical magneto-electric coupling in helical magnets Katsura, Hosho; Balatsky, Alexander V.; Nagaosa, Naoto arXiv https://doi.org/10.48550/arxiv.cond-mat/0602547	text	January 2006
Electromagnons in multiferroic YMn2O5 and TbMn2O5 Sushkov, A. B.; Aguilar, R. Valdes; Park, S. arXiv https://doi.org/10.48550/arxiv.cond-mat/0608707	text	January 2006

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Vibrational spectra of multiferroics with Y- and Z-type hexaferrite structures Kamba, Stanislav; Borodavka, Fedir; Kadlec, Filip Ferroelectrics, Vol. 532, Issue 1 https://doi.org/10.1080/00150193.2018.1499406	journal	August 2018
Electromagnon Resonance at Room Temperature with Gigantic Magnetochromism Shishikura, H.; Tokunaga, Y.; Takahashi, Y. Physical Review Applied, Vol. 9, Issue 4 https://doi.org/10.1103/physrevapplied.9.044033	journal	April 2018

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