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Title: Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells

Journal Article · · Advanced Materials
 [1];  [2];  [3];  [4];  [5];  [5];  [6];  [7];  [6];  [6];  [7];  [4];  [8];  [3]; ORCiD logo [6]
  1. Univ. at Buffalo, NY (United States). Dept. of Chemical and Biological Engineering; East China Univ. of Science and Technology, Shanghai (China). School of Mechanical and Power Engineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
  5. Oregon State Univ., Corvallis, OR (United States). School of Chemical, Biological, and Environmental Engineering
  6. Univ. at Buffalo, NY (United States). Dept. of Chemical and Biological Engineering
  7. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  8. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States); Univ. at Buffalo, NY (United States); East China Univ. of Science and Technology, Shanghai (China); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE Office of Science (SC); National Science Foundation (NSF); Shanghai Natural Science Foundation of China; USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC05-00OR22725; AC02-06CH11357; SC0012704; CBET-1604392; 16ZR1408600; 89233218CNA000001
OSTI ID:
1422592
Alternate ID(s):
OSTI ID: 1417922; OSTI ID: 1558078
Report Number(s):
LA-UR-19-27321; TRN: US1801631
Journal Information:
Advanced Materials, Vol. 30, Issue 11; ISSN 0935-9648
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 825 works
Citation information provided by
Web of Science

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Single Atoms on Graphene for Energy Storage and Conversion journal April 2019
A sacrificial Zn strategy enables anchoring of metal single atoms on the exposed surface of holey 2D molybdenum carbide nanosheets for efficient electrocatalysis journal January 2020
Carbon‐Coated and Interfacial‐Functionalized Mixed‐Phase Mo x Ti 1− x O 2‐δ Nanotubes as Highly Active and Durable PtRu Catalyst Support for Methanol Electrooxidation journal March 2019
A Pyrolysis-Free Covalent Organic Polymer for Oxygen Reduction journal August 2018
One‐Step Interfacial Functionalization and Synthesis of Mo–Modified TiO 2 Nanocrystalline as Composite PtRu Anode Catalyst Support for DMFCs journal May 2019
Structure, Activity, and Faradaic Efficiency of Nitrogen-Doped Porous Carbon Catalysts for Direct Electrochemical Hydrogen Peroxide Production journal September 2018
Exploring the Influence of Halogen Coordination Effect of Stable Bimetallic MOFs on Oxygen Evolution Reaction journal October 2019
A Single‐Atom Iridium Heterogeneous Catalyst in Oxygen Reduction Reaction journal July 2019
N,S–Codoped hierarchical porous carbon spheres embedded with cobalt nanoparticles as efficient bifunctional oxygen electrocatalysts for rechargeable zinc-air batteries journal January 2019
Modulating the Electronic Structure of Single‐Atom Catalysts on 2D Nanomaterials for Enhanced Electrocatalytic Performance journal March 2019
Integration mesoporous surface and hollow cavity into PtPdRh nano-octahedra for enhanced oxygen reduction electrocatalysis journal October 2019
Boosting the performance of the Fe–N–C catalyst for the oxygen reduction reaction by introducing single-walled carbon nanohorns as branches on carbon fibers journal January 2019
Multiscale porous Fe–N–C networks as highly efficient catalysts for the oxygen reduction reaction journal January 2019
Oxygen Reduction Reactions of Fe-N-C Catalysts: Current Status and the Way Forward journal March 2019
Recent Advances in Carbon‐Based Metal‐Free Electrocatalysts journal December 2018
Alloyed Pt 3 M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction journal January 2019
Tailoring Nitrogen‐Doped Carbons as Hosts for Single‐Atom Catalysts journal May 2019
A Review on Recent Progress in the Aspect of Stability of Oxygen Reduction Electrocatalysts for Proton‐Exchange Membrane Fuel Cell: Quantum Mechanics and Experimental Approaches journal June 2019
Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation journal July 2019
Ultrathin Nitrogen-Doped Holey Carbon@Graphene Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions in Alkaline and Acidic Media journal November 2018
Simultaneously Integrating Single Atomic Cobalt Sites and Co 9 S 8 Nanoparticles into Hollow Carbon Nanotubes as Trifunctional Electrocatalysts for Zn–Air Batteries to Drive Water Splitting journal March 2020
Isolated Fe atoms dispersed on cellulose-derived nanocarbons as an efficient electrocatalyst for the oxygen reduction reaction journal January 2019
Boosting the Loading of Metal Single Atoms via a Bioconcentration Strategy journal March 2020
Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion journal March 2019
Standing Carbon‐Supported Trace Levels of Metal Derived from Covalent Organic Framework for Electrocatalysis journal October 2019
Dispersive Single-Atom Metals Anchored on Functionalized Nanocarbons for Electrochemical Reactions journal January 2019
Controllable synthesis of CoN 3 catalysts derived from Co/Zn-ZIF-67 for electrocatalytic oxygen reduction in acidic electrolytes journal January 2019
The Multifaceted Reactivity of Single-Atom Heterogeneous Catalysts journal October 2018
Atomically Dispersed Binary Co‐Ni Sites in Nitrogen‐Doped Hollow Carbon Nanocubes for Reversible Oxygen Reduction and Evolution journal October 2019
Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N 2 and H 2 O journal February 2020
Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells journal March 2019
Recent Advances for MOF‐Derived Carbon‐Supported Single‐Atom Catalysts journal February 2019
A Facile Route for Constructing Effective Cu−N x Active Sites for Oxygen Reduction Reaction journal December 2019
Heterogeneous Single Atom Electrocatalysis, Where “Singles” Are “Married” journal January 2020
Carbon-Rich Nanomaterials: Fascinating Hydrogen and Oxygen Electrocatalysts journal July 2018
Unveiling the Activity Origin of Electrocatalytic Oxygen Evolution over Isolated Ni Atoms Supported on a N‐Doped Carbon Matrix journal October 2019
Two‐Dimensional Conjugated Aromatic Networks as High‐Site‐Density and Single‐Atom Electrocatalysts for the Oxygen Reduction Reaction journal September 2019
Rapid and energy-efficient microwave pyrolysis for high-yield production of highly-active bifunctional electrocatalysts for water splitting journal January 2020
Cobalt‐based coordination polymer as high activity electrocatalyst for oxygen reduction reaction: Catalysis by novel active site CoO 4 N 2 journal December 2019
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Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction journal November 2019
Atomic‐Scale Insights into the Low‐Temperature Oxidation of Methanol over a Single‐Atom Pt 1 ‐Co 3 O 4 Catalyst journal April 2019
Cobalt Nanoparticles and Atomic Sites in Nitrogen‐Doped Carbon Frameworks for Highly Sensitive Sensing of Hydrogen Peroxide journal August 2019
Preparation of reduced graphite oxide loaded with cobalt(II) and nitrogen co-doped carbon polyhedrons from a metal-organic framework (type ZIF-67), and its application to electrochemical determination of metronidazole journal August 2019
Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction in PEM Fuel Cells: Self-Template Synthesis Approach to Enhancing Catalytic Activity and Stability journal March 2019
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Core-Shell Polydopamine@Zr-Hemin MOFs Derived Fe-N-Doped Porous Carbon Nanospheres Electrocatalysts for the Oxygen Reduction journal January 2018
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Transition Metal–Nitrogen–Carbon (M–N–C) Catalysts for Oxygen Reduction Reaction. Insights on Synthesis and Performance in Polymer Electrolyte Fuel Cells journal February 2019
Bacterium, Fungus, and Virus Microorganisms for Energy Storage and Conversion journal October 2019
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A review of non-precious metal single atom confined nanomaterials in different structural dimensions (1D–3D) as highly active oxygen redox reaction electrocatalysts journal January 2020
Direct Growth of Carbon Nanotubes Doped with Single Atomic Fe–N 4 Active Sites and Neighboring Graphitic Nitrogen for Efficient and Stable Oxygen Reduction Electrocatalysis journal September 2019
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Figures / Tables (5)