Real-Time Visualization of Active Species in a Single-Site Metal–Organic Framework Photocatalyst

Yang, Sizhuo; Pattengale, Brian; Lee, Sungsik; Huang, Jier

doi:10.1021/acsenergylett.8b00062

Title: Real-Time Visualization of Active Species in a Single-Site Metal–Organic Framework Photocatalyst

Journal Article · Tue Feb 06 00:00:00 EST 2018 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.8b00062· OSTI ID:1425274

Yang, Sizhuo ^[1]; Pattengale, Brian ^[1]; Lee, Sungsik ^[2];

^[1]

Marquette Univ., Milwaukee, WI (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division

Here in this work, we report a new single-site photocatalyst (Co-Ru-UIO- 67(bpy)) based on a metal-organic framework platform with incorporated molecular photosensitizer and catalyst. We show that this catalyst not only demonstrates exceptional activity for light-driven H₂ production but also can be recycled without loss of activity. Using the combination of optical transient absorption spectroscopy and in situ X-ray absorption spectroscopy, we not only captured the key Co^I intermediate species formed after ultrafast charge transfer from the incorporated photosensitizer but also identified the rate-limiting step in the catalytic cycle, providing insight into the catalysis mechanism of these single-site metal-organic framework photocatalysts.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1425274

Journal Information:: ACS Energy Letters, Vol. 3, Issue 3; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 46 works

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