New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior

Shan, Weida; Fulvio, Pasquale F.; Kong, Liyun; Schott, Jennifer A.; Do-Thanh, Chi-Linh; Tian, Tao; Hu, Xunxiang; Mahurin, Shannon M.; Xing, Huabin; Dai, Sheng

doi:10.1021/acsami.7b15873

Title: New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior

Journal Article · Tue Dec 26 00:00:00 EST 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b15873· OSTI ID:1422616

Shan, Weida ^[1]; Fulvio, Pasquale F. ^[2]; Kong, Liyun ^[3];

^[3];

^[3]; Tian, Tao ^[4];

^[5]; Mahurin, Shannon M. ^[4];

^[6];

^[7]

Zhejiang Univ., Hangzhou (China). Key Lab. of Biomass Chemical Engineering. College of Chemical and Biological Engineering; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Univ. of Puerto Rico, San Juan, PR (United States). Dept. of Chemistry; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Zhejiang Univ., Hangzhou (China). Key Lab. of Biomass Chemical Engineering. College of Chemical and Biological Engineering
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Porous materials have already manifested their unique properties in a number of fields. Generally, all porous materials are in a solid state other than liquid, in which molecules are closely packed without porosity. “Porous” and “liquid” seem like antonyms. In this paper, we report a new class of Type 3 porous liquids based on rational coupling of microporous framework nanoparticles as porous hosts with a bulky ionic liquid as the fluid media. Positron annihilation lifetime spectroscopy (PALS) and CO₂ adsorption measurements confirm the successful engineering of permanent porosity into these liquids. Compared to common porous solid materials, as-synthesized porous liquids exhibited pronounced hysteresis loops in the CO₂ sorption isotherms even at ambient conditions (298 K, 1 bar). Finally, the unique features of these novel porous liquids could bring new opportunities in many fields including gas separation and storage, air separation and regeneration, gas transport, and permanent gas storage at ambient conditions.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1422616

Journal Information:: ACS Applied Materials and Interfaces, Vol. 10, Issue 1; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 87 works

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Transforming Porous Organic Cages into Porous Ionic Liquids via a Supramolecular Complexation Strategy Jie, Kecheng; Onishi, Nicole; Schott, Jennifer A. Angewandte Chemie, Vol. 132, Issue 6 https://doi.org/10.1002/ange.201912068	journal	December 2019
Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents Cahir, John; Tsang, Min Ying; Lai, Beibei Chemical Science, Vol. 11, Issue 8 https://doi.org/10.1039/c9sc05770f	journal	January 2020
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Porous Ionic Liquids or Liquid Metal-Organic Frameworks? Costa Gomes, Margarida; Pison, Laure; Červinka, Ctirad Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201805495	journal	August 2018
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