Non-oxidative Coupling of Methane to Ethylene Using Mo2 C/[B]ZSM-5

Sheng, Huibo; Schreiner, Edward P.; Zheng, Weiqing; Lobo, Raul F.

doi:10.1002/cphc.201701001

Non-oxidative Coupling of Methane to Ethylene Using Mo₂ C/[B]ZSM-5

Journal Article · 05 January 2018 · ChemPhysChem

DOI:https://doi.org/10.1002/cphc.201701001· OSTI ID:1423345

Sheng, Huibo ^[1]; Schreiner, Edward P. ^[1]; Zheng, Weiqing ^[1]; ^[1]

Center for Catalysis Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street Newark DE 19716 USA

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: AFR

OSTI ID:: 1423345

Journal Information:: ChemPhysChem, Vol. 19, Issue 4; ISSN 1439-4235

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: ENGLISH

References (40)

Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century No authors listed Catalysis Today https://doi.org/10.1016/S0920-5861(00)00456-9		December 2000
CH4 dehydroaromatization on Mo/H–ZSM-5: 1. Effects of co-processing H2 and CH3COOH No authors listed Journal of Catalysis https://doi.org/10.1016/j.jcat.2013.06.003		October 2013
The Effects of Silanation of External Acid Sites on the Structure and Catalytic Behavior of Mo/H–ZSM5 No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.2001.3457		February 2002
Partial oxidation of methane to synthesis gas using carbon dioxide No authors listed Nature https://doi.org/10.1038/352225a0		July 1991
Methane dehydro-aromatization on Mo/ZSM-5: About the hidden role of Brønsted acid sites No authors listed Applied Catalysis A: General https://doi.org/10.1016/j.apcata.2007.08.026		March 2008
Passivation agents and conditions for Mo2C and W2C: Effect on catalytic activity for toluene hydrogenation No authors listed Journal of Catalysis https://doi.org/10.1016/j.jcat.2017.01.002		March 2017
The preparation and genesis of molybdena-alumina and related catalyst systems No authors listed Journal of Catalysis https://doi.org/10.1016/0021-9517(82)90163-4		September 1982
Dehydrogenation and aromatization of methane under non-oxidizing conditions No authors listed Catalysis Letters https://doi.org/10.1007/BF00767368		January 1993
UV−Vis Microspectroscopy: Probing the Initial Stages of Supported Metal Oxide Catalyst Preparation No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja044460u		April 2005
Spectroscopic investigation of bismuth–molybdenum–oxide catalysts No authors listed J. Chem. Soc. A https://doi.org/10.1039/J19700003183		January 1970
Effect of Local Structure on the UV-Visible Absorption Edges of Molybdenum Oxide Clusters and Supported Molybdenum Oxides No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1995.1052		February 1995
Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Catalysts for Nonoxidative Methane Conversion No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp990866v		July 1999
Changes in the structure of ZSM-5 zeolites during boron and aluminium substitution No authors listed Journal of the Chemical Society, Faraday Transactions https://doi.org/10.1039/ft9908600753		January 1990
Nonoxidative Activation of Methane No authors listed Catalysis Reviews https://doi.org/10.1081/CR-120017010		January 2003
Determination of structural boron in borosilicate molecular sieves via X-ray diffraction No authors listed Journal of Catalysis https://doi.org/10.1016/0021-9517(85)90348-3		February 1985
Remarkable Improvement on the Methane Aromatization Reaction: A Highly Selective and Coking-Resistant Catalyst No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp020166h		August 2002
Polyoxometallates as models for oxide catalysts Part I. An UV-visible reflectance study of polyoxomolybdates: Influence of polyhedra arrangement on the electronic transitions and comparison with supported molybdenum catalysts No authors listed Journal of Catalysis https://doi.org/10.1016/0021-9517(89)90170-X		October 1989
The properties of boralites studied by infrared spectroscopy No authors listed Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases https://doi.org/10.1039/f19898500047		January 1989
Study with density functional theory method on methane C–H bond activation on the MoO2/HZSM-5 active center No authors listed Chemical Physics Letters https://doi.org/10.1016/S0009-2614(03)00513-X		May 2003
Effect of thermal treatment on states of molybdenum in Mo/H?ZSM-5 catalyst for methane dehydroaromatization: ESR and UV?VIS study No authors listed Topics in Catalysis https://doi.org/10.1007/s11244-005-9260-5		February 2005
Selectivities in Post-Synthetic Modification of Borosilicate Zeolites No authors listed Topics in Catalysis https://doi.org/10.1007/s11244-015-0382-0		April 2015
Aromatization of Methane over Supported and Unsupported Mo-Based Catalysts No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1997.1478		January 1997
Characterization of surface carbon formed during the conversion of methane to benzene over Mo/H-ZSM-5 catalysts No authors listed Catalysis Letters https://doi.org/10.1023/A:1019094630691		June 1998
Raman and X-Ray Absorption Studies of Mo Species in Mo/H-ZSM5 Catalysts for Non-Oxidative CH4 Reactions No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1999.2795		April 2000
Methane Conversion to Aromatics on Mo/H-ZSM5: Structure of Molybdenum Species in Working Catalysts No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp0030692		January 2001
Structural Characterization of Molybdenum Oxide Supported on Zirconia No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp002419h		November 2000
Methane activation without using oxidants over Mo/HZSM-5 zeolite catalysts No authors listed Catalysis Letters https://doi.org/10.1007/BF00813680		January 1995
Characterization of a Mo/ZSM-5 Catalyst for the Conversion of Methane to Benzene No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1997.1712		July 1997
On the Induction Period of Methane Aromatization over Mo-Based Catalysts No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.2000.2908		August 2000
Cobalt–molybdenum–alumina hydrodesulphurisation catalysts. Part I. A spectroscopic and magnetic study of the fresh catalyst and model compounds No authors listed J. Chem. Soc. A https://doi.org/10.1039/J19680002821		January 1968
The monoclinic framework structure of zeolite H-ZSM-5. Comparison with the orthorhombic framework of as-synthesized ZSM-5 No authors listed Zeolites https://doi.org/10.1016/0144-2449(94)90134-1		April 1990
Aromatization of methane over zeolite supported molybdenum: active sites and reaction mechanism No authors listed Journal of Molecular Catalysis A: Chemical https://doi.org/10.1016/S1381-1169(01)00373-9		March 2002
Non-oxidative methane dehydroaromatization on Mo/HZSM-5 catalysts: Tuning the acidic and catalytic properties through partial exchange of zeolite protons with alkali and alkaline-earth cations No authors listed Applied Catalysis A: General https://doi.org/10.1016/j.apcata.2016.01.044		April 2016
Catalytic Dehydrocondensation of Methane with CO and CO2toward Benzene and Naphthalene on Mo/HZSM-5 and Fe/Co-Modified Mo/HZSM-5 No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1998.2319		February 1999
Density Functional Theory Study on Structure of Molybdenum Carbide and Catalytic Mechanism for Methane Activation over ZSM-5 Zeolite No authors listed Chinese Journal of Catalysis https://doi.org/10.1016/S1872-2067(09)60062-0		January 2010
A versatile sample-environment cell for non-ambient X-ray scattering experiments No authors listed Journal of Applied Crystallography https://doi.org/10.1107/S0021889808020165		July 2008
Conversion of Methane to Benzene over Transition Metal Ion ZSM-5 Zeolites No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1998.2010		April 1998
Titanium Boralites with MFI Structure Characterized Using XRD, XANES, IR, and UV-Visible Techniques: Effect of Hydrogen Peroxide on the Preparation No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1995.1284		November 1995
The effects of boron and silver on the oxygen-free conversion of methane over Mo/H-ZSM-5 catalysts No authors listed Journal of Molecular Catalysis A: Chemical https://doi.org/10.1016/j.molcata.2008.10.047		June 2009
Bifunctional Catalysis of Mo/HZSM-5 in the Dehydroaromatization of Methane to Benzene and Naphthalene XAFS/TG/DTA/MASS/FTIR Characterization and Supporting Effects No authors listed Journal of Catalysis https://doi.org/10.1006/jcat.1998.2310		January 1999