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Title: Corrosion in ICPP fuel storage basins

Technical Report ·
DOI:https://doi.org/10.2172/142494· OSTI ID:142494

The Idaho Chemical Processing Plant currently stores irradiated nuclear fuel in fuel storage basins. Historically, fuel has been stored for over 30 years. During the 1970`s, an algae problem occurred which required higher levels of chemical treatment of the basin water to maintain visibility for fuel storage operations. This treatment led to higher levels of chlorides than seen previously which cause increased corrosion of aluminum and carbon steel, but has had little effect on the stainless steel in the basin. Corrosion measurements of select aluminum fuel storage cans, aluminum fuel storage buckets, and operational support equipment have been completed. Aluminum has exhibited good general corrosion rates, but has shown accelerated preferential attack in the form of pitting. Hot dipped zinc coated carbon steel, which has been in the basin for approximately 40 years, has shown a general corrosion rate of 4 mpy, and there is evidence of large shallow pits on the surface. A welded Type 304 stainless steel corrosion coupon has shown no attack after 13 years exposure. Galvanic couples between carbon steel welded to Type 304 stainless steel occur in fuel storage yokes exposed to the basin water. These welded couples have shown galvanic attack as well as hot weld cracking and intergranular cracking. The intergranular stress corrosion cracking is attributed to crevices formed during fabrication which allowed chlorides to concentrate.

Research Organization:
Westinghouse Idaho Nuclear Co., Inc., Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC07-84ID12435
OSTI ID:
142494
Report Number(s):
WINCO-1153; ON: DE94008811; TRN: 94:006565
Resource Relation:
Other Information: PBD: Sep 1993
Country of Publication:
United States
Language:
English