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Title: Self-healing liquid/solid state battery

Patent ·
OSTI ID:1423297

A battery system that exchanges energy with an external device is provided. The battery system includes a positive electrode having a first metal or alloy, a negative electrode having a second metal or alloy, and an electrolyte including a salt of the second metal or alloy. The positive electrode, the negative electrode, and the electrolyte are in a liquid phase at an operating temperature during at least one portion of operation. The positive electrode is entirely in a liquid phase in one charged state and includes a solid phase in another charged state. The solid phase of the positive electrode includes a solid intermetallic formed by the first and the second metals or alloys. Methods of storing electrical energy from an external circuit using such a battery system are also provided.

Research Organization:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Total S.A. (Courbevoie, FR), Total Energies Nouvelles Activites USA (Coubervoie, FR)
Sponsoring Organization:
USDOE
DOE Contract Number:
AR0000047
Assignee:
Massachusetts Institute of Technology (Cambridge, MA); Total S.A. (Courbevoie, FR) Total Energies Nouvelles Activites USA; (Coubervoie, FR)
Patent Number(s):
9,905,888
Application Number:
14/526,897
OSTI ID:
1423297
Resource Relation:
Patent File Date: 2014 Oct 29
Country of Publication:
United States
Language:
English

References (20)

Regeneration of EMF Cells Having Molten Metal Electrodes and a Fused Salt Electrolyte patent March 1966
Storage Battery Electrolyte patent May 1972
Lithium Storage Cells with a Fused Electrolyte patent November 1973
High-amperage energy storage device with liquid metal negative electrode and methods patent September 2012
Alkaline earth metal ion battery patent December 2012
Alkali metal ion battery with bimetallic electrode patent April 2015
Electrochemical energy storage devices patent April 2016
Liquid Electrode Battery patent-application January 2011
Alkali Metal Ion Battery with Bimetallic Electrode patent-application May 2012
Arrangement and Method for Storing Electric Energy in Electrochemical Cells with a Large Diameter and High Storage Capacity patent-application March 2013
Low-Temperature Liquid Metal Batteries for Grid-Scaled Storage patent-application April 2014
Electrochemical Energy Storage Devices patent-application April 2014
High Amperage Batteries with Displacement Salt Electrodes patent-application September 2014
Electrochemical Energy Storage Devices patent-application January 2015
Electrochemical Energy Storage Devices patent-application May 2015
Electrochemical Energy Storage Devices patent-application September 2015
Electrochemical Energy Storage Devices patent-application September 2015
Calcium–bismuth electrodes for large-scale energy storage (liquid metal batteries) journal November 2013
Self-healing Li–Bi liquid metal battery for grid-scale energy storage journal February 2015
The Sodium∣Tin Liquid-Metal Cell journal January 1962

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