Effect of Cation-π Interaction on Macroionic Self-Assembly

Luo, Jiancheng; Chen, Kun; Yin, Panchao; Li, Tao; Wan, Gang; Zhang, Jin; Ye, Songtao; Bi, Xiaoman; Pang, Yi; Wei, Yongge; Liu, Tianbo

doi:10.1002/anie.201800409

Title: Effect of Cation-π Interaction on Macroionic Self-Assembly

Journal Article · Tue Feb 13 00:00:00 EST 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201800409· OSTI ID:1461310

^[1]; Chen, Kun ^[2]; Yin, Panchao ^[1]; Li, Tao ^[3]; Wan, Gang ^[4]; Zhang, Jin ^[2]; Ye, Songtao ^[1]; Bi, Xiaoman ^[1]; Pang, Yi ^[1]; Wei, Yongge ^[2];

^[1]

Univ. of Akron, Akron, OH (United States)
Tsinghua Univ., Beijing (People's Republic of China)
Argonne National Lab. (ANL), Argonne, IL (United States); Northern Illinois Univ., DeKalb, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Abstract A series of rod‐shaped polyoxometalates (POMs) [Bu ₄ N] ₇ [Mo ₆ O ₁₈ NC(CH ₂ O) ₃ MnMo ₆ O ₁₈ (OCH ₂ ) ₃ CNMo ₆ O ₁₈ ] and [Bu ₄ N] ₇ [ArNMo ₆ O ₁₇ NC(CH ₂ O) ₃ MnMo ₆ O ₁₈ (OCH ₂ ) ₃ CNMo ₆ O ₁₇ NAr] (Ar=2,6‐dimethylphenyl, naphthyl and 1‐methylnaphthyl) were chosen to study the effects of cation–π interaction on macroionic self‐assembly. Diffusion ordered spectroscopy (DOSY) and isothermal titration calorimetry (ITC) techniques show that the binding affinity between the POMs and Zn ²⁺ ions is enhanced significantly after grafting aromatic groups onto the clusters, leading to the effective replacement of tetrabutylammonium counterions (TBAs) upon the addition of ZnCl ₂ . The incorporation of aromatic groups results in the significant contribution of cation–π interaction to the self‐assembly, as confirmed by the opposite trend of assembly size vs. ionic strength when compared with those without aromatic groups. The small difference between two aromatic groups toward the Zn ²⁺ ions is amplified after combining with the clusters, which consequently triggers the self‐recognition behavior between two highly similar macroanions.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1461310

Alternate ID(s):: OSTI ID: 1423707

Journal Information:: Angewandte Chemie (International Edition), Vol. 57, Issue 15; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
binding affinity
cation-pi interaction
macroionic self-assembly
polyoxometalates
self-recognition