Energetics of bulk lutetium‐doped Ce 1−x Lu x O 2−x/2 compounds
- Department of Materials and Interfaces Weizmann Institute of Science Rehovot Israel
- Peter A. Rock Thermochemistry Laboratory NEAT‐ORU University of California Davis Davis California
- Applied Research Center Ben Gurion University of the Negev Beer Sheva Israel
- Peter A. Rock Thermochemistry Laboratory NEAT‐ORU University of California Davis Davis California, Department of Materials Nuclear Research Center Beer Sheva Israel
Abstract The dissolution enthalpy , Δ H DS , and the formation enthalpy, Δ H f,ox , of bulk lutetium‐doped cerium oxide (LuDC) were studied at 701°C in molten sodium molybdate. For the composition range of Ce 1− X Lu X O 2− X /2 , studied 0 ≤ X ≤ 0.3, the Δ H DS decreases linearly and smoothly with lutetium content according to Δ H DS , kJ/mol = 73.5(1.0)−165.1(5.5)· x ). The enthalpy of formation, Δ H f,ox , becomes more exothermic linearly with lutetium content. No anomaly in Δ H f,ox is observed at low Lu 2 O 3 concentration as reported previously for several other rare‐earth‐doped ceria systems, suggesting possible differences in clustering and microstructure, which may also be related to difference in processing conditions.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1422636
- Journal Information:
- Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Vol. 101 Journal Issue: 8; ISSN 0002-7820
- Publisher:
- Wiley-BlackwellCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
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